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Smectite transformation in high molar KOH solutions

Published online by Cambridge University Press:  09 July 2018

A. Bauer  and
B. Velde
A. Bauer
Affiliation:
Ecole Normale Supérieure, Laboratoire de Géologie, 24, rue Lhomond, 75231 Paris Cedex 05 BRGM, Département Géomatériaux et Géoprocédés, Avenue de Concyr, B.P. 6009, 45060 Orléans Cedex 2, France
B. Velde
Affiliation:
Ecole Normale Supérieure, Laboratoire de Géologie, 24, rue Lhomond, 75231 Paris Cedex 05
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Abstract

Batch reactor experiments were performed at 35°C and 80°C to determine the effect of high molar KOH solutions on the mineralogy and solution chemistry of two different smectites. The Ceca smectite is a nearly pure montmorillonite, and the Ibeco clay has a significant component of 35% beidellitic charge. Each reactor was charged with 1 g of <2 mm fraction smectite and 80, 160, 240 ml of 0.1–4 M KOH solution. In these experiments, the changes in solution composition and mineralogy were monitored as a function of time.

In the experiments, at all temperatures and under all chemical conditions, the smectite appears to change in diffracting domain size, which decreases with time. This probably reflects a change in crystal shape. The structures then become more illite rich and the diffracting domain continues to decrease.

Information

Type
Research Article
Information
Clay Minerals , Volume 34 , Issue 2 , June 1999 , pp. 259 - 273
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1999

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References

Andersson, K., Allard, B., Bengtsson, M. & Magnusson, B. (1989) Chemical composition of cement pore waters. Cement Concrete Res. 19, 327–332.Google Scholar
Barrer, R.M. (1982) Hydrothermal Chemistry of Zeolites. Academic Press, New York.Google Scholar
Bauer, A. & Berger, G. (1998) Kaolinite and smectite dissolution rate in high molar KOH solutions at 35° and 80°C. Appl. Geochem. 13, 905–916.CrossRefGoogle Scholar
Day, P.R. (1965) Particle fractionation and particle size analysis. Pp. 545-567 in: Methods of Soil Analysis (Black, C.A., editor). Am. Soc. Agron. Inc.Google Scholar
Donahoe, R.J. & Liou, J.G. (1985) An experimental study on the process of zeolite formation. Geochim. Cosmochim. Acta, 49, 2349–2360.Google Scholar
Donahoe, R.J., Liou, J.G. & Guldman, S. (1984) Synthesis and characterisation of zeolites in the system Na2O-K2O-Al2O3-SiO2-H2O. Clays Clay Miner. 32, 433–443.Google Scholar
Dougan, W.K. & Wilson, A.L. (1974) The absorptiometry determination of Al in water. A comparison of some chromogenic reagents and the development of an improved method. Analyst, 99, 413–430.Google Scholar
Eberl, D.D. (1978) The reaction of montmorillonite to mixed-layer clay. Geochim. Cosmochim. Acta, 42, 1–7.CrossRefGoogle Scholar
Eberl, D.D. & Hower, J. (1977) The hydrothermal transformation of sodium and potassium smectite into mixed layer clays. Clays Clay Miner. 25, 215–227.CrossRefGoogle Scholar
Eberl, D.D., Velde, B. & McCormick, T. (1993) Synthesis of illite-smectite from smectite at earth surface temperatures and high pH. Clay Miner. 28, 49–60.CrossRefGoogle Scholar
Farmer, V.C. (1974) The Infrared Spectra of Minerals. Monograph No. 4, Mineralogical Society, London.Google Scholar
Grasshof, K. (1976) Methods of Seawater Analysis. Springer Verlag, Heidelberg.Google Scholar
Hawkins, D.B. (1981) Kinetics of glass dissolution and zeolite formation under hydrothermal conditions. Clays Clay Miner. 29, 331–340.CrossRefGoogle Scholar
Haworth, A., Sharland, S.M. & Tweed, C.J. (1989) Modelling of the degradation of cement in a nuclear waste repository. Mat. Res. Soc. Symp. Proc. 127, 447-454.Google Scholar
Howard, J. J. & Roy, D. M. (1985) Development of layer charge and kinetics of experimental smectite alteration. Clays Clay Miner. 33, 81–88.Google Scholar
Inoue, A. (1983) Potassium fixation by clay minerals during hydrothermal treatment. Clays Clay Miner. 31, 81–91.Google Scholar
Inoue, A. (1995) The formation of clay minerals in hydrothermal environments. Pp. 268-269 in: Origin and Mineralogy of Clays (Velde, B., editor). Springer-Verlag, Berlin.Google Scholar
Inoue, A. & Watanabe, T. (1989) Infra-red spectra of interstratified illite/smectite from hydrothermally altered tuffs (Shinzan, Japan) and diagenetic bentonites (Kinnekulle, Sweden). Clay Sci. 7, 263–275.Google Scholar
Jardine, P.M., Zelaszny, L.W. & Evans, A. (1986) Solution aluminium anomalies resulting from various filtering materials. Soil Sci. Amer. 50, 891–894.Google Scholar
Jennings, S. & Thompson, G.R. (1986) Diagenesis of Plio-Pleistocene sediments of the Colorado River Delta, southern California. J. Sed. Pet. 56, 89–98.Google Scholar
Klug, H.P. & Alexander, L.E. (1954) Crystallite-size determination from line broadening. Pp. 491-538 in X-ray Diffraction Procedures. Wiley, New York.Google Scholar
Komareni, S. & White, W.B. (1983) Hydrothermal reaction of strontium and transuranic simulator elements with clay minerals, zeolites and shales. Clays Clay Miner. 31, 113.Google Scholar
Kumar, S., Yen, T.F., Chilingarian, G.V. & Donaldson, E.C. (1989) Alkaline flooding. In: Enhanced Oil Recovery, II Process & Operations. (Donaldson, E.C., Chilingarian, G.V. and Yen, T.F., Editors). Developments in Petroleum Science, Elsevier, Amsterdam.Google Scholar
Lanson, B. (1990) Mise en évidence des mécanismes de transformation des interstratifiés illite/smectite au cours de la diagenèse. Thesis, Univ. Paris IV, France.Google Scholar
Lanson, B. (1997) Decomposition of experimental X-ray diffraction patterns (profile fitting). A convenient way to study clay minerals. Clays Clay Miner. 45, 132–146.Google Scholar
Lee, S.Y. & Tank, R.W. (1985) Role of clays in the disposal of nuclear waste: a review. Appl. Clay Sci. 1, 145–162.Google Scholar
Lunden, I. & Andersson, K. (1989) Modelling the mixing of cement pore water and groundwater using the PHREEQE code. Mat. Res. Soc. Symp. Proc. 127, 949-956.Google Scholar
Mohnot, S.M., Bae, J.H. & Foley, W.L. (1987) A study of alkali/mineral reactions. SPE Reserv. Eng. 653-663.Google Scholar
Moore, D.M. & Reynolds, C.R. Jr. (1989) X-ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford Univ. Press, New York.Google Scholar
Nadeau, P.H. & Reynolds, C.R. Jr. (1981) Burial metamorphism in the Mancos Shale. Clays Clay Miner. 19, 249–259.Google Scholar
Nadeau, P.H., Wilson, M.J., McHardy, W.J. & Tait, J.M. (1984) Interstratified clay as fundamental particles. Science, 225, 223–225.Google Scholar
Novosad, Z. & Novosad, J. (1984) Determination of alkalinity losses resulting from hydrogen ion exchange in alkaline flooding. SPE of AIME, 49-52.Google Scholar
Reynolds, R.C. Jr. (1980) interstratfied clay minerals. Pp. 249-303 in: Crystal Structures of Clay Minerals and their X-ray Identification (Brindley, G.W. & Brown, G., editors) Monograph No. 5, Mineralogical Society, London.Google Scholar
Reynolds, R.C. Jr. (1985) NEWMOD, a computer program for the calculation of basal diffraction intensities of mixed layer clay minerals. (Reynolds, R.C., editor). 8 Brook Rd., Hanover, New Hampshire 03755, USA.Google Scholar
Reynolds, R.C. Jr. (1986) The Lorentz factor and preferred orientation in oriented clay aggregates. Clays Clay Miner. 34, 39–367.Google Scholar
Russell, J.D. and Fraser, A.R. (1994) Infrared methods. Pp. 11-67 in: Clay Mineralogy: Spectroscopic and Chemical Determinative Methods (Wilson, M.J., editor). Chapman & Hall, London.Google Scholar
Savage, D., Bateman, K., Hill, P., Hughes C, Milodowski, A., Pearce, J., Rae, E. & Rochelle, C. (1992) Rate and mechanism of the reaction of silicates with cement pore waters. Appl. Clay Sci. 7, 33–45.Google Scholar
Środoń, J., Elsass, F., McHardy, W.J. & Morgan, D.J. (1992) Chemistry of Mite smectite from TEM measurements of fundamental particles. Clay Miner. 27, 137-158.Google Scholar
Watanabe, T. (1981) Identification of illite/montmorillonite interstratifications by X-ray powder diffraction. J. Mineral Soc. Jpn. Spec. Issue, 15, 32–41.Google Scholar
Watanabe, T. (1988) The structural model of Mite/ smectite interstratified minerals and the diagram for its identification. Clay Sci. 7, 97–114.Google Scholar
Whitney, G. & Northrop, H.R. (1988) Experimental investigation of the smectite to Mite reaction: dual reaction mechanisms and oxygen isotope systematics. Am. Miner. 73, 77–90.Google Scholar