Hostname: page-component-7b7567c8c-fvjsw Total loading time: 0 Render date: 2026-11-13T03:04:47.883Z Has data issue: false hasContentIssue false
  • English
  • Français

Neutron Diffraction Study of Interlayer Water in Sodium Wyoming Montmorillonite Using a Novel Difference Method

Published online by Cambridge University Press:  28 February 2024

D. Hugh Powell,
Kowut Tongkhao,
Shane J. Kennedy and
Phillip G. Slade
D. Hugh Powell
Affiliation:
Department of Chemistry, University of Adelaide, South Australia 5005, Australia
Kowut Tongkhao
Affiliation:
Department of Chemistry, University of Adelaide, South Australia 5005, Australia
Shane J. Kennedy
Affiliation:
Australian Nuclear Science & Technology Organisation, Menai, New South Wales 2234, Australia
Phillip G. Slade
Affiliation:
CSIRO Division of Soils, Glen Osmond, South Australia 5064, Australia
Rights & Permissions [Opens in a new window]

Abstract

An abstract is not available for this content so a preview has been provided. As you have access to this content, a full PDF is available via the ‘Save PDF’ action button.
Image of the first page of this content. For PDF version, please use the ‘Save PDF’ preceeding this image.'

Keywords

InterlayerMontmorilloniteNeutron DiffractionStructureWater

Information

Type
Brief Report
Information
Clays and Clay Minerals , Volume 45 , Issue 2 , April 1997, pp. 290 - 294
Copyright
Copyright © 1997, The Clay Minerals Society

References

Blech, I.A. and Averbach, B.L.. 1965. Multiple scattering of neutrons in vanadium and copper. Phys Rev 137: A1113–1116.CrossRefGoogle Scholar
Boek, E.S., Coveney, P.V. and Skipper, N.T.. 1995. Monte Carlo molecular modeling studies of hydrated Li-, Na-, and K-smectites: Understanding the role of potassium as a clay swelling inhibitor. J Am Chem Soc 117: 12608–12617.CrossRefGoogle Scholar
Chang, F-RC, Skipper, N.T. and Sposito, G.. 1995. Computer simulation of interlayer molecular structure in sodium mont-morillonite hydrates. Langmuir 11: 2734–2741.CrossRefGoogle Scholar
Hawkins, R.K. and Egelstaff, P.A.. 1980. Interfacial water structure in montmorillonite from neutron diffraction experiments. Clays Clay Miner 28: 19–28.CrossRefGoogle Scholar
Hughes, D.J. and Harvey, J.F.. 1955. Neutron cross sections. New York: McGraw-Hill. 328 p.Google Scholar
Karaborni, S., Smit, B., Heidug, W., Urai, J. and van Oort, E.. 1996. The swelling of clays: Molecular simulations of the hydration of montmorillonite. Science 271: 1102–1104.CrossRefGoogle Scholar
Méring, J. and Brindley, G.W.. 1967. X-ray diffraction band profiles of montmorillonite—Influence of hydration and of the exchangeable cations. Clays Clay Miner 15: 51–60.CrossRefGoogle Scholar
Montague, D.G., Gibson, I.P. and Dore, J.C.. 1981. Structural studies of liquid alcohols by neutron diffraction: I. Deuterated methyl alcohol CD3OD. Mol Phys 44: 1355–1367.CrossRefGoogle Scholar
Newman, A.C.D.. 1987. Chemistry of clays and clay minerals. London: Mineral Soc. 480 p.Google Scholar
North, D.M., Enderby, J.E. and Egelstaff, P.A.. 1968. The structure factor for liquid metals. I. The application of neutron diffraction techniques. J Phys C 1: 784–794.CrossRefGoogle Scholar
Paalman, H.H. and Pings, C.J.. 1962. Numerical evaluation of X-ray absorption factors for cylindrical samples and annular cells. J Appl Phys 33: 2635–2639.CrossRefGoogle Scholar
Powell, D.H., Neilson, G.W. and Enderby, J.E.. 1989. A neutron diffraction study of NiCl2 in D2O and H2O. A direct determination of gNiH(r). J Phys: Condens Matter 1: 8721–8733.Google Scholar
Sears, V.F.. 1992. Neutron scattering lengths and cross sections. Neutron News 3: 26–37.CrossRefGoogle Scholar
Skipper, N.T., Smalley, M.V., Williams, G.D., Soper, A.K. and Thompson, C.H.. 1995. Direct measurement of the electrical double-layer structure in hydrated lithium vermiculite clays by neutron diffraction. J Phys Chem 99: 14201–14204.CrossRefGoogle Scholar
Skipper, N.T., Soper, A.K. and McConnell, J.D.C.. 1991. The structure of interlayer water in vermiculite. J Chem Phys 94: 5751–5760.CrossRefGoogle Scholar
Skipper, N.T., Soper, A.K. and Smalley, M.V.. 1994. Neutron diffraction study of calcium vermiculite: Hydration of calcium ions in a confined environment. J Phys Chem 98: 942–945.CrossRefGoogle Scholar
Skipper, N.T., Sposito, G. and Chang, F-RC. 1995. Monte Carlo simulation of interlayer molecular structure in swelling clay minerals: 1. Methodology. Clays Clay Miner 43: 285–293.CrossRefGoogle Scholar
Slade, P.G., Quirk, J.P. and Norrish, K.. 1991. Crystalline swelling of smectite samples in concentrated NaCl solutions in relation to layer charge. Clays Clay Miner 39: 234–238.CrossRefGoogle Scholar
Slade, P.G., Stone, P.A. and Radoslovich, E.W.. 1985. Interlayer structure of the two-layer hydrates of Na- and Ca- vermic-ulites. Clays Clay Miner 33: 51–61.Google Scholar
Soper, A.K. and Phillips, M.G.. 1986. A new determination of the structure of water at 25°C. Chem Phys 107: 47–60.CrossRefGoogle Scholar
Sposito, G. and Prost, R.. 1982. Structure of water absorbed on smectites. Chem Rev 82: 553–573.CrossRefGoogle Scholar