Weak equivalence of primitive matrices is a known invariant arising naturally from the study of inverse limit spaces. Several new invariants for weak equivalence are described. It is proved that a positive dimension group isomorphism is a complete invariant for weak equivalence. For the transition matrices corresponding to periodic kneading sequences, the discriminant is proved to be an invariant when the characteristic polynomial is irreducible. The results have direct application to the topological classification of one-dimensional inverse limit spaces.