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Spectroscopy of Palladium Nanoparticle Synthesis: Tailoring Nanoparticle Growth Parameters for Hydrogen Storage

Published online by Cambridge University Press:  27 April 2020

Amanda L. HoukOpen the ORCID record for Amanda L. Houk[Opens in a new window] and
Levi R. Houk
Amanda L. Houk*
Affiliation:
Savannah River National Laboratory, Aiken, SC 29808, U.S.A.
Levi R. Houk*
Affiliation:
Savannah River National Laboratory, Aiken, SC 29808, U.S.A.
*
*Corresponding Authors: amanda.houk@srnl.doe.gov, levi.houk@srnl.doe.gov
*Corresponding Authors: amanda.houk@srnl.doe.gov, levi.houk@srnl.doe.gov
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Abstract

Using palladium for hydrogen storage requires palladium (Pd) particles exhibiting specific parameters, including surface area, particle size, and particle shape, with increased interest in palladium nanoparticles (Pd NPs). In order to routinely monitor the synthesis of these particles a spectroscopic method is being developed using infrared (IR), Raman, and UV-Vis spectroscopy. By monitoring the production of Pd NPs, the growth of the NPs can be controlled to ensure quality of the product to match the desired finished particle specifications. For the reaction presented, the conversion of the intermediate tetraamminepalladium(II) chloride (PTC) to diamminepalladium(II) chloride (PDC) can influence the Pd NPs properties. This study is first being developed in lab bench scale quantities to allow ultimate control of the Pd NPs.

Keywords

Pdspectroscopyinfrared (IR) spectroscopyRaman spectroscopy

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MRS Advances , Volume 5 , Issue 40-41: Nanoscale and Quantum Materials , 2020, pp. 2085 - 2090
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Copyright © Materials Research Society 2020

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