Hostname: page-component-7b7567c8c-7pwfn Total loading time: 0 Render date: 2026-11-15T23:24:54.280Z Has data issue: false hasContentIssue false
  • English
  • Français

Polymer/Halloysite Nanotubes Composites: Mechanical Robustness and Optical Transmittance

Published online by Cambridge University Press:  19 December 2016

Kenan Song,
Michael F. Rubner,
Robert E. Cohen and
Khalid A. Askar
Kenan Song*
Affiliation:
Department of Materials Science and Engineering, MIT, Massachusetts 02139, United States
Michael F. Rubner
Affiliation:
Department of Materials Science and Engineering, MIT, Massachusetts 02139, United States
Robert E. Cohen
Affiliation:
Department of Chemical Engineering, MIT, Massachusetts 02139, United States
Khalid A. Askar
Affiliation:
Department of Materials Science and Engineering, Masdar Institute, United Arab Emirates
*
*(Email: song.k@husky.neu.edu)
Get access

Abstract

Halloysite nanotubes (HNTs) have attracted attention for their potential use in a variety of applications owing to their mechanical robustness, thermal stability, natural abundance and low cost. The inclusion of HNTs into epoxy matrix at low concentrations was found to be effective in stiffening and hardening. At 1 vol% loading, composites showed improvements up to 50% in modulus and 100% in hardness compared to pure epoxy, based on nanoindentation measurements. In addition, tribology studies using TriboIndenter and AFM showed an increase of wear resistance; depending on their orientation in the composite, HNTs can decrease the scratch volume by 50% at fixed loading levels. Adding HNTs into epoxy had almost no effect on the transmittance over the range of wavelength from 400 to 700 nm. Transmittance values of 91% were observed for HNT concentrations as high as 10 vol%.

Keywords

compositeelastic propertiesoptical properties

Information

Type
Articles
Information
MRS Advances , Volume 2 , Issue 1: Nanomaterials , 2017, pp. 27 - 32
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

Song, K., Zhang, Y., Meng, J., Green, E.C., Tajaddod, N., Li, H. and Minus, M.L., Mater. 6, 2543 (2013).Google Scholar
Aliofkhazraei, M., Characterization of Nanostructured Coatings, in Nanocoatings (Springer Berlin Heidelberg, Berlin, 2011), p. 77.Google Scholar
Bhushan, B. and Gupta, B.K., Handbook of tribology: materials, coatings, and surface treatments, 1st ed. (McGraw-Hill, New York, NY, Malabar, FL, 1991), p. 10.Google Scholar
Song, K., Zhang, Y., Meng, J. and Minus, M.L., J. Appl. Polym. Sci. 127, 2977 (2013).CrossRefGoogle Scholar
Zhang, Y., Song, K., Meng, J. and Minus, M.L., ACS Appl. Mater. Interfaces 5, 807 (2013).Google Scholar
Friedrich, K., Zhang, Z. and Schlarb, A.K., Compos. Sci. Technol. 65, 2329 (2005).Google Scholar
Myshkin, N., Petrokovets, M. and Kovalev, A., Tribol. Int. 38, 910 (2006).CrossRefGoogle Scholar
Deng, X., Mammen, L., Butt, H.-J. and Vollmer, D., Sci. 335, 67 (2012).CrossRefGoogle Scholar
Jin, H., Tian, X., Ikkala, O. and Ras, R.H.A., ACS Appl. Mater. Interfaces 5, 485 (2013).CrossRefGoogle Scholar
Seyedmehdi, S., Zhang, H. and Zhu, J., J. Appl. Polym. Sci. 128, 4136 (2013).Google Scholar
Geng, Z. and He, J., J. Mater. Chem. A 2, 16601 (2014).Google Scholar
Zhou, H., Wang, H., Niu, H., Gestos, A., Wang, X. and Lin, T., Adv. Mater. 24, 2409 (2012).CrossRefGoogle Scholar
Meng, J., Zhang, Y., Song, K. and Minus, M.L., Macromol. Mater. Eng. 299, 144 (2014).CrossRefGoogle Scholar
Song, K., Zhang, Y., Meng, J. and Minus, M.L., Polym. 75, 187 (2015).Google Scholar
Song, K., Zhang, Y. and Minus, M.L., Macromol. Chem. Phys. 216, 1313 (2015).Google Scholar
Tajaddod, N., Song, K., Green, E.C., Zhang, Y. and Minus, M.L., Macromol. Mater. Eng. 30, 315 (2016).Google Scholar
Song, K., Chen, D., Polak, R., Rubner, M.F., Cohen, R.E. and Askar, K.A., ACS Appl. Mater. Interfaces (2016).Google Scholar
Song, K., Polak, R., Chen, D., Rubner, M.F., Cohen, R.E. and Askar, K.A., ACS Appl. Mater. Interfaces 8, 20396 (2016).Google Scholar
Jalili, R., Razal, J.M. and Wallace, G.G., Sci. Rep. 3, 3438 (2013).Google Scholar
Brahim, S.B. and Cheikh, R.B., Compos. Sci. Technol. 67, 140 (2007).Google Scholar
Jacob, M., Thomas, S. and Varughese, K.T., Compos. Sci. Technol. 64, 955 (2004).Google Scholar
Herrera-Franco, P. and Valadez-Gonzalez, A., Composites Part A: Applied Science and Manufacturing 35, 339 (2004).CrossRefGoogle Scholar
Fu, S.-Y. and Lauke, B., Compos. Sci. Technol. 56, 1179 (1996).Google Scholar
Tungjitpornkull, S. and Sombatsompop, N., J. Mater. Process. Technol. 209, 3079 (2009).CrossRefGoogle Scholar
Kato, K., Wear 241, 151 (2000).Google Scholar