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Synthesis of LiFePO4 Using an Ionic Liquid/Water Composite Medium

Published online by Cambridge University Press:  31 January 2017

Rany Tith,
Darren Kwee,
Kichang Jung and
Alfredo A. Martinez-Morales
Rany Tith*
Affiliation:
College of Engineering, Center for Environmental Research and Technology, Riverside, CA 92507, U.S.AWinston Chung Global Energy Center, University of California, Riverside, CA 92521, U.S.A.
Darren Kwee
Affiliation:
College of Engineering, Center for Environmental Research and Technology, Riverside, CA 92507, U.S.AWinston Chung Global Energy Center, University of California, Riverside, CA 92521, U.S.A.
Kichang Jung
Affiliation:
College of Engineering, Center for Environmental Research and Technology, Riverside, CA 92507, U.S.ADepartment of Chemical and Environmental Engineering, University of California, Riverside, CA 92521, U.S.A
Alfredo A. Martinez-Morales
Affiliation:
College of Engineering, Center for Environmental Research and Technology, Riverside, CA 92507, U.S.AWinston Chung Global Energy Center, University of California, Riverside, CA 92521, U.S.A.
*
*(Email: rany.r.tith@gmail.com)
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Abstract

In this work, we investigate a novel synthesis route for the synthesis of LiFePO4 material that utilizes an ionic liquid/water composite medium. The effect of reaction time and reaction temperature on the crystallinity of synthesized material is investigated through X-ray diffraction (XRD). Morphology is analyzed through scanning electron microscopy (SEM). It is observed that the intensity of peaks corresponding to LiFePO4 increase as reaction time increases, but unwanted peaks are present as well. SEM characterization indicates that various structures are initially formed, but as the reaction time progresses product morphology changes in size.

Keywords

energy storageenergetic materialenergy generation

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Type
Articles
Information
MRS Advances , Volume 2 , Issue 17: Processing and Manufacturing , 2017, pp. 945 - 949
Copyright
Copyright © Materials Research Society 2017 

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References

REFERENCES

Armand, M., & Tarascon, J.-M. (2008). Building better batteries. Nature, 451(7179), 652–657. Retrieved from http://www.nature.com/doifinder/10.1038/451652a CrossRefGoogle ScholarPubMed
Padhi, A.K., Nanjundaswamy, K.S., and , J. B. G. (1997). Phospho-Olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries. J. Electrochem. Soc., 144(4), 1–7.Google Scholar
Andersson, A. S., Thomas, J. O., Kalska, B., and Häggström, L., “Thermal Stability of LiFePO 4 -Based Cathodes,” Electrochem. Solid-State Lett., vol. 3, no. 2, pp. 66–68, 2000.Google Scholar
Recham, N., Dupont, L., Courty, M., Djellab, K., Larcher, D., Armand, M., & Tarascon, J. M. (2009). Ionothermal Synthesis of Tailor-Made LiFePO 4 Powders for Li-Ion Battery Applications. Chemistry of Materials, 21(5), 1096–1107. http://doi.org/10.1021/cm803259x Google Scholar
Antonietti, M., Kuang, D., Smarsly, B., & Zhou, Y. (2004). Ionic Liquids for the Convenient Synthesis of Functional Nanoparticles and Other Inorganic Nanostructures. Angewandte Chemie International Edition, 43(38), 4988–4992. JOUR. http://doi.org/10.1002/anie.200460091 Google Scholar
quan Feng, W., heng Lu, Y., Chen, Y., wei Lu, Y., and Yang, T., “Thermal stability of imidazolium-based ionic liquids investigated by TG and FTIR techniques,” J. Therm. Anal. Calorim., vol. 125, no. 1, pp. 143–154, 2016.CrossRefGoogle Scholar
Parnham, E. R., & Morris, R. E. (n.d.). Ionothermal Synthesis of Zeolites, Metal–Organic Frameworks, and Inorganic– Organic Hybrids. http://doi.org/10.1021/ar700025k Google Scholar