Hostname: page-component-7b7567c8c-lpg2g Total loading time: 0 Render date: 2026-11-15T09:33:25.313Z Has data issue: false hasContentIssue false
  • English
  • Français

New Phenomena and Opportunities in Molecule-Based Magnets

Published online by Cambridge University Press:  31 January 2011

Arthur J. Epstein
Get access

Extract

Molecule-based magnets display the full range of phenomena observed in conventional transition-metal and rareearth-based magnets, as well as unusual phenomena unique to themselves. These materials form in a wide range of one-, two-, and three-dimensional network structures, with disorder often playing a substantial role.

Information

Type
Research Article
Information
MRS Bulletin , Volume 25 , Issue 11: Molecule-Based Magnets , November 2000, pp. 33 - 40
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

1.Miller, J.S., Calabrese, J.C., Epstein, A.J., Bigelow, R.W., Zhang, J.H., and Reiff, W.E., J. Chem. Comm. (1986) p. 1026; S. Chittipeddi, K.R. Cromack, J.S. Miller, and A.J. Epstein, Phys. Rev. Lett. 58 (1987) p. 2695.CrossRefGoogle Scholar
2.Manriquez, J.M., Yee, G.T., McLean, R.S., Epstein, A.J., and Miller, J.S., Science 252 (1991) p. 1415.CrossRefGoogle Scholar
3.Chakraborty, A., Epstein, A.J., Lawless, W.N., and Miller, J.S., Phys. Rev. B 40 (1989) p. 11422.CrossRefGoogle Scholar
4.Manson, J.L., Kmety, C.R., Huang, Q.-Z., Lynn, J.W., Bendele, G.M., Pagola, S., Stephens, P.W., Liable-Sands, L.M., Rheingold, A.L., Epstein, A.J., and Miller, J.S., Chem. Mater. 10 (1998) p. 2552.CrossRefGoogle Scholar
5.Batten, S.R., Jensen, P., Moubaraki, B., Murray, K.S., and Robson, R., Chem. Commun. (Cambridge) (1998) p. 439.Google Scholar
6.Kurmoo, M. and Kepert, C.J., New J. Chem. 22 (1998) p. 1515.CrossRefGoogle Scholar
7.Kmety, C.R., Manson, J.L., Huang, Q., Lynn, J.W., Erwin, R.W., Miller, J.S., and Epstein, A.J., Phys. Rev. B 60 (1999) p. 60.CrossRefGoogle Scholar
8.Manson, J.L., Kmety, C.R., Epstein, A.J., and Miller, J.S., Inorg. Chem.. 38 (1999) p. 2552.CrossRefGoogle Scholar
9.Batten, S.R., Jensen, P., Kepert, C.J., Kurmoo, M., Moubaraki, B., Murray, K.S., and Price, D.J., J. Chem. Soc., Dalton Trans. (1999) p. 2987.CrossRefGoogle Scholar
10.Kmety, C.R., Huang, Q., Lynn, J.W., Erwin, R.W., Manson, J.L., McCall, S., Crow, J.E., Stevenson, K.L., Miller, J.S., and Epstein, A.J., Phys. Rev. B 62 (2000) p. 5576.CrossRefGoogle Scholar
11.Kmety, C.R., “Phase Transitions in Molecule-Based Magnets: Neutron Diffraction, Magnetic and Specific Heat Studies,” PhD dissertation, The Ohio State University, 2000.Google Scholar
12.Kmety, C.R., Manson, J.L., Miller, J.S., and Epstein, A.J., to be published.Google Scholar
13.Pokhodnya, K.I., Epstein, A.J., and Miller, J.S., Adv. Mater. 12 (2000) p. 410.3.0.CO;2-B>CrossRefGoogle Scholar
14.Zhou, P., Morin, B., Epstein, A.J., and Miller, J.S., Phys. Rev. B 48 (1993) p. 1325.CrossRefGoogle Scholar
15.Zhou, P., Long, S.M., Miller, J.S., and Epstein, A.J., Phys. Lett. A 181 (1993) p. 71.CrossRefGoogle Scholar
16.Chudnovsky, E.M., Phys. Rev. B 33 (1986) p. 2021; J. Magn. Magn. Mater. 79 (1989) p. 127.CrossRefGoogle Scholar
17.Gebring, P.M., Salamon, M.B., Moral, A. del, and Arnautdas, J.I., Phys. Rev. B 41 (1990) p. 9134; J. Filippi, V.S. Amaral, and B. Barbara, Phys. Rev. B 44 (1991) p. 2842; M.J. O'Shea, K.M. Lee, and A. Fert, J. Appl. Phys. 67 (1990) p. 5769.CrossRefGoogle Scholar
18.Wynn, C.M., Girtu, M., Brinckerhoff, W.B., Sugiura, K.-I., Miller, J.S., and Epstein, A.J., Chem. Mater. 9 (1997) p. 2156.CrossRefGoogle Scholar
19.Miller, J.S. and Epstein, A.J., J. Chem. Soc., Chem. Commun. (1998) p. 1319.Google Scholar
20.Wynn, C.M., Girtu, M.A., Miller, J.S., and Epstein, A.J., Phys. Rev. B 56 (1997) p. 315.CrossRefGoogle Scholar
21.Seiden, J., J. Phys. (France) 44 (1983) p. L947.Google Scholar
22.Girtu, M.A., Wynn, C.M., Sugiura, K.-I., Miller, J.S., and Epstein, A.J., J. Appl. Phys. 81 (1997) p. 4410; Synth. Met.. 85 (1997) p. 1703.CrossRefGoogle Scholar
23.Rittenberg, D.K., Sugiura, K.-I., Sakata, Y., Mikami, S., Epstein, A.J., and Miller, J.S., Adv. Mater. 12 (2000) p. 126.3.0.CO;2-5>CrossRefGoogle Scholar
24.Zhou, P., Morin, B.G., Epstein, A.J., McLean, R.S., and Miller, J.S., J. Appl. Phys. 73 (1993) p. 6569.CrossRefGoogle Scholar
25.Morrish, A.H., The Physical Principles of Magnetism (Kreiger, Huntington, NY, 1980) p. 511.Google Scholar
26.Mathoniere, A., Carlling, S.G., Yusheng, D., and Day, P., J. Chem. Soc., Chem. Commun. (1994) p. 1551; A. Mathoniere, C.J. Nuttall, S.G. Carling, and P. Day, Inorg. Chem. 35 (1996) p. 1201.CrossRefGoogle Scholar
27.Buschmann, W.E., Paulson, S.C., Wynn, C.M., Girtu, M.A., Epstein, A.J., White, H.S., and Miller, J.S., Adv. Mater. 9 (1997) p. 645.CrossRefGoogle Scholar
28.Sato, O., Iyoda, T., Fujishima, A., and Hashimoto, K., Science 271 (1996) p. 49.CrossRefGoogle Scholar
29.Sato, O., Einaga, Y., Iyoda, T., Fujishima, A., and Hashimoto, K., J. Electrochem. Soc. 144 (1997) p. L11.CrossRefGoogle Scholar
30.Sato, O., Einaga, Y., Fujishima, A., and Hashimoto, K., Inorg. Chem. 38 (1999) p. 4405.CrossRefGoogle Scholar
31.Varret, F., Constant-Machado, H., Dormann, J.L., Goujon, A., Jeftic, J., Nogues, M., Bousseksou, A., Klokishner, S., Dolbecq, A., and Verdaguer, M., Hyperfine Interact. 113 (1998) p. 37.CrossRefGoogle Scholar
32.Ohkoshi, S., Yorozu, S., Sato, O., Iyoda, T., Fujishima, A., and Hashimoto, K., Appl. Phys. Lett. 70 (1997) p. 1040.CrossRefGoogle Scholar
33.Sastry, M.D., Bhide, M.K., Kadam, R.M., Chavan, S.A., Yakhmi, J.V., and Kahn, O., Chem. Phys. Lett. 301 (1999) p. 385.CrossRefGoogle Scholar
34.Pejakovic, D.A., Manson, J.L., Miller, J.S., and Epstein, A.J., J. Appl. Phys. 87 (2000) p. 6028.CrossRefGoogle Scholar
35.Pejakovic, D.A., Manson, J.L., Miller, J.S., and Epstein, A.J., Phys. Rev. Lett. 85 (2000) p. 1994.CrossRefGoogle Scholar
36.Koshihara, S., Oiwa, A., Hirasawa, M., Katsumoto, S., Iye, Y., Urano, C., Takagi, H., and Munekata, H., Phys. Rev. Lett. 78 (1997) p. 4617; H. Munekata, T. Abe, S. Koshihara, A. Oiwa, M. Hirasawa, S. Katsumoto, Y. Iye, C. Urano, and H. Takagi, J. Appl. Phys. 81 (1997) p. 4862.CrossRefGoogle Scholar
37.Awschalom, D.D., Freeman, M.R., Samarth, N., Luo, H., and Furdyna, J.K., Phys. Rev. Lett. 66 (1991) p. 1212; D.D. Awschalom, J. Warnock, and S. von Molnár, Phys. Rev. Lett. 58 (1987) p. 812.CrossRefGoogle Scholar
38.Krenn, H., Zawadzki, W., and Bauer, G., Phys. Rev. Lett. 55 (1985) p. 1510; H. Krenn, K. Kaltenegger, T. Dietl, J. Spalek, and G. Bauer, Phys. Rev. B 39 (1989) p. 10918.CrossRefGoogle Scholar
39.Haneda, S., Munekata, H., Takatani, Y., and Koshihara, S., J. Appl. Phys. 87 (2000) p. 6445.CrossRefGoogle Scholar
40.Baran, M., Gnatchenko, S.L., Gorbenko, O. Yu., Kaul, A.R., Szymczak, R., and Szymczak, H., Phys. Rev. B 60 (1999) p. 9244.CrossRefGoogle Scholar
41.Yoshizawa, K., Mohri, F., Nuspl, G., and Yamabe, T., J. Phys. Chem. B 102 (1998) p. 5432; G.L. Gutsev, B.V. Reddy, S.N. Khanna, B.K. Rao, and P. Jena, Phys. Rev. B 58 (1998) p. 14131; M. Nishino and K. Yamaguchi, Phys. Rev. B 58 (1998) p. 9303; T. Kawamoto, Y. Asai, and S. Abe, Phys. Rev. B 60 (1999) p. 12990.CrossRefGoogle Scholar
42.Pejakovic, D.A., Zhang, J., Miller, J.S., and Epstein, A.J., to be published.Google Scholar
43.Wynn, C.M., Girtu, M.A., Zhang, J., Miller, J.S., and Epstein, A.J., Phys. Rev. B 58 (1998) p. 8508.CrossRefGoogle Scholar