Hostname: page-component-7b7567c8c-2n9c9 Total loading time: 0 Render date: 2026-11-14T22:28:19.901Z Has data issue: false hasContentIssue false
  • English
  • Français

Toward the Rational Design of Open-Framework Materials

Published online by Cambridge University Press:  31 January 2011

Anthony K. Cheetham and
C. N. R. Rao
Get access

Abstract

In spite of the enormous level of interest in open-framework materials (materials with porous channel structures, such as zeolites), the mechanisms by which they are formed are in many cases poorly understood. As a consequence, our ability to design reaction conditions that might lead to the formation of particular crystal architectures is quite limited. This article discusses the state of the art in this area, with particular emphasis on our joint work that was recently recognized by the 2004 S miya Award from the International Union of Materials Research Societies (IUMRS) and presented at the 2004 Materials Research Society Spring Meeting/IUMRS 9th International Conference on Electronic Materials.

Keywords

adsorptioncatalytic materialshydrothermal conditionsopen-framework materialsstructurezeolites.

Information

Type
Research Article
Information
MRS Bulletin , Volume 30 , Issue 2 , February 2005, pp. 93 - 98
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

1.Cheetham, A.K., Férey, G., and Loiseau, T., Angew. Chem. Int. Ed. 38 (1999) p. 3268.3.0.CO;2-U>CrossRefGoogle Scholar
2.Rao, C.N.R., Natarajan, S., and Vaidhayanathan, R., Angew. Chem. Int. Ed. 43 (2004) p. 1466.CrossRefGoogle Scholar
3.Eddaoudi, M., Moler, D.B., Li, H., Chen, B., Reineke, T.M., O'Keefe, M., and Yaghi, O.M., Acc. Chem. Res. 34 (2001) p. 319.CrossRefGoogle Scholar
4.Wilson, S.T., Lok, B.M., Messina, C.A., Cannon, T.R., and Flanigen, E.M., J. Am. Chem. Soc. 104 (1982) p. 1146.CrossRefGoogle Scholar
5.Davis, M.E. and Lobo, R.F., Chem. Mater. 4 (1992) p. 756.CrossRefGoogle Scholar
6.Lewis, D.W., Sankar, G., Wyles, J.K., Thomas, J.M., Catlow, C.R.A., and Willock, D.J., Angew. Chem. Int. Ed. 36 (1997) p. 2675.CrossRefGoogle Scholar
7.Chang, J.-S., Hwang, J.-S., Jhung, S.H., Park, S.-E., Férey, G., and Cheetham, A.K., Angew. Chem. Int. Ed. 43 (2004) p. 2819.CrossRefGoogle Scholar
8.Natarajan, S., Attfield, M.P., and Cheetham, A.K., Angew. Chem. Int. Ed. 36 (1997) p. 978.CrossRefGoogle Scholar
9.Guillou, N., Gao, Q., Forster, P.M., Chang, J.-S., Nogues, M., Park, S.-E., Férey, G., and Cheetham, A.K., Angew. Chem. Int. Ed. 40 (2001) p. 2831.3.0.CO;2-Z>CrossRefGoogle Scholar
10.Natarajan, S., Eswaramoorthy, M., Cheetham, A.K., and Rao, C.N.R., J. Chem. Soc., Chem. Commun. (1998) p. 1561.CrossRefGoogle Scholar
11.Ayyappan, S., Bu, X., Cheetham, A.K., and Rao, C.N.R., Chem. Mater. 10 (1998) p. 3308.CrossRefGoogle Scholar
12.Ayyappan, S., Cheetham, A.K., Natarajan, S., and Rao, C.N.R., J. Solid State Chem. 139 (1998) p. 207.CrossRefGoogle Scholar
13.Ayyappan, S., Bu, X., Cheetham, A.K., Natarajan, S. and Rao, C.N.R., J. Chem. Soc., Chem. Commun. (1998) p. 2181.CrossRefGoogle Scholar
14.Natarajan, S. and Cheetham, A.K., J. Solid State Chem. 140 (1998) p. 435.CrossRefGoogle Scholar
15.Rao, C.N.R., Natarajan, S., and Neeraj, S., J. Am. Chem. Soc. 122 (2000) p. 2810.CrossRefGoogle Scholar
16.Neeraj, S., Forster, P.M., Rao, C.N.R., and Cheetham, A.K., J. Chem. Soc., Chem. Commun. (2001) p. 2716.CrossRefGoogle Scholar
17.Neeraj, S., Rao, C.N.R., and Cheetham, A.K., J. Mater. Chem. 14 (2004) p. 814.CrossRefGoogle Scholar
18.Neeraj, S. and Cheetham, A.K., J. Chem. Soc., Chem. Commun. (2002) p. 1738.CrossRefGoogle Scholar
19.Ayyappan, S., Cheetham, A.K., Natarajan, S., and Rao, C.N.R., Chem. Mater. 10 (1998) p. 3746.CrossRefGoogle Scholar
20.Natarajan, S., Vaidhyanathan, R., Rao, C.N.R., Ayyappan, S., and Cheetham, A.K., Chem. Mater. 11 (1999) p. 1633.CrossRefGoogle Scholar
21.Vaidhyanathan, R., Natarajan, S., Cheetham, A.K., and Rao, C.N.R., Chem. Mater. 11 (1999) p. 3636.CrossRefGoogle Scholar
22.Neeraj, S., Noy, M.L., Rao, C.N.R., and Cheetham, A.K., Solid State Sci. 4 (2002) p. 1231.CrossRefGoogle Scholar
23.Dan, M., Shivashankar, K., Cheetham, A.K., and Rao, C.N.R., J. Solid State Chem. 174 (2003) p. 60.CrossRefGoogle Scholar
24.Forster, P.M. and Cheetham, A.K., Angew. Chem. Int. Ed. 41 (2002) p. 457.3.0.CO;2-W>CrossRefGoogle Scholar
25.Vaidhyanathan, R., Natarajan, S., and Rao, C.N.R., J. Chem. Soc. Dalton Trans. (2003) p. 1459.CrossRefGoogle Scholar
26.Ayyappan, S., Diaz de Delgado, G., Cheetham, A.K., Férey, G., and Rao, C.N.R., J. Chem. Soc. Dalton Trans. (1999) p. 2905.CrossRefGoogle Scholar
27.Dan, M., Behera, J.N., and Rao, C.N.R., J. Mater. Chem. 14 (2004) p. 1257.CrossRefGoogle Scholar
28.Udayakumar, D. and Rao, C.N.R., J. Mater. Chem. 13 (2003) p. 1635.CrossRefGoogle Scholar
29.Behera, J.N., Ayi, A.A., and Rao, C.N.R., Chem. Commun. (2004) p. 968.CrossRefGoogle Scholar
30.Rao, C.N.R., Natarajan, S., Choudhury, A., Neeraj, S., and Ayi, A.A., Acc. Chem. Res. 34 (2001) p. 80.CrossRefGoogle Scholar
31.Choudhury, A. and Rao, C.N.R., Chem. Commun. (2003) p. 366.CrossRefGoogle Scholar
32.Dan, M., Udayakumar, D., and Rao, C.N.R., Chem. Commun. (2003) p. 2212.CrossRefGoogle Scholar
33.Forster, P.M., Burbank, A.M., Livage, C., Férey, G., and Cheetham, A.K., J. Chem. Soc., Chem. Commun. (2004) p. 368.CrossRefGoogle Scholar
34.Stock, N. and Bein, T., Angew. Chem. Int. Ed. 43 (2004) p. 749.CrossRefGoogle Scholar
35.Vaidhyanathan, R., Natarajan, S., and Rao, C.N.R., J. Chem. Soc., Dalton Trans. (2001) p. 699.CrossRefGoogle Scholar
36.Mellot-Draznieks, C., Newsam, J.M., Gorman, A.M., Freeman, C.M., and Férey, G., Angew. Chem. Int. Ed. 39 (2000) p. 2270.3.0.CO;2-A>CrossRefGoogle Scholar
37.Mellot-Draznieks, C., Girard, S., and Férey, G., J. Am. Chem. Soc. 124 (2002) p. 15326.CrossRefGoogle Scholar
38.Walawalkar, M.G., Roesky, H.W., Murugavel, R., Acc. Chem. Res. 32 (1999) p. 117.CrossRefGoogle Scholar
39.Vaidhyanathan, R., Natarajan, S., and Rao, C.N.R., Chem. Mater. 13 (2001) p. 3524.CrossRefGoogle Scholar
40.Masciocchi, N., Castelli, F., Forster, P.M., Tafoya, M.M., and Cheetham, A.K., Inorg. Chem. 42 (2003) p. 6147.CrossRefGoogle Scholar