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Li Ion Migration at the Interfaces

Published online by Cambridge University Press:  31 January 2011

Janko Jamnik  and
Miran Gaberscek
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Abstract

During the past decade, the electrochemical properties (energy density, power capability, and cycling stability) of practical lithium (Li) batteries have been enormously improved. Surprisingly, although the knowledge exists of how to prepare excellent batteries, a detailed understanding of how they actually work is still lacking. In particular, the impact of interfaces in electrode composites is poorly understood. Here, we collect the most advanced mechanistic studies performed in our laboratory or published in recent literature and try to embed this knowledge into the well-established concepts used in solid-state ionics for many decades. In particular, we focus on the so-called perpendicular and parallel interfacial effects. We show that much of the old wisdom can be applied to batteries, although there are several important differences. We discuss, in some detail, the effects of charge incorporation, electronic interphase contacting, electrode porosity, and heterogeneous doping in selected advanced electrode materials and emphasize the future perspectives.

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Type
Research Article
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MRS Bulletin , Volume 34 , Issue 12: Solid-State Ionics in the 21st Century , December 2009 , pp. 942 - 948
Copyright
Copyright © Materials Research Society 2009

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References

1Masquelier, C., Padhi, A.K., Nanjundaswamy, K.S., Goodenough, J.B., J. Solid State Chem. 135, 228 (1998).CrossRefGoogle Scholar
2Breger, J., Dupre, N., Chupas, P.J., Lee, P.L., Proffen, T., Parise, J.B., Grey, C.P., J. Am. Chem. Soc. 127, 7529 (2005).CrossRefGoogle Scholar
3Du, N., Zhang, H., Chen, B., Wu, J.B., Ma, X.Y., Liu, Y.H., Zhang, Y.Q., Yang, D., Huang, X.H., Tu, J.P., Adv. Mater 19, 4505 (2007).CrossRefGoogle Scholar
4Yamakawa, N., Jiang, M., Key, B., Grey, C.P., J. Am. Chem. Soc. 131, 10525 (2009).CrossRefGoogle Scholar
5Pop, N., Pralong, V., Caignaert, V., Colin, J.F., Malo, S., Van Tendeloo, G., Raveau, B., Chem. Mater. 21, 3242 (2009).CrossRefGoogle Scholar
6Gaberscek, M., Kuzma, M., Jamnik, J., Phys. Chem. Chem. Phys. 9, 1815 (2007).CrossRefGoogle Scholar
7Gaberscek, M., Moskon, J., Erjavec, B., Dominko, R., Jamnik, J., Electrochem. Solid State Lett. 11, A170 (2008).CrossRefGoogle Scholar
8Jamnik, J., Dominko, R., Erjavec, B., Remskar, M., Pintar, A., Gaberscek, M., Adv. Mater. 21, 2715 (2009).CrossRefGoogle Scholar
9Roberts, M.R., Spong, A.D., Vitins, G., Owen, J.R., J. Electrochem. Soc. 154, A921 (2007).CrossRefGoogle Scholar
10Roberts, M.R., Vitins, G., Owen, J.R., J. Power Sources 179, 754 (2008).CrossRefGoogle Scholar
11Bauerle, J.E., J. Phys. Chem. Solids 30, 2657 (1969).CrossRefGoogle Scholar
12Sata, N., Eberman, K., Eberl, K., Maier, J., Nature 408, 946 (2000).CrossRefGoogle Scholar
13Kim, S., Maier, J., J. Electrochem. Soc. 149, J73 (2002).CrossRefGoogle Scholar
14Jamnik, J., Maier, J., Phys. Chem. Chem. Phys. 5, 5215 (2003).CrossRefGoogle Scholar
15Maier, J., Jamnik, J., Leonhardt, M., Solid State Ionics 129, 25 (2000).CrossRefGoogle Scholar
16Lubomirsky, I., Fleig, J., Maier, J., J. Appl. Phys. 92, 6819 (2002).Google Scholar
17Waser, R., Hagenbeck, R., Acta Mater. 48, 797 (2000).CrossRefGoogle Scholar
18Maier, J., Angew. Chem. Int. Edit. 32, 313 (1993).CrossRefGoogle Scholar
19Maier, J., Angew. Chem. Int. Edit. 32, 528 (1993).CrossRefGoogle Scholar
20Kaiser, A.B., Adv. Mater. 13, 927 (2001).3.0.CO;2-B>CrossRefGoogle Scholar
21Jamnik, J., Maier, J., Solid State Ionics 119, 191 (1999).CrossRefGoogle Scholar
22Peled, E., J. Electrochem. Soc. 124, C270 (1977).CrossRefGoogle Scholar
23Dominko, R., Bele, M., Goupil, J.-M., Gaberscek, M., Hanzel, D., Remskar, M., Jamnik, J., Chem. Mater. 19, 2960 (2007).CrossRefGoogle Scholar
24Delmas, C., Maccario, M., Croguennec, L., Le Cras, F., Weill, F., Nat. Mater. 7, 665 (2008).CrossRefGoogle Scholar
25Takahashi, M., Tobishima, S., Takei, K., Sakurai, Y., Solid State Ionics 148, 283 (2002).CrossRefGoogle Scholar
26Wang, G.X., Yang, L., Chen, Y., Wang, J.Z., Bewley, S., Liu, H.K., Electrochim. Acta 50, 4649 (2005).CrossRefGoogle Scholar
27Bramnik, N.N., Nikolowski, K., Baehtz, C., Bramnik, K.G., Ehrenberg, H., Chem. Mater. 19, 908 (2007).CrossRefGoogle Scholar
28Yu, D.Y.W., Fietzek, C., Weydanz, W., Donoue, K., Inoue, T., Kurokawa, H., Fujitani, S., J. Electrochem. Soc. 154, A253 (2007).CrossRefGoogle Scholar
29Liao, X.-Z., Ma, Z.-F., He, Y.-S., Zhang, X.-M., Wang, L., Jiang, Y., J. Electrochem. Soc. 152, A1969 (2005).CrossRefGoogle Scholar
30Hong, J., Wang, C., Kasavajjula, U., J. Power Sources 162, 1289 (2006).CrossRefGoogle Scholar
31Kerlau, M., Kostecki, R., J. Electrochem. Soc. 153, A1644 (2006).CrossRefGoogle Scholar
32Shin, H.C., Cho, W.I., Jang, H., J. Power Sources 159, 1383 (2006).CrossRefGoogle Scholar
33Gaberscek, M., Dominko, R., Jamnik, J., Electrochem. Commun. 9, 2778 (2007).CrossRefGoogle Scholar
34Abe, T., Ogumi, Z., in Meeting Abstracts, The 14th International Meeting on Lithium Batteries (IMLB), TEDA/Tianjin, China, 22–28 June 2008, Abstract 65.Google Scholar
35Gaberscek, M., Jamnik, J., Solid State Ionics 177, 2647 (2006).CrossRefGoogle Scholar
36Levi, M.D., Salitra, G., Markovsky, B., Teller, H., Aurbach, D., Heider, U., Heider, L., J. Electrochem. Soc. 146, 1279 (1999).CrossRefGoogle Scholar
37Erjavec, B., Dominko, R., Umek, P., Sturm, S., Pejovnik, S., Gaberscek, M., Jamnik, J., Electrochem. Comm. 10, 926 (2008).CrossRefGoogle Scholar
38Erjavec, B., Dominko, R., Umek, P., Sturm, S., Pintar, A., Gaberscek, M., J. Power Sources 189, 869 (2009).CrossRefGoogle Scholar
39Liang, C.C., J. Electrochem. Soc. 120, 1289 (1973).CrossRefGoogle Scholar
40Yamada, A., Koizumi, H., Nishimura, S.I., Sonoyama, N., Kanno, R., Yonemura, M., Nakamura, T., Kobayashi, Y., Nat. Mater. 5, 357 (2006).CrossRefGoogle Scholar
41Poizot, P., Laruelle, S., Grugeon, S., Dupont, L., Tarascon, J.-M., Nature 407, 496 (2000).CrossRefGoogle Scholar
42Zhukovskii, Y.F., Balaya, P., Kotomin, E.A., Maier, J., Phys. Rev. Lett. 96, 058302 (2006).CrossRefGoogle Scholar
43Bhattacharyya, A.J., Maier, J., Adv. Mater. 16, 811 (2004).CrossRefGoogle Scholar
44Lee, Y.J., Yi, H., Kim, W.-J., Kang, K., Yun, D.S., Strano, M.S., Ceder, G., Belcher, A.M., Science 324, 1051 (2009).CrossRefGoogle Scholar