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CdSe Nanoparticle/Metal-Organic Inks For Printable Electronics

Published online by Cambridge University Press:  11 February 2011

Douglas L. Schulz*
Affiliation:
CeraMem Corporation, Waltham, MA 02453, U.S.A.
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Abstract

The research objective of this project was the spray deposition of CdSe films using a nanoparticle CdSe suspension as the precursor ink. This ink consisted of CdSe nanoparticles (nano-CdSe) mixed with a “reactive dispersant” in a non-aqueous solvent. The reactive dispersant, a metal-organic molecule, served two purposes; (1) to form a dispersed CdSe suspension at room temperature, and (2) to thermally “unzip” giving CdSe and a byproduct. The CdSe thereby formed could be deposited at the grain boundaries and serve to physically and electrically connect the CdSe nanoparticles at moderate, plastic-compatible temperatures. If electronics-grade CdSe layers could be produced at low deposition temperatures, this approach may be applicable to printed CdSe-based thin film field-effect transistors (TFTs) on flexible substrates.

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