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Electrodeposited Cu-In-Ga-Se Thin Films for CIGS-based Solar Cells

Published online by Cambridge University Press:  31 January 2011

Raghu Bhattacharya*
Affiliation:
raghu.bhattacharya@nrel.gov, National Renewable Energy Laboratory, 1617 Cole Boulevard, Golden, Colorado, 80401, United States
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Abstract

Cyclic voltammogram studies were performed on H2SeO3, CuSO4, In2(SO4)3, GaCl3, H2SeO3 + CuSO4 + In2(SO4)3 and H2SeO3 + CuSO4 + In2(SO4)3 + GaCl3 to understand the electrodeposition mechanism. The reduction potential from the cyclic voltammogram studies indicates that the first deposited layer is Cu from the Cu-In-Se and Cu-In-Ga-Se solution mixture. The subsequent deposition of the In and Ga layer is more favorable on the first-deposited Cu layer.

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