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A Grazing Incidence X-Ray Diffraction Study of Self-Assembled Monolayers

Published online by Cambridge University Press:  21 February 2011

P. Fenter,
Jun Li,
p. Eisenberger,
T. A. Ramanarayanan and
K. S. Liang
P. Fenter
Affiliation:
Dept. of Physics, Princeton Univ., Princeton N.J.Exxon Research and Engineering, Annandale N.J.
Jun Li
Affiliation:
Dept. of Chemistry, Princeton Univ., Princeton N.J.Exxon Research and Engineering, Annandale N.J.
p. Eisenberger
Affiliation:
Dept. of Physics, Princeton Univ., Princeton N.J.
T. A. Ramanarayanan
Affiliation:
Exxon Research and Engineering, Annandale N.J.
K. S. Liang
Affiliation:
Exxon Research and Engineering, Annandale N.J.
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Abstract

We describe the two dimensional structure of n-Alkyl Thiols, CH3(CH2 17SH(C18, self-assembled on the surfaces of Au(111) and Ag(111). By using Grazing Incidence X-ray Diffraction (GIXD), we show that C18 forms ordered and dense monolayers. Although the properties of Au and Ag are very similar (for instance, the lattice constants of Au an Ag are nearly identical), the structure of C18on these two substrates is very different.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 237: Symposium Ca – Interface Dynamics and Growth , 1991, 291
Copyright
Copyright © Materials Research Society 1992

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