Hostname: page-component-7b7567c8c-tnzcf Total loading time: 0 Render date: 2026-11-15T07:24:16.159Z Has data issue: false hasContentIssue false
  • English
  • Français

Growth of Reduced Graphene Oxide

Published online by Cambridge University Press:  09 September 2014

Jingfeng Huang,
Hu Chen,
Derrick Fam,
Steve H. Faulkner,
Wenbin Niu,
Melanie Larisika,
Christoph Nowak,
Myra A. Nimmo and
Alfred Iing Yoong Tok
Jingfeng Huang
Affiliation:
School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore. Tel.: +65 67904935.Institute for Sports Research, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore.School of Sport, Exercise and Health Sciences, Loughborough University, Leicestershire, LE113TU, UK.
Hu Chen
Affiliation:
School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore. Tel.: +65 67904935.Institute for Sports Research, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore.School of Sport, Exercise and Health Sciences, Loughborough University, Leicestershire, LE113TU, UK.
Derrick Fam
Affiliation:
School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore. Tel.: +65 67904935.
Steve H. Faulkner
Affiliation:
School of Sport, Exercise and Health Sciences, Loughborough University, Leicestershire, LE113TU, UK.
Wenbin Niu
Affiliation:
School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore. Tel.: +65 67904935.
Melanie Larisika
Affiliation:
Austrian Institute of Technology (AIT) GmbH, Donau-City Str.1, Vienna, 1220, Austria.Centre for Biomimetic Sensor Science, 50 Nanyang Drive, Singapore, 637553, Singapore.
Christoph Nowak
Affiliation:
Austrian Institute of Technology (AIT) GmbH, Donau-City Str.1, Vienna, 1220, Austria.Centre for Biomimetic Sensor Science, 50 Nanyang Drive, Singapore, 637553, Singapore.
Myra A. Nimmo
Affiliation:
Institute for Sports Research, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore.School of Sport, Exercise and Health Sciences, Loughborough University, Leicestershire, LE113TU, UK.
Alfred Iing Yoong Tok*
Affiliation:
School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore. Tel.: +65 67904935.Institute for Sports Research, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore.
*
*E-mail address: miytok@ntu.edu.sg.
Get access

Abstract

Reduced graphene oxide (RGO) has the advantage of an aqueous and industrial-scalable production route. However, one of the main limitations that prevent the use of RGO in electronics is the high electrical resistance deviation between fabricated chips. In this article, we present the novel growth of RGO which can bridge the gaps in-between existing flakes and thus reduce the electrical resistance standard deviation from 80.5 % to 16.5 %. The average resistivity of the treated RGO of ∼ 3.8 nm thickness was 200 Ω/square. The study uses an atmospheric-pressure chemical vapour deposition (CVD) system with hydrogen and argon gas bubbling through ethanol before entering the furnace. With a treatment of 2 hours, 100 % of the silicon dioxide substrate was covered with RGO from an initial 65 % coverage. This technology could enable large-scale application of RGO use in practical electronic devices.

Keywords

Cchemical vapor deposition (CVD) (deposition)electrical properties

Information

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1702: Symposium OO – De Novo Graphene , 2014, mrss14-1702-oo20-05
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

Stankovich, S., Dikin, D. A., Piner, R. D., Kohlhaas, K. A., Kleinhammes, A., Jia, Y., et al. ., “Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide,” Carbon, vol. 45, pp. 1558–1565, 6// 2007.CrossRefGoogle Scholar
Dreyer, D. R., Park, S., Bielawski, C. W., and Ruoff, R. S., “The chemistry of graphene oxide,” Chemical Society Reviews, vol. 39, pp. 228–240, 2010.CrossRefGoogle ScholarPubMed
Loh, K. P., Bao, Q., Eda, G., and Chhowalla, M., “Graphene oxide as a chemically tunable platform for optical applications,” Nat Chem, vol. 2, pp. 1015–1024, 12//print 2010.CrossRefGoogle ScholarPubMed
Eda, G., Fanchini, G., and Chhowalla, M., “Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material,” Nat Nano, vol. 3, pp. 270–274, 05//print 2008.CrossRefGoogle ScholarPubMed
Li, X., Cai, W., An, J., Kim, S., Nah, J., Yang, D., et al. ., “Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils,” Science, vol. 324, pp. 1312–1314, June 5, 2009 2009.CrossRefGoogle ScholarPubMed
Li, X., Cai, W., Colombo, L., and Ruoff, R. S., “Evolution of Graphene Growth on Ni and Cu by Carbon Isotope Labeling,” Nano Letters, vol. 9, pp. 4268–4272, 2009/12/09 2009.CrossRefGoogle ScholarPubMed
Kim, K. S., Zhao, Y., Jang, H., Lee, S. Y., Kim, J. M., Kim, K. S., et al. ., “Large-scale pattern growth of graphene films for stretchable transparent electrodes,” Nature, vol. 457, pp. 706–710, 02/05/print 2009.CrossRefGoogle ScholarPubMed
Gunho, J., Minhyeok, C., Chu-Young, C., Jin Ho, K., Woojin, P., Sangchul, L., et al. ., “Large-scale patterned multi-layer graphene films as transparent conducting electrodes for GaN light-emitting diodes,” Nanotechnology, vol. 21, p. 175201, 2010.Google Scholar
Kim, K. S., Zhao, Y., Jang, H., Lee, S. Y., Kim, J. M., Kim, K. S., et al. ., “Large-scale pattern growth of graphene films for stretchable transparent electrodes,” Nature, vol. 457, pp. 706–710, // 2009.CrossRefGoogle ScholarPubMed
Yao, Y., Feng, C., Zhang, J., and Liu, Z., ““Cloning” of Single-Walled Carbon Nanotubes via Open-End Growth Mechanism,” Nano Letters, vol. 9, pp. 1673–1677, 2009/04/08 2009.CrossRefGoogle ScholarPubMed
Gong, C., Acik, M., Abolfath, R. M., Chabal, Y., and Cho, K., “Graphitization of Graphene Oxide with Ethanol during Thermal Reduction,” The Journal of Physical Chemistry C, vol. 116, pp. 9969–9979, 2012/05/10 2012.CrossRefGoogle Scholar
Su, C.-Y., Xu, Y., Zhang, W., Zhao, J., Liu, A., Tang, X., et al. ., “Highly Efficient Restoration of Graphitic Structure in Graphene Oxide Using Alcohol Vapors,” ACS Nano, vol. 4, pp. 5285–5292, 2010/09/28 2010.CrossRefGoogle ScholarPubMed
Larisika, M., Huang, J., Tok, A., Knoll, W., and Nowak, C., “An improved synthesis route to graphene for molecular sensor applications,” Materials Chemistry and Physics, vol. 136, pp. 304–308, 2012.CrossRefGoogle Scholar
Su, C.-Y., Xu, Y., Zhang, W., Zhao, J., Tang, X., Tsai, C.-H., et al. ., “Electrical and Spectroscopic Characterizations of Ultra-Large Reduced Graphene Oxide Monolayers,” Chemistry of Materials, vol. 21, pp. 5674–5680, 2009/12/08 2009.CrossRefGoogle Scholar
Huang, J., Larisika, M., Nowak, C., and Tok, I. Y. A., New Methods in Aqueous Graphene (Graphene Oxide) Synthesis for Biosensor Devices vol. 1: Taylor & Francis Group, 2013, Submitted.Google Scholar
Huang, J., Harvey, J., Chen, H., Fam, W. H. D., Nimmo, M. A., and Tok, I. Y. A., “Complete coverage of reduced graphene oxide on silicon dioxide substrates,” Chinese Physics B, 2014.Google Scholar
Huang, J., Larisika, M., Fam, W. H. D., He, Q., Nimmo, M. A., Nowak, C., et al. ., “The extended growth of graphene oxide flakes using ethanol CVD,” Nanoscale, vol. 5, pp. 2945–2951, 2013.CrossRefGoogle ScholarPubMed
Faulkner, S., Spilsbury, K., Harvey, J., Jackson, A., Huang, J., Platt, M., et al. ., “The detection and measurement of interleukin-6 in venous and capillary blood samples, and in sweat collected at rest and during exercise,” European Journal of Applied Physiology, pp. 1–10, 2014/03/01 2014.Google ScholarPubMed
Huang, J., Harvey, J., Chen, H., Nimmo, M. A., and Tok, I. Y. A., “Fully Organic Graphene Oxide-based Sensor with Integrated Pump for Sodium Detection,” in Conference Proceeding of icSports, Vilamoura, Portugal, 2013, pp. 83–88.Google Scholar
Huang, J., Harvey, J., Fam, W. H. D., Nimmo, M. A., and Tok, I. Y. A., “Novel Biosensor for InterLeukin-6 Detection,” Procedia Engineering, vol. 60, pp. 195–200, // 2013.CrossRefGoogle Scholar
Huang, J., Fam, D., He, Q., Chen, H., Zhan, D., Faulkner, S. H., et al. ., “The mechanism of graphene oxide as a growth template for complete reduced graphene oxide coverage on an SiO2 substrate,” Journal of Materials Chemistry C, vol. 2, pp. 109–114, 2014.CrossRefGoogle Scholar
, D. Fam, W. H., Palaniappan, A., Tok, A. I. Y., Liedberg, B., and Moochhala, S. M., “A review on technological aspects influencing commercialization of carbon nanotube sensors,” Sensors and Actuators B: Chemical, vol. 157, pp. 1–7, 9/20/ 2011.CrossRefGoogle Scholar
Leggate, M., Nowell, M. A., Jones, S. A., and Nimmo, M. A., “The response of interleukin-6 and soluble interleukin-6 receptor isoforms following intermittent high intensity and continuous moderate intensity cycling,” Cell Stress Chaperones, vol. 15, pp. 827–33, Nov 2010.CrossRefGoogle ScholarPubMed
, D. Fam, W. H., Tok, A. I. Y., Palaniappan, A., Nopphawan, P., Lohani, A., and Mhaisalkar, S. G., “Selective sensing of hydrogen sulphide using silver nanoparticle decorated carbon nanotubes,” Sensors and Actuators B: Chemical, vol. 138, pp. 189–192, 4/24/ 2009.CrossRefGoogle Scholar
Gray, S. R., Clifford, M., Lancaster, R., Leggate, M., Davies, M., and Nimmo, M. A., “The response of circulating levels of the interleukin-6/interleukin-6 receptor complex to exercise in young men,” Cytokine, vol. 47, pp. 98–102, Aug 2009.CrossRefGoogle ScholarPubMed