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Interfacial Reactions Between Titanium and Borate Glass

Published online by Cambridge University Press:  15 February 2011

R. K. Brow,
S. K. Saha and
J. I. Goldstein
R. K. Brow
Affiliation:
Sandia National Labs, Dept. 1845, Albuquerque, NM 87185
S. K. Saha
Affiliation:
Lehigh University, Dept. of Materials Science, Bethlehem, PA 18015
J. I. Goldstein
Affiliation:
Lehigh University, Dept. of Materials Science, Bethlehem, PA 18015
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Abstract

Interfacial reactions between the melts of several borate glasses and titanium have been investigated by analytical scanning electron microscopy (ASEM) and by x-ray photoelectron spectroscopy (XPS). A thin titanium boride interfacial layer is detected by XPS after short (30 minutes) thermal treatments. ASEM analyses after longer thermal treatments (8–120 hours) reveal boron-rich interfacial layers and boride precipitates in the Ti side of the interface.

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