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Macroporous Carbon Monoliths with Large Surface Area for Electric Double-Layer Capacitor

Published online by Cambridge University Press:  21 March 2011

George Hasegawa,
Mami Aoki,
Kazuyoshi Kanamori,
Kazuki Nakanishi,
Teiichi Hanada and
Kiyoharu Tadanaga
George Hasegawa
Affiliation:
Department of Chemistry, Graduate School of Science, Kyoto University Kitashirakawa, Sakyo-ku, Kyoto, 606-8502, Japan
Mami Aoki
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University Sakai, Osaka, 599-8531, Japan
Kazuyoshi Kanamori
Affiliation:
Department of Chemistry, Graduate School of Science, Kyoto University Kitashirakawa, Sakyo-ku, Kyoto, 606-8502, Japan
Kazuki Nakanishi
Affiliation:
Department of Chemistry, Graduate School of Science, Kyoto University Kitashirakawa, Sakyo-ku, Kyoto, 606-8502, Japan
Teiichi Hanada
Affiliation:
Department of Chemistry, Graduate School of Science, Kyoto University Kitashirakawa, Sakyo-ku, Kyoto, 606-8502, Japan
Kiyoharu Tadanaga
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University Sakai, Osaka, 599-8531, Japan
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Abstract

Macro/meso/microporous carbon monoliths doped with sulfur have been prepared from sulfonated polydivinylbenzene networks followed by the activation with CO2 resulted in the activated carbon monoliths with high surface area of 2400 m2 g−1. The monolithic electrode of the activated carbon shows remarkably high specific capacitance (175 F g−1 at 5 mV s−1 and 206 F g−1 at 0.5 A g−1).

Keywords

carbonizationelectronic materialpolymerization

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References

REFERENCES

1.Hu, Y.-S., Adelhelm, P., Smarsly, B. M., Hore, S., Antonietti, M., and Maier, J., Adv. Funct. Mater. 17, 1873 (2007).CrossRefGoogle Scholar
2.Thomas, K. M., Catal. Today 120, 389 (2007).CrossRefGoogle Scholar
3.Simon, P. and Gogotsi, Y., Nature Mater. 7, 845 (2008).CrossRefGoogle Scholar
4.Zhang, L. L. and Zhao, X. S., Chem. Soc. Rev. 38, 2520 (2009).CrossRefGoogle Scholar
5.Salitra, G., Soffer, A., Ehad, L., Cohen, Y., and Aurbach, D., J. Electrochem. Soc. 147, 2486 (2000).CrossRefGoogle Scholar
6.Barbieri, O., Hahn, M., Herzog, A., and Kötz, R., Carbon 43, 1303 (2005).CrossRefGoogle Scholar
7.Shiraishi, S., Kurihara, H., Shi, L., Nakayama, T., and Oya, A., J. Electrochem. Soc. 149, A855 (2002).CrossRefGoogle Scholar
8.Largeot, C., Portet, C., Chmiola, J., Taberna, P. L., Gogotsi, Y., and Simon, P., J. Am. Chem. Soc. 130, 2730 (2008).CrossRefGoogle Scholar
9.Brun, N., Prabaharan, S. R. S., Morcrette, M., Sanchez, C., Pécastaings, G., Derré, A., Soum, A., Deleuze, H., Birot, M., and Backov, R., Adv. Funct. Mater. 19, 3136 (2009).CrossRefGoogle Scholar
10.Ruiz, V., Blanco, C., Santamaría, R., Ramos-Fernández, J. M., Martínez-Escandell, M., Sepúlveda-Escribano, A., and Rodrígez-Reinoso, F., Carbon 47, 195 (2009).CrossRefGoogle Scholar
11.Lee, J., Yoon, S., Hyeon, T., Oh, S. M., and Kim, K. B., Chem. Commun. 21, 2177 (1999).CrossRefGoogle Scholar
12.Liu, B., Shioyama, H., Jiang, H., Zhang, X., and Xu, Q., Carbon 48, 456 (2010).CrossRefGoogle ScholarPubMed
13.Wang, D. W., Li, F., Liu, M., Lu, G. Q., and Cheng, H. M., Angew. Chem. Int. Ed. 47, 373 (2008).CrossRefGoogle Scholar
14.Woo, S. W., Dokko, K., Nakano, H., and Kanamura, K., J. Mater. Chem. 18, 1674 (2008).CrossRefGoogle Scholar
15.Hasegawa, J., Kanamori, K., Nakanishi, K., Hanada, T., and Yamago, S., Macromolecules 42, 1270 (2009).CrossRefGoogle Scholar
16.Hasegawa, J., Kanamori, K., Nakanishi, K., and Hanada, T., C. R. Chimie 13, 207 (2010).CrossRefGoogle Scholar
17.Hasegawa, G., Kanamori, K., Nakanishi, K., and Hanada, T., Carbon 48, 1757 (2010).CrossRefGoogle Scholar
18.Neely, J. W., Carbon 19, 27 (1981).CrossRefGoogle Scholar
19.Toyoda, M., Tani, U., and Soneda, Y., Carbon 42, 2833 (2004).CrossRefGoogle Scholar
20.Kim, Y. T. and Mitani, T., J. Power Sources 158, 1517 (2006).CrossRefGoogle Scholar