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Mesoporous Hybrid Thin Films: Building Blocks for Complex Materials with Spatial Organization

Published online by Cambridge University Press:  17 March 2011

Galo J. Soler-Illia,
Paula C. Angelomé,
M. Cecilia Fuertes,
Alejandro Wolosiuk,
Sara A. Bilmes,
Francisco Javier López-Alcaraz and
Hernán Míguez
Galo J. Soler-Illia
Affiliation:
UAQ, CNEA, CAC-Av Gral Paz 1499, San Martín, B1650KNA, Argentina
Paula C. Angelomé
Affiliation:
UAQ, CNEA, CAC-Av Gral Paz 1499, San Martín, B1650KNA, Argentina
M. Cecilia Fuertes
Affiliation:
UAQ, CNEA, CAC-Av Gral Paz 1499, San Martín, B1650KNA, Argentina
Alejandro Wolosiuk
Affiliation:
UAQ, CNEA, CAC-Av Gral Paz 1499, San Martín, B1650KNA, Argentina
Sara A. Bilmes
Affiliation:
DQIAyQF and INQUIMAE, Univ. of Buenos Aires, Ciudad Universitaria, Pabellón II, Buenos Aires, C1428EHA, Argentina
Francisco Javier López-Alcaraz
Affiliation:
Instituto de C de Materiales de Sevilla, CSIC, Av. A. Vespucio s/n, Isla de la Cartuja, Sevilla, 41092, Spain
Hernán Míguez
Affiliation:
Instituto de C de Materiales de Sevilla, CSIC, Av. A. Vespucio s/n, Isla de la Cartuja, Sevilla, 41092, Spain
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Abstract

Mesoporous Hybrid Thin Films (MHTF) of a variety of compositions and embedded organic functions are produced by combining sol-gel synthesis, template self-assembly and surface modification. One-pot or post-grafting strategies permit to modify the pore surface behavior. Highly controlled MHTF issued from a reproducible and modular synthesis can be used as building blocks for more complex structures, presenting order at larger scales, and novel properties derived from this multiscale order. Multilayer stacks of MHTF presenting specific and different functions and frameworks located in a well-defined position have been produced by combining sequential film deposition, selective functionalization and dissolution. These systems present new properties such as localized chemistry or modulable photonic crystal behavior.

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References

REFERENCES

1.a) See the Special Issue fiFunctional Hybrid Materialsfl, J. Mater. Chem. 2005, 15, 3557ss.Google Scholar
b) Soler-Illia, G. J. A. A., Innocenzi, P., Chem. Euro. J., 2006, 12, 4478.Google Scholar
2.a) Liu, N., Assink, R. A., Smarsly, B., Brinker, C.J., Chem. Commun. 2003, 1146;Google Scholar
b) Liu, N., Dunphy, D.R., Atanassov, P., Bunge, S.D., Chen, Z., López, G. P., Boyle, T.J., Brinker, C.J., Nano. Lett. 2004, 4, 551;Google Scholar
b) Petkov, N., Mintova, S., Jean, B., Metzger, T., Bein, T., Mat. Sci. Eng. C 2003, 23, 827.Google Scholar
3. Gibaud, A., Bardeau, J.-F., Dutreilh-Colas, M., Bellour, M., Balasubramanian, V. V., Robert, A., Mehdi, A., Reyé, C. and Corriu, R. J., J. Mater. Chem., 2004, 14, 1854.Google Scholar
4. Cagnol, F., Grosso, D., Sanchez, C., Chem. Commun. 2004, 1742.Google Scholar
5. Soler-Illia, G.J.A.A., Angelomé, P. C., Bozzano, P., Chem. Commun., 2004, 2854.Google Scholar
6.a) Crepaldi, E. L., Soler-Illia, G.J.A.A., Grosso, D., Albouy, P.-A., Sanchez, C.., Chem. Commun., 2001, 1582.Google Scholar
b) Angelomé, P. C., Aldabe-Bilmes, S., Calvo, M. E., Crepaldi, E. L., Grosso, D., Sanchez, C., Soler-Illia, G.J.A.A., New J. Chem., 2005, 29, 59.Google Scholar
7. Lee, A. Van der, Solid State Sci. 2000, 2, 157.Google Scholar
8.a) Grosso, D., Cagnol, F., Soler-Illia, G. J. A. A., Crepaldi, E. L., Amenitsch, H., BrunetBruneau, A., Bourgeois, A., Sanchez, C., Adv. Funct. Mater., 2004, 14, 309.Google Scholar
b) Angelomé, P. C., Andrini, L., Calvo, M. E., Requejo, F. G., Bilmes, S. A., Soler-Illia, G. J. A. A. J. Phys. Chem. C, 2007, 111, 10886.Google Scholar
9. Kim, T.-W., Ryoo, R., Kruk, M., Gierszal, K. P., Jaroniec, M., Kamiya, S., Terasaki, O., J. Phys. Chem. B 2004, 108, 11480.Google Scholar
10. Angelomé, P. C., Soler-Illia, G. J. A. A., Chem. Mater., 2005, 17, 322–331.Google Scholar
11.a) Song, C., Villemure, G., Microporous Mesoporous Mater., 2001, 44–45, 679.Google Scholar
b) Etienne, M., Quach, A., Grosso, D., Nicole, L., Sanchez, C., Walcarius, A., Chem. Mater. 2007, 19, 844.Google Scholar
12. Otal, E. H., Angelomé, P. C., Aldabe-Bilmes, S., Soler-Illia, G.J.A.A., Adv. Mater., 2006, 18, 934.Google Scholar
13. Grosso, D., Soler-Illia, G.J.A.A., Crepaldi, E., Cagnol, F., Sinturel, C., Bourgeois, A., Brunet-Bruneau, A., Amenitsch, H., Albouy, P.-A., Sanchez, C., Chem. Mater. 2003, 15, 4562.Google Scholar
14. Sakatani, Y., Grosso, D., Nicole, L., Boissière, C., Soler-Illia, G. J. A. A., Sanchez, C.. J. Mater. Chem., 2006, 16, 77.Google Scholar
15. Crepaldi, E. L., Soler-Illia, G.J.A.A., Grosso, D., Sanchez, C., New J. Chem., 2003, 27, 9.Google Scholar
16.a) Liu, J., Shin, Y., Nie, Z., Chang, J. H., Wang, L.-Q., Fryxell, G. E., Samuels, W. D., Exarhos, G. J., J. Phys. Chem. A 2000, 104, 8328.Google Scholar
b) Notestein, J.M., Katz, A., Chem. Euro. J. 2006, 12, 3854.Google Scholar
17. Calvo, A., Angelomé, P.C., Williams, F. J., Soler-Illia, G.J.A.A., to be published. Google Scholar
18.a) Bronstein, L., Top. Curr. Chem., 2003, 226, 55.Google Scholar
b) Shi, J.L., Hua, Z. L., Zhang, L.X., J. Mater. Chem. 2004, 14, 795.Google Scholar
19. Perez, M. D., Otal, E., Bilmes, S. A., Soler-Illia, G., Crepaldi, E. L., Grosso, D. and Sanchez, C., Langmuir, 2004, 20, 6879.Google Scholar
20. Wang, D., Luo, H., Kou, R., Gil, M. P., Xiao, S., Golub, V. O., Yang, Z., Brinker, C. J. and Lu, Y., Angew. Chem. - Int. Ed., 2004, 43, 6169.Google Scholar
21. Mallory, G. O. and Hajdu, J. B., Electroless Plating: Fundamentals and Applications, American Electroplaters and Surface Finishers Society, Florida, 1990.Google Scholar
22. Kumai, Y., Tsukada, H., Akimoto, Y., Sugimoto, N., Seno, Y., Fukuoka, A. T., Ichikawa, M. and Inagaki, S., Adv. Mater., 2006, 18, 760.Google Scholar
23. Huang, M. H., Choudrey, A. and Yang, P., Chem. Commun., 2000, 1063.Google Scholar
24. Besson, S., Gacoin, T., Ricolleau, C. and Boilot, J. P., Chem. Commun., 2003, 360.Google Scholar
25. Fuertes, M. C., Wolosiuk, A. and Soler-Illia, G. J. A. A., to be published. Google Scholar
26. Mulvaney, P., MRS Bull 2001, 1009.Google Scholar
27. Tognalli, N., Fainstein, A., Wolosiuk, A., Bilmes, S.A., Soler-Illia, G.J.A.A., to be published.Google Scholar
28. Angelomé, P. C., Fuertes, M. C., Soler-Illia, G. J. A. A., Adv. Mater., 2006, 18, 2397.Google Scholar
29. Choi, S.Y., Mamak, M., Freymann, G. von, Chopra, N., Ozin, G.A., Nano Lett. 2006, 6, 2456.Google Scholar
30. Fuertes, M. C., López-Alcaraz, F. J., Marchi, M.C., Troiani, H., Luca, V., Míguez, H., Soler-Illia, G. J. A. A., Adv. Funct. Mater., 2007, 17, 1247.Google Scholar