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Mixed Ionic Electronic Conduction in Solids

Published online by Cambridge University Press:  28 February 2011

I. Riess
I. Riess*
Affiliation:
Physics Department, Technion, Haifa 32000, Israel
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Abstract

Chemical diffusion in mixed ionic electronic conductors (MIECs) occurs via ambipolar motion. It finds many applications which are reviewed. The partial ionic and electronic conductivities are also of interest. Methods for determining these quantities are reviewed emphasizing problems with the Hebb-Wagner polarization method and suggesting an alternative method. The use of MIECs for probing simultaneously the ionic and electronic driving forces and for producing p-n junctions is discussed.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 210: Symposium L – Solid State Ionics II , 1990, 529
Copyright
Copyright © Materials Research Society 1991

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References

1) Riess, I. and Tanuhauser, D.S., in: High Solid Ionic Conductors, Recent Trends and Applications, Takahashi, T. ed. (Word Scientific, 1989); pp. 478–512.Google Scholar
2) Maier, J., Murugaraj, P., Pfundtner, G. and Sitte, W., Ber. Bunsenges. Phys. Chem. 93, 1350 (1989).Google Scholar
3) Porat, O., Riess, I. and Tuller, H.L. to be published.Google Scholar
4) Whittingham, M.S., Solid State Ionic Devices, Chowdari, B.V.R. and Radhakrishna, S. eds. (World Scientific, 1988), pp. 55–74.Google Scholar
5) Goldner, R.B., in: Solid State Ionic Devices Chowdari, B.V.R. and Radhakrishna, S. eds. (World Scientific, 1988), pp. 379–388.Google Scholar
6) Rickert, H., Electrochemistry of Solids, (Springer-Verlag, 1982), pp. 157–167.Google Scholar
7) Schmalzried, H., Solid State Reactions, (Verlag Chemie, 1981), pp. 221–226.Google Scholar
8) Libowitz, G.G., The Solid State Chemistry of Binary Metal Hydrides, (W.A. Benjamin Inc. 1965), p. 6.Google Scholar
9) Ricken, M., Nölting, J. and Riess, I., J. Solid State Chem. 54, 89–99 (1984).Google Scholar
10) Ban, Y. and Nowick, A.S., NBS Special Pub. N. 364, pp. 353–365 (1972).Google Scholar
11) Goto, K.S., Solid State Electrochemistry and its Applications to Sensors and Electronic Devices, (Elsevier, 1988), pp. 336–348.Google Scholar
12) Volkenshtein, F.F., The Electronic Theory of Catalysis on Semiconductors, (Pergam Press, 1963), pp. 63–70.Google Scholar
13) Takahashi, T. in Physics of Electrolytes, Vol. 2, Hladik, J. ed. (Academic Press 1972), pp. 989–1049.Google Scholar
14) Tannhauser, D.S., J. Electrochem. Soc. 125, 1277 (1978).Google Scholar
15) Riess, I., J. Electrochem: Soc. 128, 2077 (1981).Google Scholar
16) Siffert, P. and Coche, A., in; Semiconductor Detectors, Bertolini, G. and Coche, A. eds. (North-Holland 1968), pp. 27–52. A. Coche and P. Siffert, pp. 149-185.Google Scholar
17) Choi, G.M., Tuller, H.L. and Tsai, M.J., in: Non Stoichiometric Compounds, Nowotny, J. and Weppner, W. eds. (Kulwer Acad. Pub. 1989), pp. 451–470.Google Scholar
18) Jones, C.L., Quelch, M.J.T., Capper, P. and Gosney, J.J.G., J. Appl. Phys. 53, 9080 (1982).Google Scholar
19) Chiang, Y.M., Kingery, W.D. and Levinson, C.M., J. Appl. Phys. 53, 1765 (1982).Google Scholar
20) Allen, L.A. and Bunks, E., J. Appl. Phys. 56, 15 (1984).Google Scholar
21) Whittingham, M.S., in: Proc. of the Intern. Seminar on Solid State Ionic Devices 18-23 July 1988, Clowdari, B.V.R. and Radhakrishna, S. eds. (World Scientific, 1988), pp. 55–74.Google Scholar
22) Rickert, H., Electrochemistry of Solids (Springer Verlag 1982) pp. 84–91.Google Scholar
23) Wagner, C., Z. Elektrochem. 60, 4 (1956).Google Scholar
24) Hebb, M.H.., J. Chem. Phys. 20, 185 (1952).CrossRefGoogle Scholar
25) Heine, L., in: Solid Electrolytes, Geller, S. ed. (Springer Verlag 1977), pp. 202–217.Google Scholar
26) Tubandt, C., Z. Anorg. Allgem. Chem. 115, 105 (1921) C. Tubandt, H. Reinhold and G. Liebold 197, 225 (1931).CrossRefGoogle Scholar
27) Weppner, W. and Huggins, R.A., Ann. Rev. Mater. Sci. 8, 269 (1978).Google Scholar
28) Rickert, H., Electrochemistry of Solids, Springer-Verlag, 1982, p. 102.Google Scholar
29) Riess, I., Solid State Ionic, 44, (1990) (in print).Google Scholar
30) Riess, I., Solid State Ionic, (in print).Google Scholar
31) Riess, I. and Tannhauser, D.S., Solid State Ionics 7, 307–315 (1982).Google Scholar
32) Mizusaki, J., Fueki, K. and Mukaibo, T. Bull. Chem. Soc. Japan, 48, 428 (1975).Google Scholar
33) Riess, I., J. Phys. Chem. Solids, 47, 129 (1986).Google Scholar
34) Riess, I., Phys. Rev. B35, 5740 (1987).Google Scholar