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A New Microporous Silicate With 12-Ring Channels

Published online by Cambridge University Press:  18 March 2011

Jacques Plévert
Affiliation:
Dept of Chemical System Engineering, The University of Tokyo, Tokyo 113-8656, JapanE-mail: JPlevert@asu.edu
Yoshihiro Kubota
Affiliation:
Dept of Chemistry, Faculty of Engineering, Gifu University, Gifu 501-1193, JapanE-mail: kubota@apchem.gifu-u.ac.jp
Takahisa Honda
Affiliation:
Dept of Chemistry, Faculty of Engineering, Gifu University, Gifu 501-1193, Japan
Tatsuya Okubo
Affiliation:
Dept of Chemical System Engineering, The University of Tokyo, Tokyo 113-8656, Japan
Yoshihiro Sugi
Affiliation:
Dept of Chemistry, Faculty of Engineering, Gifu University, Gifu 501-1193, Japan
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Abstract

A new molecular sieve GUS-1 is synthesized under hydrothermal conditions using a new organic compound acting as structure-directing agent. The structure determination reveals a framework with one-dimensional 12-membered ring channels running parallel. The structure exhibits the same channel net as zeolite ZSM-12 and shows the same projection of the framework along the pores as mordenite.

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