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A New Templating Route to Ordered Mesoporous Materials

Published online by Cambridge University Press:  28 February 2011

Peter T. Tanev and
Thomas J. Pinnavaia
Peter T. Tanev
Affiliation:
Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824
Thomas J. Pinnavaia
Affiliation:
Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824
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Abstract

A new templating route to ordered mesoporous materials is demonstrated based on hydrogen bonding interactions and self-assembly between neutral primary amine surfactants (S°) and neutral inorganic precursors (1°). The S° I° templating pathway affords ordered mesoporous materials with thicker framework walls, smaller X-ray scattering domain sizes, and substantial textural mesoporosities in comparison to MCM-41 materials templated with quaternary ammonium cations. This synthetic strategy also allows for the facile, environmentally benign recovery of the cost-intensive template by simple solvent extraction methods.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 371: Symposium W1 – Advances in Porous Materials , 1994, 63
Copyright
Copyright © Materials Research Society 1995

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References

References and Notes

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