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Phase transition in non-crystalline solids viewed from heating

Published online by Cambridge University Press:  21 February 2011

K. Nakayama,
K. Kojima,
N. Takahashi,
Y. Masaki,
A. Kitagawa and
M. Suzuki
K. Nakayama
Affiliation:
Division of Radiology School of Allied Medical Professions, Kanazawa University, Kanazawa 920, Japan
K. Kojima
Affiliation:
Division of Radiology School of Allied Medical Professions, Kanazawa University, Kanazawa 920, Japan
N. Takahashi
Affiliation:
Department of Electrical and Computer Engineering, Faculty of Technology, Kanazawa University, Kanazawa 920, Japan
Y. Masaki
Affiliation:
Department of Electrical and Computer Engineering, Faculty of Technology, Kanazawa University, Kanazawa 920, Japan
A. Kitagawa
Affiliation:
Department of Electrical and Computer Engineering, Faculty of Technology, Kanazawa University, Kanazawa 920, Japan
M. Suzuki
Affiliation:
Department of Electrical and Computer Engineering, Faculty of Technology, Kanazawa University, Kanazawa 920, Japan
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Abstract

The heating-rate dependence of crystallization temperature, Tc, and the glass transition temperature, Tg, is studied from the view points of nucleation and fragmentation processes in disordered structures. Tc and Tg are expected to increase monotonically with heating rate. Such behaviors of Tc and Tg are classified into four characteristic regions with respect to the heating rate. Results are summarized in the Transient Phase Diagram where Tc and Tg are given as a function of heating rate. The scaling rule in the Transient Phase Diagram is given.

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References

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