Hostname: page-component-7b7567c8c-2rsb6 Total loading time: 0 Render date: 2026-11-13T12:37:29.071Z Has data issue: false hasContentIssue false
  • English
  • Français

Structural Dynamics of Polymer Electrolytes

Published online by Cambridge University Press:  28 February 2011

G-A. Nazri,
D.M. MacArthur and
J.F. O'Gara
G-A. Nazri
Affiliation:
General Motors Research Laboratories, Warren, MI 48090 and Ricardo Aroca, Chemistry Department, University of Windsor, Ontario N9B 3P4, Canada
D.M. MacArthur
Affiliation:
General Motors Research Laboratories, Warren, MI 48090 and Ricardo Aroca, Chemistry Department, University of Windsor, Ontario N9B 3P4, Canada
J.F. O'Gara
Affiliation:
General Motors Research Laboratories, Warren, MI 48090 and Ricardo Aroca, Chemistry Department, University of Windsor, Ontario N9B 3P4, Canada
Get access

Abstract

The structure of polyethylene oxide doped with lithium perchlorate was studied. The macroscopic structure of the polymer-salt complexes was studied by thermal analysis and xray diffraction. The microscopic structure and polymer dynamics were studied by infrared, Raman and nuclear magnetic resonance spectroscopy. Thermal analysis and x-ray diffraction studies clearly revealed the change of crystalline phase to an amorphous phase by the addition of salt. The vibrational analysis showed a conformational transformation of the polymer chain by the addition of salt. Vibrational analysis also showed clearly the formation of free ion, ion-pair and salt cluster in the polymer as the concentration of the salt increased.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 210: Symposium L – Solid State Ionics II , 1990, 163
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

1. Wright, P.V., Br. Polym. J. 7, 319 (1975).CrossRefGoogle Scholar
2. Wright, P.V. J. Polym. Sci., Polym. Phys. 14, 955 (1976).CrossRefGoogle Scholar
3. Fenton, D. E., Parker, J. M., Wright, P. V. Polymer, 14, 589 (1973).CrossRefGoogle Scholar
4. Armand, M.B., Chabagno, J. M., and Duclot, M., Extended Abstract, Second International Conference on solid Electrolytes, St. Andrews, Scotland, 1978.Google Scholar
5. Armand, M.B., Chabagno, J. M., and Duclot, M., In Fast ion Transport in Solids, Duclot, M J, Vashishta, P., Mundy, J. N. and Shenoy, G. K.; Eds.; North Holland: Amsterdam, 1979.Google Scholar
6. Blonsky, P. M., Shriver, D. F., Austin, P. and allcock, H. R., J. Am. Chem. Soc., 106, 6854 (1984).CrossRefGoogle Scholar
7. Shriver, D. F. and Farrington, G. C., Chemical and Engineering News, Special Report, May 20, 1985.Google Scholar
8. Kobayashi, N., Uchiyama, M. and Tsuchida, E., Solid State lonics, 17, 307 (1985).CrossRefGoogle Scholar
9. Armand, M., Ann. Rev. Mater. Sci. 16, 245 (1986).CrossRefGoogle Scholar
10. Ratner, M. A. and Shriver, D. F., Chem. Rev. 88, 109 (1988).CrossRefGoogle Scholar
11. Nazri, G-A., Meibuhr, S. G., J. Electrochem. Soc., 136, 2450 (1989).CrossRefGoogle Scholar
12. Nazri, G-A., MacArthur, D. M. and Ogara, J. F., Chemistry of Materials 1, 370 (1989).CrossRefGoogle Scholar
13. Pocharski, J., Materials Science Forum, 21, 173 (1987).CrossRefGoogle Scholar
14. Zahurak, S. M., Kaplan, M. L., Rietman, E. A., Murphy, D. W. and Cava, R. J., Macromolecules 21, 254 (1988).CrossRefGoogle Scholar
15. Allcock, H. R., Austin, P. E., Sisko, J. T., Blonsky, P. M. and Shriver, D.F., Macromulecules, 19, 1508 (1986).CrossRefGoogle Scholar
16. Watanabe, M., Suzuki, A., Santo, T., Sanui, K., and Ogata, N., Macromolecules, 19, 1921 (1986).CrossRefGoogle Scholar
17. Bruce, P.G. and Vincent, C.A., Faraday Discuss. Chem. Soc., 88, 000, (1989).CrossRefGoogle Scholar
18. Greenbaum, S.C., Pak, Y.S., Wintersgill, M.C. and Fontanella, J.J., Solid State Ionics, 31, 241 (1988).CrossRefGoogle Scholar
19. Nazri, G-A., MacArthur, D.M., Aroca, R., Mat. Res. Soc. Symp. Proc. Vol 175, 61 (1990).CrossRefGoogle Scholar
20. Bhattacharja, S., Smoot, S.W. and Whitmore, D.N., Solid State lonics, 18/19, 306 (1986).CrossRefGoogle Scholar
21. Stainer, M., Hardy, C.L., Whitmore, D.H. and Shriver, D.F., J. Electrochem. Soc. 131, 784 (1984).CrossRefGoogle Scholar
22. Watanabe, M., Itoh, M., Sanui, K. and Ogata, N., Macromolecules 20, 569 (1987).CrossRefGoogle Scholar
23. Wintersgill, M.C., Fontanella, J.J., Smith, M.K., Greenbaum, S.G., Adamic, K.J. and Andeen, C.G., Polymer, 28, 633 (1987).CrossRefGoogle Scholar
24. Fontanella, J.J., Wintersgill, M.C., Smith, M.K., Semancokm, J. and Andeen, C.G., J. Appl. Phys. 60, 2665 (1986).CrossRefGoogle Scholar
25. Takahashi, Y., Tadokora, H., Macromolecules, 6, 672 (1973).CrossRefGoogle Scholar
26. Matsuura, H. and Fukuhara, K., J. of Polymer Science: Part B: Polymer Physics, 24, 1383 (1986).CrossRefGoogle Scholar
27. Abe, A., Tasaki, K. and Mark, J., Polymer Journal 17, 883 (1985).CrossRefGoogle Scholar
28. Matsuura, H. and Miyazawa, T., Bulletin of the Chemical Society of Japan, 41, 1808 (1968).Google Scholar
29. Koenig, J.L. and Angood, A.C., J. Polymer Science, Part A: 8, 1787 (1970).CrossRefGoogle Scholar
30. Maxfield, J. and Shepherd, I.W., Polymer, 1, 505 (1975).CrossRefGoogle Scholar
31. Williams, M.L., Landel, R.F. and Ferry, J.D., J. Am. Cbem. Soc., 77, 3701 (1955).CrossRefGoogle Scholar