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Vanadium Oxide Frameworks Modified with Transition Metals

Published online by Cambridge University Press:  18 March 2011

Peter Y. Zavalij and
M. Stanley Whittingham
Peter Y. Zavalij
Affiliation:
Institute for Materials Research and Chemistry Department, State University of New York at Binghamton, Binghamton, NY, 13902-6016, USA
M. Stanley Whittingham
Affiliation:
Institute for Materials Research and Chemistry Department, State University of New York at Binghamton, Binghamton, NY, 13902-6016, USA
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Abstract

It is well known that vanadium oxides readily form open structures that defines the potential use of vanadium compounds as cathode materials for lithium batteries. In order to stabilize open frameworks during electrochemical cycling and improve their performance, vanadium oxide can be modified with other transition metals. This work presents the structural analysis of vanadium oxide frameworks modified with Mn and Zn as well as reporting on several interesting new structures, such as TMA4[Zn4V21O58] and NaMn(VO3)4·2H2O.

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References

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