Hostname: page-component-7b7567c8c-7pwfn Total loading time: 0 Render date: 2026-11-12T20:02:15.543Z Has data issue: false hasContentIssue false
  • English
  • Français

Copper-Containing Ceramic Precursor Synthesis: Solid-State Transformations and Materials Technology

Published online by Cambridge University Press:  22 February 2011

Aloysius F. Hepp,
William E. Eckles,
Stan A. Duraj,
Maria T. Andras,
Phillip E. Fanwick,
Robert M. Richman,
Michael L. Sabat,
Michael B. Power,
Edward M. Gordon and
Andrew R. Barron
Aloysius F. Hepp
Affiliation:
NASA Lewis Research Center, Photovoltaic Branch, M.S. 302-1, Cleveland, OH 44135
William E. Eckles
Affiliation:
Department of Chemistry, Cleveland State University, Cleveland, OH 44115
Stan A. Duraj
Affiliation:
Department of Chemistry, Cleveland State University, Cleveland, OH 44115
Maria T. Andras
Affiliation:
NASA Lewis Research Center, Photovoltaic Branch, M.S. 302-1, Cleveland, OH 44135National Research Council/NASA Lewis Research Center Resident Research Associate
Phillip E. Fanwick
Affiliation:
Department of Chemistry, Purdue University, West Lafayette, IN 47907
Robert M. Richman
Affiliation:
Mount St. Mary's College, Emmitsburg, MD 21727
Michael L. Sabat
Affiliation:
Departjnent of Chemistry, University of Virginia, Charlottesville, VA 22901
Michael B. Power
Affiliation:
Gallia, Inc., 53 Beaver Rd., Weston, MA 02193
Edward M. Gordon
Affiliation:
Division of Natural Sciences, Wilberforce University, WIlberforce, OH 45384NASA Lewis Research Center Resident Research Associate
Andrew R. Barron
Affiliation:
Department of Chemistry, Harvard University, Cambridge, MA 02138
Get access

Abstract

Three copper systems with relevance to materials technology are discussed. In the first, a CuS precursor, Cu4S 10(4-methylpyridine)4 (4-MePy), was prepared by three routes: reaction of Cu2S, reaction of CuBr•SMe2 and oxidation of copper powder with excess sulfur in 4-methylpyridine by sulfur. In the second, copper powder was found to react with excess thiourea (H2NC(S)NH2) in 4-methylpyridine to produce thiocyanate (NCS-) complexes. Three isolated and characterized compounds are: Cu(NCS)(4-MePy)2, a polymer, [4-MePy•H][Cu(NCS)3(4-MePy)2], a salt, and t-Cu(NCS)2(4-MePy)4. Finally, an attempt to produce a mixed-metal sulfide precursor of Cu and Ga in N-methylimidazole (N-MeIm) resulted in the synthesis of a Cu-containing polymer, Cu(S04)(N-Melm). The structures are presented; the chemistry will be briefly discussed in the context of preparation and processing of copper-containing materials for aerospace applications.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 327: Symposium N – Covalent Ceramics II: Non-Oxides , 1993, 23
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

1. Cotton, F.A. and Wilkinson, G. et al. Advanced Inorganic Chemistry, et al. 5th ed. (John Wiley and Sons, New York, 1988), pg. 756.Google Scholar
2. Murarka, S.P. and Peckerar, M.C., Electronic Materials Science and Technology (Academic Press, New York, 1989).Google Scholar
3. Kazmerski, L.L. and Wagner, S., in et al. Current Topics in Photovoltaics, et al. edited by Coutts, T. J. and Meakin, J. D. (Academic Press, London, 1985) pp. 41–109.Google Scholar
4. Muller, K.A. and Bednorz, J.G., Science 237, 1133 (1987).Google Scholar
5. Kaloyeros, A.E., Feng, A., Garhart, J., Brooks, K.C., Gosh, S.K., Saxena, A.N., and Leuthers, F., J. Electron. Mater. 19, 271 (1990).Google Scholar
6. Beach, D.B., LeGoues, F.K., and Hu, C.K., Chem. Mater. 2, 216 (1990).Google Scholar
7. Shin, H.K., Chi, K.M., Hampden-Smith, M.J., Kodas, T.T., Farr, J.D., and Paffett, M., Chem. Mater. 4, 788 (1992).Google Scholar
8. Jain, A., Farkas, J., Kodas, T.T., Chi, K.-M., Hampden-Smith, M.J., Appl. Phys. Lett. 61, 2262 (1992).Google Scholar
9. Winters, H.F., J. Vac. Sci. Technol. A 3, 786 (1985).Google Scholar
10. Veen, G.N.A. van, Baller, T., and Vries, A.D. De, J. Appl. Phys. 60, 3746 (1986).Google Scholar
11. Farkas, J., Chi, K.-M., Kodas, T.T., and Hampden-Smith, M.J., in et al. Advanced Metallization for ULSI Applications, et al. edited by Rana, V.V.S., Joshi, R.V., and Ohdomari, I. (Mater. Res. Soc. Conf. Proc., Pittsburgh, PA, 1992) pp. 445–449.Google Scholar
12. Farkas, J., Chi, K.-M., Hampden-Smith, M.J., Kodas, T.T., and Dubois, L., J. Appl. Phys. 73, 1455 (1993).Google Scholar
13. Nomura, R., Seki, S., and Matsuda, H., J. Mater. Chem. 2, 765 (1992).Google Scholar
14. Hirpo, W., Dhingra, S., Sutorik, A., and Kanatzidis, M.G., J. Am. Chem. Soc. 115, 1597 (1993).Google Scholar
15. Chemistry of High-Temperature Superconductors, edited by Nelson, D.L., Whittingham, M.S., and George, T.F. (American Chemical Society, Washington, D.C., 1987).Google Scholar
16. High-Temperature Superconductors: Fundamental Properties and Novel Material Processing, edited by Christen, D., Narayan, J., and Schneemeyer, L. (Mater. Res. Soc. Proc. 169, Conference Proceedings, Pittsburgh, PA, 1990).Google Scholar
17. Sneeden, R.P.A., in Comprehensive Organometallic Chemistry, Vol. 8, edited by Wilkinson, G., Stone, F.G.A., and Abel, E.W. (Pergamon Press, Oxford, 1982) pp. 1–17.Google Scholar
18. Power, M.B. and Barron, A.R., J. Chem. Soc., Chem. Comm., 1315 (1991).Google Scholar
19. Hepp, A.F., Eckles, W.E., Richman, R.M., Duraj, S.A., Andras, M.T., and Sabat, M.L., manuscript in preparation.Google Scholar
20. Ramli, E., Rauchfuss, T.B., and Stern, C.L., J. Am. Chem. Soc. 112, 4043 (1990).Google Scholar
21. Muller, A. and Diemann, E., Adv. Inorg. Chem. 31, 89 (1987).Google Scholar
22. Dev, S., Ramli, E., Rauchfuss, T.B., and Wilson, S.R., Inorg. Chem. 30, 2514 (1991).Google Scholar
23. Healy, P.C., Pakawatchai, C., Papasegio, R.I., Patrick, V.A., and White, A.H., Inorg. Chem. 23, 3769 (1984).Google Scholar
24. Frost, J.G., Lawson, M.B., and MacPherson, W.G., Inorg. Chem. 15, 940 (1976).Google Scholar
25. Jedrzejas, M.J., Towns, R.L.R., Baker, R.J., Duraj, S.A., and Hepp, A.F., Acta Cryst., Sect. C 49, 538 (1993).Google Scholar
26. Kozisek, J., Hricov, A., and Langfelderova, H., Acta Cryst., Sect. C 49, 885 (1989).Google Scholar
27. Caneschi, A., Gatteschi, D., Sessoli, R., Rey, P., and Cabello, C.I., J. Mater. Chem. 2, 1283 (1992).Google Scholar