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Correlations Between Medium Frequency Blocking Parameters and Microstructure in Low Conductivity Materials

Published online by Cambridge University Press:  10 February 2011

M. Kleitz
Affiliation:
Laboratoire d'Ionique et d'Electrochimie du Solide de renoble (INPG / CNRS) 38402 Saint Martin d'Hères, France
L. Dessemond
Affiliation:
Laboratoire d'Ionique et d'Electrochimie du Solide de renoble (INPG / CNRS) 38402 Saint Martin d'Hères, France
M. C. Steil
Affiliation:
Centre S.M.S., Laboratoire de Ceramiques Speciales Ecole des Mines de St Etienne 42023 Saint Etienne, France
F. Thevenot
Affiliation:
Centre S.M.S., Laboratoire de Ceramiques Speciales Ecole des Mines de St Etienne 42023 Saint Etienne, France
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Abstract

Observations have been made by impedance spectroscopy of various microstructure-induced blocking effects in cubic zirconias and composites. Correlations have been established between shape parameters of the microstructure defects and specific parameters of the electric response, such as the blocking factor and frequency factor, in the medium frequency range.

Appropriate diagrams show the continuity and changes in the regimes of the microstructure evolutions.

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Type
Research Article
Copyright
Copyright © Materials Research Society 1996

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