Hostname: page-component-7b7567c8c-7pwfn Total loading time: 0 Render date: 2026-11-14T10:09:46.126Z Has data issue: false hasContentIssue false
  • English
  • Français

Dynamics of Flexible Polyions in Solution: Ionic Strength Effects

Published online by Cambridge University Press:  21 February 2011

Hedi Mattoussi,
Kenneth H. Langley and
Frank E. Karasz
Hedi Mattoussi
Affiliation:
Polymer Science & Engineering Department, University of Massachusetts
Kenneth H. Langley
Affiliation:
Department of Physics and Astronomy, University of Massachusetts, Amherst, MA 01003.
Frank E. Karasz
Affiliation:
Polymer Science & Engineering Department, University of Massachusetts
Get access

Abstract

Measurements of the collective diffusion coefficient, for polyelectrolyte solutions at high ionic strength and in the dilute regime, are reported. The data are discussed within the framework of a persistent chain with electrostatic contribution to account for the Coulomb interactions.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 177: Symposium V – Macromolecular Liquids , 1989, 71
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

[1] Morawetz, M., Macromolecules in Solutions, V. XXI, in High Polymers, Wiley, New York (1975).Google Scholar
[2] Nagasawa, M., Takahaski, A. in Light Scattering from Polymer Solutions, Ed. by Huglin, M. B., Wiley, New York (1972) Ch. 16.Google Scholar
[3] Lin, S. G., Lee, W. L., Schurr, J. M., Biopolymers, 17, 1041 (1978).Google Scholar
[4] Schurr, J. M., Chem. Phys. 45, 113 (1980).Google Scholar
[5] Odjik, T., Howart, A. C., J. Poly. Sci., Poly. Phy. Ed., 16, 627 (1978).Google Scholar
[6] Berry, G. C., Proceedings MRS, Boston Meeting, November (1988).Google Scholar
[7] Mattoussi, H., Karasz, F.E., Langley, K. H., to be published.Google Scholar
[8] Berne, B., Pecora, R., Dynamic Light Scattering, Wiley, New York (1976).Google Scholar
[9] Koene, R. S., Mandel, M., Macromolecules, 21, 3015 (1983).Google Scholar
[10] Machado, J., Denton, F. R. III, Shlenoff, J. B., Karasz, F. R., Lahti, P. M., J. Polym. Sci., Part B Polym. Phys., Ed., 27, 199 (1989).Google Scholar
[11] Yamakawa, H., Fujii, M., Macromolecules, 6, 407 (1973).Google Scholar
[12] Yamakawa, H., Modern Theory of Polymer Solutions, Harper and Row, New York (1971).Google Scholar
[13] Mattoussi, H., o'Donohue, S., Karasz, F. E., in preparation.Google Scholar
[14] Casassa, E. F., Berry, G. C., in Comprehensive Polymer Science, Vol.2, Cha. 2, Ed. by Allen, S. & al, Pergamon Press, Oxford (1989).Google Scholar
[15] Berry, G. C., in Encyclopedia of Polymer Science & Engineering, (Mark, H. et al Ed.), Wiley, New York ( 1987) p. 721.Google Scholar