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Four-Wave Mixing in Metal Poly-Ynes

Published online by Cambridge University Press:  25 February 2011

C. C. Frazier,
E. A. Chauchard,
M. P. Cockerham and
P. L. Porter
C. C. Frazier
Affiliation:
Martin Marietta Laboratories, 1450 S. Rolling Rd., Baltimore, MD 21227-3898
E. A. Chauchard
Affiliation:
Martin Marietta Laboratories, 1450 S. Rolling Rd., Baltimore, MD 21227-3898
M. P. Cockerham
Affiliation:
Martin Marietta Laboratories, 1450 S. Rolling Rd., Baltimore, MD 21227-3898
P. L. Porter
Affiliation:
Martin Marietta Laboratories, 1450 S. Rolling Rd., Baltimore, MD 21227-3898
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Abstract

We have reported previously that metal poly-ynes have large thirdorder optical susceptibilities. Based on the four-wave mixing studies reported here, we conclude that strong two-photon absorptions in metal poly-ynes contribute significantly to the observed third-order nonlinearities of these materials. Hyperpolarizability/r.u. increases only slightly with chain length for tetrahydrofuran solutions of the metal poly-ynes. The possible influence of conformers on this behavior is discussed.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 109: Symposium K – Nonlinear Optical Properties of Polymers , 1987, 323
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

1. Frazier, C.C., Harvey, M.A., Cockerham, M.P., Hand, H.M., Chauchard, E.A., Lee, C.H., J. Phys. Chem. 90, 5703 (1986).CrossRefGoogle Scholar
2. Frazier, C.C., Guha, S., Chen, W.P., Cockerham, M.P., Porter, P.L., Chauchard, E.A., Lee, C.H., Polymer 28, 553 (1987).Google Scholar
3. Calabrese, J.C. and Tam, W., Chem. Phys. Lett. 133, 244 (1987).CrossRefGoogle Scholar
4. Eaton, D.F., Anderson, A.G., Tam, W., and Wang, Y., J. Am. Chem. Soc. 109, 1886 (1987).CrossRefGoogle Scholar
5. Williams, D.J., ed., Nonlinear Optical Properties of Organic and Polymeric Materials, ACS Symposium Series No. 233 (American Chemical Society, Washington, 1983).Google Scholar
6. Zyss, J.J., J. Non-Cryst. Solids 47, 211 (1982).CrossRefGoogle Scholar
7. Shen, Y.R., The Principles of Nonlinear Optics (John Wiley and Sons, New York, 1984), Chap. 15.Google Scholar
8. Levenson, M.D., Introduction to Nonlinear Laser Spectroscopy (Academic Press, New York, 1982), Chap. 4.Google Scholar
9. Takahashi, S., Kariya, M., Yatake, T., Sonogashira, K., Hagihara, N., Macromolecules 11, 1063 (1978).CrossRefGoogle Scholar
10. Takahashi, S., Morimoto, H., Murata, E., Kataoka, S., Sonogashira, K., Hagihara, N., J. Polym. Sci. Polym. Chem. Ed. 20, 565 (1982).Google Scholar
11. Takahashi, S., Ohyama, Y., Murata, E., Sonogashira, K., Hagihara, H., J. Polym. Sci. Chem. Ed. 18, 349 (1980).Google Scholar
12. Sonogashira, K., Fujikura, Y., Yatake, T., Tokoshima, N., Takahashi, S., Hagihara, N., J. Organometal. Chem. 145, 101 (1978).Google Scholar
13. Sonogashira, K., Yatake, T., Tohda, Y., Takahashi, S., Hagihara, N., J. Chem. Soc. Chem. Comm. 291 (1977).Google Scholar
14. Meredith, G.R., Buchalter, B., and Hanzlik, C., J. Chem. Phys. 78, 1543 (1983).CrossRefGoogle Scholar
15. Shand, M.L. and Chance, R.R., J. Chem. Phys. 69, 4482 (1978).Google Scholar
16. Lynch, R.T., Loten, H., J. Chem. Phys. 66, 1905 (1977).Google Scholar
17. Oudar, J.L., J. Chem. Phys. 67, 446 (1977).Google Scholar
18. Beratan, D.N., Onuchic, J.N., Perry, J.W., J. Phys. Chem. 91, 2696 (1987).Google Scholar