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Impurity Distribution Profiles and Surface Disorder after Laser Induced Diffusion.

Published online by Cambridge University Press:  15 February 2011

E. Fogarassy
Affiliation:
Centre De Recherches Nucléaires Laboratoire Phase, 67037 Strasbourg Cedex France
R. Stuck
Affiliation:
Centre De Recherches Nucléaires Laboratoire Phase, 67037 Strasbourg Cedex France
P. Siffert
Affiliation:
Centre De Recherches Nucléaires Laboratoire Phase, 67037 Strasbourg Cedex France
F. Broutet
Affiliation:
Faculté des Sciences PoitiersFrance
J. C. Desoyer
Affiliation:
Faculté des Sciences PoitiersFrance
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Abstract

A model for laser induced diffusion is proposed, assuming the melting of Si surface under pulsed laser irradiation and the diffusion ,in liquid phase, of a thin filmof impurity deposited according to the “limited source” conditions. Depending on the thickness of the film, it results in a dopant distribution profile with a surface disordered layer induced either by segregation effects or precipitation of the dopant in excess of the solubility limit achieved by laser annealing. Experimental results, obtained for a ruby laser irradiation of thin films of different impurities of group III and V, like antimony, bismuth, gallium and indium deposited on silicon substrates are in good agreement with the model. Their effective segregation coefficients have been deduced by fitting the experimental amount of dopant precipitated in the disordered surface layer with the numerical calculations. A cellular structure is seen on surface.

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Type
Research Article
Copyright
Copyright © Materials Research Society 1983

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