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Metallic Glass Formation Diagrams*

Published online by Cambridge University Press:  15 February 2011

B. C. Giessen and
S. H. Whang
B. C. Giessen
Affiliation:
Materials Science Division, Institute of Chemical Analysis and Department of Chemistry, Northeastern University, Boston, Massachusetts, 02115, USA
S. H. Whang
Affiliation:
Materials Science Division, Institute of Chemical Analysis and Department of Chemistry, Northeastern University, Boston, Massachusetts, 02115, USA
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Abstract

The ability to predict ready glass formation (RGF) in binary alloy systems upon rapid cooling of the melt is of value both theoretically and practically. Two-dimensional maps show promise as a means of associating RGF with two system parameters which must have a combination of favorable values. In this paper, two types of glass formation diagrams are reviewed. One of these, the ΔH-r/R plot, is based on fundamental parameters which can, in principle, be derived from elemental quantities for each binary alloy system. The second type of diagram, the temperature-composition map, uses two equilibrium phase diagram features, namely reduced liquidus temperatures and reduced eutectic compositions to predict RGF. Both approaches are compared for binary alloys of Zr. The temperature-composition plot approach can be extended to predict qualitatively the RGF composition range of a given alloy system.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 19: Symposium E – Alloy Phase Diagrams , 1982, 289
Copyright
Copyright © Materials Research Society 1983

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Footnotes

*

Communication #163 of the Institute of Chemical Analysis at Northeastern University, Boston, Massachusetts 02115 USA.

References

REFERENCES

1. Klement, W. Jr., Willens, R.H., and Duwez, P., Nature 187, 809 (1960).Google Scholar
2. Turnbull, D., J. Phys. (Paris) 35, Colloque C-4, C4-1 (1974).Google Scholar
3. Polk, D.E. and Giessen, B.C., in: Metallic Glasses, Gilman, J.J. and Leamy, J.H., eds. (ASM, Metals Park, OH 1978), p. 1.Google Scholar
4. Takayama, S., J. Mater. Sci. 11, 164 (1976).CrossRefGoogle Scholar
5. Giessen, B.C. and Whang, S., J. Phys. (Paris) 41, Colloque C-8, C8-95 (1980).Google Scholar
6. Giessen, B.C. and Polk, D.E., in: Theory of Alloy Phase Formation, Bennett, L.H., ed. (TMS-AIME, Warrendale, PA 1980), p. 487.Google Scholar
7. Hafner, J., Phys. Rev. B 21, 406 (1980).Google Scholar
8. Jones, H., Rep. Prog. Phys. 36, 1425 (1973).Google Scholar
9. Darken, L.S. and Gurry, R.W., Physical Chemistry of Metals (McGraw-Hill, New York 1953), p. 74.Google Scholar
10. Bennett, L.H. and Watson, R.E., in: Theory of Alloy Phase Formation, Bennett, L.H., ed. (TMS-AIME, Warrendale, PA 1980), p. 390.Google Scholar
11. Giessen, B.C., in: Proc. Fourth Internat. Conf. on Rapidly Quenched Metals, Vol. I, T. Masumoto and K. Suzuki, eds. (The Japan Institute of Metals, Sendai 1981), p. 213.Google Scholar
12. Inoue, A., Takahashi, Y., Toyota, N., Fukase, T. and Masumoto, T., in: Proc. Fourth Internat. Conf. on Rapidly Quenched Metals, Vol II, T. Masumoto and K. Suzuki, eds. (The Japan Institute of Metals, Sendai 1981), p. 1221.Google Scholar
13. Whang, S.H., Mater. Sci. and Eng. 57, 87 (1983).Google Scholar
14. Miedema, A.R. and de Châtel, P.F., in: Theory of Alloy Phase Formation, Bennett, L.H., ed. (TMS-AIME, Warrendale, PA 1980), p. 344.Google Scholar
15. Hodges, C.H., in: Theory of Alloy Phase Formation, Bennett, L.H., ed. (TMS-AIME, Warrendale, PA 1980), p. 503.Google Scholar
16. Hafner, J., Private Communication.Google Scholar
17. Alonso, J.A. and Simozar, S., Phys. Rev. B 22, 5583 (1980).Google Scholar
18. Hume-Rothery, W., J. Inst. Met. 35, 295, 307 (1926).Google Scholar
19. Boettinger, W.J., in: Rapidly Solidified Amorphous and Crystalline Alloys, MRS Symp. Proc. Vol. 8, Kear, B.H., Giessen, B.C., and Cohen, M., eds. (North Holland, NY 1982), p. 15.Google Scholar