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Metallization at Microindentations

Published online by Cambridge University Press:  15 February 2011

John J. Gilman*
Affiliation:
Lawrence Berkeley Laboratory, Berkeley, California 94720
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Abstract

It is shown that quite generally there is a correlation between insulator-metal transition pressures and indentation hardness numbers for covalent crystals. They are numerically equal for the Group IV elements. Three elements plus five III–V compounds acquire the β-Sn structure upon metallizing. Bondbending, rather than bond-shortening, appears to lead to their transformations. A simple version of the theory of covalent bonds gives the critical transformation bond-angle correctly.

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