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Multi-Electron-Transfer Catalysts Needed for Artificial Photosynthesis

Published online by Cambridge University Press:  18 May 2012

James Vickers,
Hongjin Lv,
Petro F. Zhuk,
Yurii V. Geletii and
Craig L. Hill
James Vickers
Affiliation:
Department of Chemistry, Emory University, Atlanta, Georgia 30322, U.S.A.
Hongjin Lv
Affiliation:
Department of Chemistry, Emory University, Atlanta, Georgia 30322, U.S.A.
Petro F. Zhuk
Affiliation:
National Aviation University, Kiev, Ukraine
Yurii V. Geletii
Affiliation:
Department of Chemistry, Emory University, Atlanta, Georgia 30322, U.S.A.
Craig L. Hill
Affiliation:
Department of Chemistry, Emory University, Atlanta, Georgia 30322, U.S.A.
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Abstract

We report a study on catalytic water oxidation by cobalt in oxygen ligand environments because such systems are as promising as any in the water oxidation component of solar fuel production. We have re-examined the catalytic activity of Co(II) in aqueous solution using either [Ru(bpy)3]3+ as a stoichiometric oxidant or in visible-light-driven reactions with persulfate as a sacrificial electron acceptor. In both systems a distinctive induction period is observed. A simple kinetic model is proposed that describes the experimental data well. The presence of an induction period is explained by relatively slow formation of the true catalyst from aquacobalt(II).

Keywords

catalytickineticsoxidation

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1387: Symposium E – Advanced Materials for Solar-Fuel Generation , 2012, mrsf11-1387-e02-01
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

[1] Bard, A.J. and Fox, M.A., Acc. Chem. Res. 28(3), 141–145 (1995).Google Scholar
[2] Brunschwig, B.S., Chou, M.H., Creutz, C., Ghosh, P. and Sutin, N., J. Am. Chem. Soc. 105 4832–4833 (1983).Google Scholar
[3] Harriman, A., Porter, G. and Walters, P., J. Chem. Soc. Faraday Trans. 2 77 2373–2383 (1981).Google Scholar
[4] Khannanov, N.K. and Shafirovich, V.Y., Doklady Akademii Nauk SSSR 260(6), 1418–1421 (1981).Google Scholar
[5] Khannanov, N.K., Khramov, A.V., Moravskii, A.P. and Shafirovich, V.Y., Kinetika i Kataliz 24(4), 858–864 (1983).Google Scholar
[6] Moravskii, A.P., Khannanov, A.P. and Khramov, A.V., Khimicheskaya Fizika 3(11), 1584–1590 (1984).Google Scholar
[7] Ghosh, P.K., Brunschwig, B.S., Chou, M., Creutz, C. and Sutin, N., J. Am. Chem. Soc. 106 4772–4783 (1984).Google Scholar
[8] Geletii, Y.V., Botar, B., Kögerler, P., Hillesheim, D.A., Musaev, D.G. and Hill, C.L., Angew. Chem. Int. Ed. 47 3896–3899 (2008).Google Scholar
[9] Sartorel, A., Carraro, M., Scorrano, G., Zorzi, R.D., Geremia, S., Mcdaniel, N.D., Bernhard, S. and Bonchio, M., J. Am. Chem. Soc 130(15), 5006–5007 (2008).Google Scholar
[10] Geletii, Y.V., Huang, Z., Hou, Y., Musaev, D.G., Lian, T. and Hill, C.L., J. Am. Chem. Soc. 131 7522–7523 (2009).Google Scholar
[11] Cao, R., Ma, H., Geletii, Y.V., Hardcastle, K.I. and Hill, C.L., Inorg. Chem. 48 5596–5598 (2009).Google Scholar
[12] Yin, Q., Tan, J.M., Besson, C., Geletii, Y.V., Musaev, D.G., Kuznetsov, A.E., Luo, Z., Hardcastle, K.I. and Hill, C.L., Science 328 342–345 (2010).Google Scholar
[13] Huang, Z., Luo, Z., Geletii, Y.V., Vickers, J., Yin, Q., Wu, D., Hou, Y., Ding, Y., Song, J., Musaev, D.G., Hill, C.L. and Lian, T., J. Am. Chem. Soc. 133 2068–2071 (2011).Google Scholar
[14] Kanan, M.W. and Nocera, D.G., Science 321 1072–1075 (2008).Google Scholar
[15] Kanan, M.W., Surendranath, Y. and Nocera, D.G., Chem. Soc. Rev. 38 109–114 (2009).Google Scholar
[16] Lutterman, D.A., Surendranath, Y. and Nocera, D.G., J. Am. Chem. Soc. 131 3838–3839 (2009).Google Scholar
[17] Mendes, P., Vol. 9, Comput. Applic. Biosci., 1997, pp. 563–571.Google Scholar
[18] Stracke, J.J. and Finke, R.G., J. Am. Chem. Soc. 133 14872–14875 (2011).Google Scholar
[19] Gerken, J.B., Mcalpin, J.G., Chen, J.Y.C., Rigsby, M.L., Casey, W.H., Britt, R.D. and Stahl, S.S., J. Am. Chem. Soc. 133 14431–14442 (2011).Google Scholar