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Preceramic Polymers for Aluminum Oxides

Published online by Cambridge University Press:  25 February 2011

William S. Rees JR.
Affiliation:
Department of Chemistry and Materials Research and Technology Center, Florida State University, Tallahassee, Florida 32306-3006
Werner Hesse
Affiliation:
Department of Chemistry and Materials Research and Technology Center, Florida State University, Tallahassee, Florida 32306-3006
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Abstract

The utilization of recently discovered aluminum-oxygen-carbon backbone polymers in the preparation of various phases of A12O3 is presented. The structure of the polymers has been examined by ss 27AI NMR, TGA, MS, SEM, XRD, and EDAX. The solid pyrolysis products of these polymers have been characterized by ss 27AI NMR, XRD, SEM, and EDAX. The volatile products of pyrolysis have been studied by trapping, TGA and MS.

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