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Preparation and Phase Relations in the CuSbSe2 – CuInSe2 System

Published online by Cambridge University Press:  31 May 2016

Barys V. Korzun,
Valery R. Sobol,
Marin Rusu,
Ruben M. Savizky,
Alena A. Fadzeyeva,
Ivan I. Maroz,
Andrei N. Gavrilenko,
Vadim L. Matukhin and
Martha Ch. Lux-Steiner
Barys V. Korzun
Affiliation:
Belarusian State Pedagogical University, 18 Sovetskaya, Minsk, 220030, Belarus
Valery R. Sobol
Affiliation:
Belarusian State Pedagogical University, 18 Sovetskaya, Minsk, 220030, Belarus
Marin Rusu
Affiliation:
Helmholtz-Zentrum Berlin für Materialen und Energie, 1 Hahn-Meitner Platz, Berlin, 14109, Germany
Ruben M. Savizky
Affiliation:
The Cooper Union for the Advancement of Science and Art, 30 Cooper Square, New York, NY 10003, U.S.A.
Alena A. Fadzeyeva
Affiliation:
Scientific-Practical Materials Research Centre of the National Academy of Sciences of Belarus, 19 P. Brovki, Minsk, 220072, Belarus
Ivan I. Maroz
Affiliation:
Scientific-Practical Materials Research Centre of the National Academy of Sciences of Belarus, 19 P. Brovki, Minsk, 220072, Belarus
Andrei N. Gavrilenko
Affiliation:
Kazan State Power Engineering University, 51 Krasnoselskaya, Kazan, 420066, Russia.
Vadim L. Matukhin
Affiliation:
Kazan State Power Engineering University, 51 Krasnoselskaya, Kazan, 420066, Russia.
Martha Ch. Lux-Steiner
Affiliation:
Helmholtz-Zentrum Berlin für Materialen und Energie, 1 Hahn-Meitner Platz, Berlin, 14109, Germany
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Abstract

The CuInSe2 and CuSbSe2 ternary compounds and alloys of the (CuSbSe2)1-x·(CuInSe2)x system with the mole fraction of CuInSe2 (x) equal to 0.05, 0.15, 0.25, 0.375, 0.50, 0.625, 0.75, 0.85, and 0.95 were prepared and the phase relations in this system were investigated by X-ray powder diffraction, optical microscopy, and scanning electron microscopy. It was shown that the alloys of the CuSbSe2-CuInSe2 system are biphasic at room temperature in the whole range of compositions, and the limits of solubility for CuSbSe2 in CuInSe2 and for CuInSe2 in CuSbSe2 do not exceed 0.001 mole fraction.

Keywords

x-ray diffraction (XRD)microstructurescanning electron microscopy (SEM)

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References

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