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Reactive Template-Induced Self-Assembly to Ordered Mesoporous Polymer and Carbon

Published online by Cambridge University Press:  08 August 2013

Yeru Liang,
Ruowen Fu and
Dingcai Wu
Yeru Liang
Affiliation:
Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China
Ruowen Fu
Affiliation:
Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China
Dingcai Wu*
Affiliation:
Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China
*
*Email: wudc@mail.sysu.edu.cn
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Abstract

As an important method for preparing ordered mesoporous polymer and carbon, organic template directed self-assembly is facing challenges because of the weak non-covalent interactions between the organic templates and the building blocks. Herein we developed a novel synthetic procedure based on a reactive template-induced self-assembly to construct ordered mesoporous framework. The aldehyde end-group of reactive template can react with the building blocks (i.e., resol) to form a stable covalent bond during the self-assembly process. This leads to an enhanced interaction between resol and template and thus achieves the formation of ordered mesostructure.

Keywords

self-assemblychemical synthesisnanostructure

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References

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