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Robust Microporous Molecular Frameworks Which Retain Structural Integrity Upon Template Loss

Published online by Cambridge University Press:  16 February 2011

C. J. Kepert ,
M. J. Rosseinsky ,
D. Hesek  and
P. D. Beer
C. J. Kepert
Affiliation:
Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, Oxford, OX1 3QR
M. J. Rosseinsky
Affiliation:
Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, Oxford, OX1 3QR
D. Hesek
Affiliation:
Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, Oxford, OX1 3QR
P. D. Beer
Affiliation:
Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, Oxford, OX1 3QR
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Abstract

Retention of the void space upon loss of the solvent template is directly demonstrated using single-crystal X-ray diffraction for molecular frameworks constructed using both hydrogen and co-ordinate bonds. While the co-ordination polymer remains rigid upon desolvation, the extra flexibility in the hydrogen-bonded framework, due both to the large number of redundant hydrogen-bonding donor and acceptor groups and the possibility of significant φ-φ stacking interactions within the framework, lead to a significant structural and symmetry change while retaining significant void volume. Molecular modelling techniques are used to understand and predict the guest uptake chemistry of these host frameworks.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 547: Symposium DD – Solid-State Chemistry of Inorganic Materials II , 1998 , 511
Copyright
Copyright © Materials Research Society 1999

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References

(1) Allison, S. A.; Barrer, R. M., J. Chem. Soc. A 1717 (1969).Google Scholar
(2) Hoskins, B. F.; Robson, R., Journal Of The American Chemical Society 112, 1546 (1990).Google Scholar
(3) Batten, S. R.; Robson, R., Angewandte Chemie-International Edition 37, 1461 (1998).Google Scholar
(4) Venkataraman, D.; Lee, S.; Zhang, J. S.; Moore, J. S., Nature 371, 591 (1994).Google Scholar
(5) Yaghi, O. M.; Li, H. L.; Davis, C.; Richardson, D.; Groy, T. L., Accounts Of Chemical Research 31, 474 (1998).Google Scholar
(6) Yaghi, O. M.; Li, G. M.; Li, H. L., Nature 378, 703 (1995).Google Scholar
(7) Li, H.; Eddaoudi, M.; Groy, T. L.; Yaghi, O. M., Journal Of The American Chemical Society 120, 8571 (1998).Google Scholar
(8) Kondo, M.; Yoshitomi, T.; Seki, K.; Matsuzaka, H.; Kitagawa, S., Angewandte Chemie-International Edition In English 36, 1725 (1997).Google Scholar
(9) Yoneda, S.; Kawase, T.; Inaba, M.; Yoshida, Z., Journal of Organic Chemistry 43, 595 (1978).Google Scholar
(10) Sheldrick, G. M.; Universitat Gottingen, 1993.Google Scholar
(11) Otwinowski, Z.; Minor, W. In Methods in Enzymology; Carter, C. W., Sweet, R. M., Eds.; Academic Press: New York, 1996; pp 276.Google Scholar
(12) Power, K. N.; Hennigar, T. L.; Zaworotko, M. J., New Journal Of Chemistry 22, 177 (1998).Google Scholar
(13) Spek, A. L., Acta Cryst. A46, C (1990).Google Scholar
(14) Maxwell, I. E.; de Boer, J. J., J. Phys. Chem. 79, 1875 (1975).Google Scholar