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Solid Phase Equilibria in the Ni-in-P System.

Published online by Cambridge University Press:  25 February 2011

Margaretha Andersson-Söderberg
Margaretha Andersson-Söderberg*
Affiliation:
Institute of Chemistry, Solid State Chemistry Group Box 531, S-751 21 Uppsala, Sweden
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Abstract

The solid phase equilibria in the Ni-In-P system at 800 °C have been determined at ambient pressure using X-ray diffraction supplemented with differential thermal analysis from room temperature to 800 °C. One ternary phase, Ni21In2P6, was found in the system. It crystallizes with space group Fm3m and is isostructural with Cr23C6. Indium phosphide forms equilibria with the nickel phosphides Ni2P, Ni5P4, NiP2 and NiP3 and indium with Ni12P5 and Ni2P. The results are in agreement with previous observations that Ni2P is a stable phase when a nickel thin film deposited on InP is reacted to completion.

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References

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