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Structures of New Nitrides Prepared using Solid Oxide Precursors

Published online by Cambridge University Press:  10 February 2011

Joel D. Houmes,
David S. Bem and
Hans-Conrad Zur Loye
Joel D. Houmes
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry Cambridge, MA 02139
David S. Bem
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry Cambridge, MA 02139
Hans-Conrad Zur Loye
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry Cambridge, MA 02139
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Abstract

Several novel transition metal nitrides and oxynitrides were synthesized via ammonolysis of solid state oxide precursors at temperatures ranging from 700°C-900°C and reaction times ranging from 12 hours to 4 days. The products were characterized by powder X-ray diffraction and their structures were determined by powder X-ray Rietveld refinement. The relationships between the structures of these nitrides and oxynitrides, and their similarity to the structures of the transition metal dichalcogenides, is discussed.

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