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Surface Assembled Hybrid Polymers

Published online by Cambridge University Press:  15 February 2011

Philip L. Rose,
Larry Manziek and
Michael K. Gallagher
Philip L. Rose
Affiliation:
Rohm and Haas Company, Research Laboratory, 727 Norristown Road, Spring House, PA, 19477
Larry Manziek
Affiliation:
Rohm and Haas Company, Research Laboratory, 727 Norristown Road, Spring House, PA, 19477
Michael K. Gallagher
Affiliation:
Rohm and Haas Company, Research Laboratory, 727 Norristown Road, Spring House, PA, 19477
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Abstract

Novel copolymer composite resins have been synthesized using the surface assembled hybrid technology. Monodisperse polystyrene/DVB microspheres with diameters of 5.3 and 7.5 μm and polydisperse carbonaceous and acrylic microspheres with diameters ranging from 5–30 μm have been assembled onto the surface of styrene and acrylonitrile based gel and macroreticular resins.

Carbonaceous adsorbents with holes of controlled diameter on their surfaces have been prepared using the surface assembling technique. Core-shell carbonaceous adsorbents with divergent surface chemistries have been prepared using this technique

Novel catalytic materials have been made and are envisioned using the assembling technique to form short-diffusion path reactive systems. The range of surface functional groups include: strong acid, strong base, palladium, silver, gold and reductive amine-borane.

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References

1. Kunin, R., Ion Exchange Resins; Robert E. Krieger Publishing Co.: Huntington, New York, 1972.Google Scholar
2. Thorpe, F.G., in New Methods of Polymer Synthesis Ebdon, J. R., Ed.; Chapman &Hall: N.Y., 1991.Google Scholar
3. March, J., Advanced Orgic Chemistry. 4th Ed.. John Wiley & Sons: New York, 1992.Google Scholar
4. Pohl, C.A. and Papanu, S.C., EP 0134099,13 March 1985 and references therein.Google Scholar
5. Stevens, T.S. and Langhorst, MA., US 4,519,905, 28 May 1985 and references therein.Google Scholar
6. Stevens, T.S., Langhorst, M.A. and Randall, O.W., 3rd, US 4,927,539,22 May 1990.Google Scholar
7. Fritz, J.S., Naples, J.O., Warth, L.M., EP 0346037,13 December 1989.Google Scholar
8. Warth, L.M. and Naples, J.O., J. Chromatography, 462,165 (1989).Google Scholar
9. Strasburg, R.F., Fritz, J.S., Naples, J.O., J. Chromatography,, 547,11, (1991).Google Scholar
10. Ludwig, R.C., J. Chromatography, 592, 101, (1992).Google Scholar
11. Hanaoka, Y., Murayama, T. and Muramoto, S., US 4,447,559, 8 May 1984.Google Scholar
12. McDougall, G.J. and Fleming, C.A., in Critical Reports on Appl. Chem.. 19, J. Wiley & Sons: N.Y., 1987.Google Scholar