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Third-Order Nonlinear Optical Properties of Phthalocyanines

Published online by Cambridge University Press:  25 February 2011

James S. Shirk
Affiliation:
Naval Research Laboratory, Washington, DC 20375
J. R. Undle
Affiliation:
Naval Research Laboratory, Washington, DC 20375
Steven R. Flom
Affiliation:
Naval Research Laboratory, Washington, DC 20375
F. J. Bartoli
Affiliation:
Naval Research Laboratory, Washington, DC 20375
Arthur W. Snow
Affiliation:
Naval Research Laboratory, Washington, DC 20375
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Abstract

This paper discusses the third-order nonlinear optical (NLO) properties of substituted phthalocyanines measured by time-resolved degenerate four-wave mixing at 1064 nm. The study explores optical pumping as a mechanism contributing to a large third-order optical nonlinearity in one member of this interesting class of NLO materials, PbPc(CP)4.

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