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Time-Resolved Saxs and Waxs Studies on Ordering Process in Oriented Crystallization of Polymers

Published online by Cambridge University Press:  26 February 2011

Kenji Saijo and
Takeji Hashimoto
Kenji Saijo
Affiliation:
Department of Polymer Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606, Japan
Takeji Hashimoto
Affiliation:
Department of Polymer Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606, Japan
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Abstract

Mechanism and dynamics of the ordering process in oriented crystallization of polymers were investigated by time-resolved small-angle X-ray scattering (SAXS) and wide-angle X-ray diffraction (WAXS). As a model system for the oriented crystallization, a cross-linked polybutadiene rubber with a high cis-1,4-linkage was chosen, and the structure evolution during the isothermal crystallization was investigated under constant elongations by real time and in situ analyses of the microscopic observables such as long spacing, crystallite size, SAXS integrated intensity, WAXS crystallinity and WAXS line width as well as a macroscopic observable such as stress. The isothermal ordering processes were explored in three different crystallization regimes: crystallization from (i) unoriented melts, (ii) weakly-to-moderately oriented melts and (iii) highly oriented melts.

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References

1. Koch, M.J.H, Bordas, J., Schola, E. and Chr, H.. Broecker, Polymer Bull., 1, 709 (1979).Google Scholar
2. 1 Schultz, M., in ‘Polymer Research at Synchrotron Radiation Sources’(Eds. Russell, T.P. and Goland, A.N., Proceedings of a Symposium at Brookhaven National Laboratory, Oct. 29–31,(1984)), BNL 51847 VC -25 (January 1985), p.85Google Scholar
3. Chirico, A.D., Lanzani, P.C., Raggi, E. and Bruzzone, M., Makromol. Chem. 175, 2029 (1974).Google Scholar
4. Suehiro, S., Saijo, K., Ohta, Y., Hashimoto, T. and Kawai, H., Analytica Chimica Acta, 189, 41 (1986).Google Scholar
5. Hashimoto, T., Saijo, K., Kość, M., Kawai, H., Wasiak, A. and Ziabicki, A., Macromolecules, 18, 472 (1985).Google Scholar
6. Saijo, K. and Hashimoto, T., to be submitted.Google Scholar
7. Strobl, G.R. and Schneider, M., J. Polym. Sci., Polym. Phys. Ed., 18, 1343 (1980).Google Scholar
8. Saijo, K., Wasiak, A., Kawai, H., and Hashimoto, T., to be submitted.Google Scholar
9. Schultz, J.M., Lin, J.S. and Hendricks, R.W., J. Appl. Cryst., 11, 551 (1978).Google Scholar
10. Elsner, G., Zachmann, H.G. and Milch, J.R., Makromol. Chem.,182, 657(1981)Google Scholar
11. Saijo, K., Zhu, Y.P., and Hashimoto, T., to be submitted.Google Scholar
12. Fischer, E.W. and Strobl, G. R., private communications.Google Scholar
13. Petermann, J., Gohil, R M., Schultz, J.M. and Hendricks, R.W., J. Polym. Sci., Polym. Phys. Ed., 20, 523 (1982); J. Petermann, Makromol. Chem., 182, 613 (1981).Google Scholar
14. Hashimoto, T., Itakura, M. and Hasegawa, H., J. Chem. Phys., 85, 6118 (1986); T. Hashimoto, M. Itakura and N. Shimidzu, J. Chem. Phys., 85, 6773 (1986).Google Scholar
15. Inaba, N., Sato, K., Suzuki, S., and Hashimoto, T., Macromolecules, 19, 1690 (1986).Google Scholar
16. Nakai, A., Shiwaku, T., Hasegawa, H., and Hashimoto, T., Macromolecules, 19, 3008 (1986).Google Scholar
17. Fischer, E.W. et al., Proc. IUPAC Symp., Toront, (1968).Google Scholar
18. Vignaud, R. and Schultz, J.M., Polymer, 27, 651 (1986).Google Scholar
19. Zernicke, F. and Prins, J.A., Z. Phys. 41, 184 (1927).Google Scholar
20. Hashimoto, T. and Saijo, K., to be submitted.Google Scholar
21. Kawai, T., Iguchi, M. and Tonami, H., Kolloid Z. 221, 28 (1968)Google Scholar
22. Gent, A. J. Polymer Sci., A–24, 447 (1966)Google Scholar