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Transformations and Hydrogen Storage in Ball-Milled Iron-Titanium

Published online by Cambridge University Press:  25 February 2011

P. Tessier,
L. Zaluski,
Z.-H. Yan,
M.L. Trudeau,
R. Bormann,
R. Schulz and
J.O. Ström-Olsen
P. Tessier
Affiliation:
Centre for the Physics of Materials, McGill University, Montréal, Québec, H3A 2T8, Canada
L. Zaluski
Affiliation:
Centre for the Physics of Materials, McGill University, Montréal, Québec, H3A 2T8, Canada
Z.-H. Yan
Affiliation:
Institut de recherche d'Hydro-Québec, Varennes, Québec, J3X 1S1, Canada
M.L. Trudeau
Affiliation:
Institut de recherche d'Hydro-Québec, Varennes, Québec, J3X 1S1, Canada
R. Bormann
Affiliation:
Institute for Materials Research, GKSS Research Center Geesthacht, D-2054 Geesthacht, Germany
R. Schulz
Affiliation:
Institut de recherche d'Hydro-Québec, Varennes, Québec, J3X 1S1, Canada
J.O. Ström-Olsen
Affiliation:
Centre for the Physics of Materials, McGill University, Montréal, Québec, H3A 2T8, Canada
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Abstract

Nanocrystalline and amorphous Fe-Ti at or close to the equiatomic composition have been prepared by ball milling, starting either from the elemental components or from the pre-melted intermetallic. The final structure, whose evolution has been monitored by Xray diffraction and transmission electron microscopy, is found to be critically dependent on milling conditions and contamination level.

Hydrogen absorption properties of both the amorphous and nanocrystalline alloys have been investigated. These properties are substantially modified by the reduction in grain size. We will also discuss the influence of the activation process and repeated hydrogen charging on substitutional disorder and grain size.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 286: Symposium J – Nanophase and Nanocomposite Materials , 1992, 209
Copyright
Copyright © Materials Research Society 1993

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References

REFERENCES

1. Reilly, J.J. and Wiswall, R.H. Jr., Inorg. Chem. 13, 218 (1974).Google Scholar
2. Trudeau, M.L., Schulz, R., Zaluski, L., Hosatte, S., Ryan, D.H., Doner, C.B., Tessier, P., Strèm-Olsen, J.O. and Neste, A. Van, Materials Science Forum 89–90 (1992)Google Scholar
3. Zaluski, L., Hosatte, S., Tessier, P., Ryan, D.H., Ström-Olsen, J.O., Trudeau, M.L. and Schulz, R., to be published in J. Alloys and CompoundsGoogle Scholar
4. Chu, B.L., S.M. Lee and Perng, T.P., Int. J. Hydrogen Energy 16, 413 (1991)Google Scholar
5. Eckert, J., Schultz, L. and Urban, K., J. Non-Cryst. Solids 172, 90 (1991).Google Scholar
6. Dolgin, D.P., Vanek, M.A., McGory, T. and Ham, D.J., J. Non-Cryst. Solids 87, 281 (1986).Google Scholar
7. Batalla, E., Strèm-Olsen, J.O., Altounian, Z., Boothroyd, D. and Harris, R., J. Mater. Res. 1, 765 (1986).Google Scholar
8. Hellstern, E., Fecht, H.J., Fu, Z. and Johnson, W.L., J. Mater. Res. 4, 1292 (1989).Google Scholar
9. Ray, R., Giessen, B.C. and Grant, N.J., Metall. Trans. 3, 627 (1972).Google Scholar
10. Murray, J.L., Bulletin of Alloy Phase Diagrams 2, 320 (1981).Google Scholar
11. Kaufman, L. and Bernstein, H., Computer Calculations of Phase Diagrams, Academic Press, New York, 1970 Google Scholar
12. Lukas, H.L., Henig, E.T. and Zimmermann, B., CALPHAD 1, 225 (1979).Google Scholar
13. Bormann, R., Gartner, F. and Zoltzer, K., J. Less-Common Metals 145, 19 (1988).Google Scholar
14. Bormann, R. and Zoltzer, K., Phys. Stat. Sol. A 131, 691 (1992).Google Scholar
15. Kivilahti, J.K. and Tarasova, O.B., Metal. Trans. A 18, 1679 (1987).Google Scholar
16. Dinsdale, A.T., SGTE Data fo Pure Elements, NPL Report, DMA(A), 1989 Google Scholar
17. Fruehan, R.J., Metal. Trans. 1, 3403 (1970).Google Scholar
18. Ohtani, H., Tanaka, T., Hasebe, M. and Nishizawa, T., CALPHAD 12, 225 (1988).Google Scholar
19. Gachon, J.C. and Hertz, J., CALPHAD 7, 1 (1983).Google Scholar
20. Wang, H., Luck, R. and Predel, B., Z. Metallkde. 82, 659 (1991).Google Scholar
21. DSC measurements of amorphous alloys sent by Sumiyama, K., being under investigationGoogle Scholar
22. Eckert, J., private communicationGoogle Scholar