Hostname: page-component-7b7567c8c-lpg2g Total loading time: 0 Render date: 2026-11-15T20:03:38.759Z Has data issue: false hasContentIssue false
  • English
  • Français

Xas Studies of Peo Based Polymer Electrolytes

Published online by Cambridge University Press:  16 February 2011

J. Mcbreena,
X. Q. Yang,
H. S. Lee and
Y. Okamoto
J. Mcbreena
Affiliation:
Brookhaven National Laboratory, Upton, NY 11973
X. Q. Yang
Affiliation:
Brookhaven National Laboratory, Upton, NY 11973
H. S. Lee
Affiliation:
Brookhaven National Laboratory, Upton, NY 11973
Y. Okamoto
Affiliation:
Polytechnic University, Brooklyn, NY 11201
Get access

Abstract

X-ray absorption spectroscopy (XAS) has been very useful in elucidation the structure of polymer electrolytes, in particular ion-ion and ion-polymer interactions. Several examples are discussed. One is the use of XAS to study the effect of temperature on ion pairing. The other is the elucidation of the mixed cation effect on electrolyte conductivity. Several investigations have indicated abnormally high oxygen coordination numbers for cations. These are discussed.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 369: Symposium U – Solid State Ionics IV , 1994, 559
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

1. Chadwick, A. V., in Applications of Synchrotron Radiation, eds. Catlow, C. R. A. and Greaves, G. N. (Blackie & Son Ltd., Glasgow, 1990), pp.171–200.Google Scholar
2. Grey, F. M., Solid Polymer Electrolytes (VCH Press, New York, 1991).Google Scholar
3. Schantz, S., J. Chem. Phys. 94, 6296 (1991).Google Scholar
4. Bernson, A. and Lindgren, J., Solid State Ionics 60, 37 (1993).Google Scholar
5. Bruce, P. G., Hardgrave, M. T. and Vincent, C. A., Solid State Ionics 53-56, 1087 (1992).Google Scholar
6. Fuller, T. F., Doyle, M. and Newman, J., J. Electrochem. Soc. 141, 1 (1994).Google Scholar
7. McLin, M. G. and Angell, C. A., J. Phys. Chem. 95, 9464 (1991).Google Scholar
8. Torell, L. M., Jacobsson, P., Sidebottom, D. and Petersen, G., Solid State Ionics 53-56, 1037 (1992).Google Scholar
9. Schantz, S., Torell, L. M., and Stevens, J. R., J. Chem. Phys. 94, 6862 (1991).Google Scholar
10. Kakihana, M.. Schantz, S. and Torell, L. M., J. Chem. Phys. 92. 6271 (1992).Google Scholar
11. Yang, X. Q., Chen, J., Harris, C. S., Skotheim, T. A., Boer, M. L. den, Mei, H., Okamoto, Y. and Kirkland, J., Mol. Cryst. Liq. Cryst. 160, 89 (1988).Google Scholar
12. Yang, X. Q., Chen, J., Harris, C. S., Skotheim, T. A., Okamoto, Y., Kirkland, J. and Boer, M. L. den, Phys. Rev. B40, 7948 (1989).Google Scholar
13. Yang, X. Q., Lee, H. S., McBreen, J., Xu, Z. S., Skotheim, T. A., Okamoto, Y. and Lu, F., J. Chem. Phys. 101, 3230 (1994).Google Scholar
14. Latham, R. J., Linford, R. G., Pynenburg, R. A. J. and Schlindwein, W. S., Electrochimica Acta 37, 1529 (1992).Google Scholar
15. Chowdari, B. V. R., Huq, R. and Farrington, G. C., Solid State Ionics 57, 49 (1992).Google Scholar
16. McBreen, J., Yang, X. Q., Lee, H. S. and Okamoto, Y., Electrochim. Acta, (1994) (submitted).Google Scholar
17. Mendolia, M. S. and Farrington, G. C., Electrochim. Acta 37, 1695 (1992).Google Scholar
19. Andrews, K. C., Cole, M., Latham, R. J., Lindford, R. G., Williams, H. M. and Dobson, B. R., Solid State Ionics 28/30, 929 (1988).Google Scholar
20. Bernson, A. and Lindgren, J., Solid State Ionics 60. 31 (1993).Google Scholar
21. McBreen, J., Yang, X. Q., Lee, H. S. and Okamoto, Y., J. Electrochem. Soc., (1994) (accepted).Google Scholar