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X-Ray Crystal Diffraction Study of Zr,Na-β-Alumina

Published online by Cambridge University Press:  25 February 2011

Wayne H. Pearson and
Joseph F. Lomax
Wayne H. Pearson
Affiliation:
Chemistry Department, 572 Holloway Rd., United States Naval Academy, Annapolis, MD, 21402-5026
Joseph F. Lomax
Affiliation:
Chemistry Department, 572 Holloway Rd., United States Naval Academy, Annapolis, MD, 21402-5026
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Abstract

The reaction of crystalline lithium-stabilized Na-β”-Alumina with zirconium(IV) chloride at 400°C for 303h has caused sodium ions to exchange with zirconium ions. An X-ray crystal diffraction study of both the parent lithium stabilized Na-β”-alumina (1) and the partially zirconium exchanged product (2) have been made at 147 K. Crystal data for 1: rhombohedral, R 3 m, a = 5.6037 (3), c = 33.6210 (86) Å, V = 914.31 (24) Å3. Crystal data for 2: rhombohedral, R 3 m, a = 5.5994 (5), c = 33.7711 (51) Å, V = 916.96 (16) Å3. Zirconiums in 2 reside, predominately, in the Beevers-Ross type site.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 293: Symposium U – Solid State Ionics III , 1992, 315
Copyright
Copyright © Materials Research Society 1993

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