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Published online by Cambridge University Press: 10 January 2013
Three orthovanadates ATh2(VO4)3with A = Li, Na, Ag have been synthesized by solid state reaction. Single crystals of AgTh2(VO4)3were obtained. This compound is isotypic with sheelite whose space group is I41/a(88). The two other compounds (A = Li, Na) have a zircon type structure: I41/ amd(141). Unit-cell parameters and powder diffraction data for the three compounds are reported.