Hostname: page-component-7b7567c8c-fvjsw Total loading time: 0 Render date: 2026-11-12T10:49:23.845Z Has data issue: false hasContentIssue false
  • English
  • Français

Crystal Data for LnKFe (CN)6·4H20, Ln=La, Ce, Pr, and Nd Compound

Published online by Cambridge University Press:  10 January 2013

D.F. Mullica and
E.L. Sappenfield
D.F. Mullica
Affiliation:
Departments of Chemistry and Physics, Baylor University, Waco, Texas 76798, U.S.A.
E.L. Sappenfield
Affiliation:
Departments of Chemistry and Physics, Baylor University, Waco, Texas 76798, U.S.A.
Get access

Abstract

Crystal data and a representative X-ray powder diffraction pattern are reported for a series of isomorphous compounds, LnKFe(CN)6.4H2O where Ln = La, Ce, Pr and Nd. They crystallize in the hexagonal space group P63/m (176) with Z = 2. A plot of the unit cell volume (V) versus the cube of the Ln ionic radius (r3) yields linearity with a correlation coeficient of 0.9998.

Information

Type
Research Article
Information
Powder Diffraction , Volume 4 , Issue 2 , June 1989, pp. 101 - 102
Copyright
Copyright © Cambridge University Press 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

Beall, G.W., Mullica, D.F., Milligan, W.O., Korp, J., & Bernal, I. (1978). Ada Crystallogr., B34, 1446–1449.CrossRefGoogle Scholar
Cotton, F.A. and Wilkinson, G. (1980). Advanced Inorganic Chemistry, 4th Ed., pp. 981–983. New York: J. Wiley and Sons.Google Scholar
Milligan, W.O., Mullica, D.F., & Perkins, H.O. (1982). Inorg. Chem. Acta 60, 35–38.CrossRefGoogle Scholar
Mullica, D.F., Milligan, W.O., & Oliver, J.D. (1979). Inorg. Nucl. Chem. Lett. 15, 1–5.CrossRefGoogle Scholar
Muljica, D.F., Sappenfield, E.L., & Perkins, H.O. (1988). J. Solid State Chem. 73, 65–70.CrossRefGoogle Scholar
Prandtl, W. & Mohr, S. (1938). Z. Anorg. Allg. Chem. 236, 243–251.CrossRefGoogle Scholar
Roof, R.B. Jr., (Personal Communication)Google Scholar
Shannon, R.D. (1976). Acta Crystallogr. A32, 751–767.CrossRefGoogle Scholar
Smith, G.S., & Snyder, R.L. (1979). J. Appl. Crystallogr. 23, 60–65.CrossRefGoogle Scholar
de Wolff, P.M. (1968). J. Appl. Crystallogr. 1, 108–113.CrossRefGoogle Scholar