Hostname: page-component-7b7567c8c-k5hsr Total loading time: 0 Render date: 2026-11-12T05:06:56.528Z Has data issue: false hasContentIssue false
  • English
  • Français

Structural characterization of dimercury(1+) pentacyanonitrosylferrate(2−), Hg2[Fe(CN)5NO]

Published online by Cambridge University Press:  10 January 2013

V. Venegas,
G. Rueda-Morales,
E. Reguera and
F. Caleyo
V. Venegas
Affiliation:
Escuela Superior de Física y Matemáticas, Departamento de Ciencia de Materiales, Instituto Politécnico Nacional, UP-ALM, Edif. 9. Lindavista 07738, México D.F., México
G. Rueda-Morales
Affiliation:
Escuela Superior de Física y Matemáticas, Departamento de Física, Instituto Politécnico Nacional, UP-ALM, Edif. 9. Lindavista 07738, México D.F., México
E. Reguera
Affiliation:
Escuela Superior de Física y Matemáticas, Departamento de Física, Instituto Politécnico Nacional, UP-ALM, Edif. 9. Lindavista 07738, México D.F., México
F. Caleyo
Affiliation:
Instituto Nacional de Investigaciones Nucleares, G. Ciencia de Materiales, AP 18-1027, Col. Escandón, México 11801, D.F., México
Get access

Abstract

The titled compound, Hg2[Fe(CN)5NO], was synthesized and studied by X-ray powder diffraction, infrared spectroscopy, Mössbauer spectroscopy, and atomic force microscopy. The results arising from this study indicate that this compound is anhydrous and crystallizes in the P222 orthorhombic symmetry. The unit cell parameters were quantified as a=16.5905(9) Å, b=12.3145(8) Å, and c=8.7576(5) Å. The measured and calculated density values are Dm=1.149 g/cm3 and Dc=1.145 g/cm3, respectively, with Z=2.

Keywords

Hexacyanidesnitrosylpentacyanides

Information

Type
New Diffraction Data
Information
Powder Diffraction , Volume 15 , Issue 3 , September 2000, pp. 193 - 197
Copyright
Copyright © Cambridge University Press 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

Castellano, E. E., Piro, O. E., and Rivero, B. E. (1977). “The crystal and molecular structure of strontium nitroprusside tetrahydrate,” Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 33, 1725–1728.CrossRefGoogle Scholar
Fernández-Bertrán, J., and Reguera, E. (1995). “The CN stretch of insoluble metal nitroprussides as a sensor of ligand-outer cation interactions,” Spectrosc. Lett. 28, 1015–1020.CrossRefGoogle Scholar
Gentil, L. A., Baran, E. J., and Aymonino, P. J. (1976). “On some divalent transition and post-transition metal nitroprussides,” Inorg. Chim. Acta 20, 251–262.CrossRefGoogle Scholar
Mighell, A. D., Hubbard, C. R., and Stalik, J. K. (1981). “NBS*AIDS80: A FORTRAN program for crystallographic data evaluation,” U.S. Natl. Bur. Stand. Tech. Note 1141. (NBS*AIDS83 is an expanded version of NBS*AIDS80).Google Scholar
Mullica, D. F., Sappenfield, E. L., Tippin, D. B., and Leschnitzer, D. H. (1989). “Synthesis spectroscopic studies, and crystal structure analysis of zinc nitrosylpentacyanoferrate trihydrate, Zn[Fe(CN)5NO].3H 2O,”Inorg. Chim. Acta 164, 99–103.CrossRefGoogle Scholar
Mullica, D. F., Tippin, D. B., and Sappenfield, E. L. (1990). “The crystal structure of two nitroprussides: Mn[Fe(CN)5NO].3H 2O and Cd[Fe(CN)5NO].3H 2O,”Inorg. Chim. Acta 174, 129–135.Google Scholar
Mullica, D. F., Wardojo, T. A., and Sappenfield, E. L. (1993). “Synthesis, spectroscopic, and structural studies of two mixed transition metal complexes,” J. Solid State Chem. 106, 379–387.CrossRefGoogle Scholar
Puente, G., Rigotti, G., Rivero, B. E., Podjarny, A. D., and Castellano, E. E. (1980). “Structure of calcium nitroprusside tetrahydrate,” Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 36, 1472–1475.CrossRefGoogle Scholar
Reguera, E., Bertrán, J. F., Miranda, J., and Portilla, C. (1992). “Study of the dependence of Mössbauer parameters on the outer cation in nitroprussides,” J. Radioanal. Nucl. Chem. 165, 191–201.CrossRefGoogle Scholar
Reguera, E., Dago, A., Gómez, A., and Bertrán, J. F. (1996). “Structural changes in insoluble metal nitroprussides on ageing,” Polyhedron 15(18),3139–3145.CrossRefGoogle Scholar
Rigotti, G., Puente, G., and Rivero, B. E. (1980). “Structure of thallium nitroprusside,” Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B 36, 1475–1477.Google Scholar
Smith, G. S., and Snyder, R. L. (1979). “Fn: A criterion for rating powder diffraction patterns and evaluating the reliability of powder-pattern indexing,” J. Appl. Crystallogr. 12, 60–65.Google Scholar
Soria, D. B., Amalvy, I. J., Piro, O. E., Castellano, E. E., and Aymonino, P. J. (1996). “Crystal and molecular structure determination, TGA-DTA, and infrared and Raman spectra of rubidium nitroprusside, Rb 2[Fe(CN)5NO],”J. Chem. Crystallogr. 26, 325–330.CrossRefGoogle Scholar
Venegas, V., Gómez, A., and Reguera, E. (1999). “Powder X-ray diffraction study of disilver(1+) pentacyanonitrosylferrate(2−),”Powder Diffraction 14, 219–221.Google Scholar
Werner, P.-E., Eriksson, L., and Westdahl, M. (1985). “TREOR, a semiexhaustive trial and error powder indexing program for all symmetries,” J. Appl. Crystallogr. 18, 367–370.CrossRefGoogle Scholar
Wolff, P. M. (1968). “A simplified criterion for the reliability of a powder pattern indexing,” J. Appl. Crystallogr. 1, 108–113.CrossRefGoogle Scholar