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Steering a thermally activated micromotor with a nearby isothermal wall

Published online by Cambridge University Press:  11 March 2021

Antarip Poddar
Affiliation:
Department of Mechanical Engineering, Indian Institute of Technology Kharagpur, Kharagpur, West Bengal 721302, India
Aditya Bandopadhyay
Affiliation:
Department of Mechanical Engineering, Indian Institute of Technology Kharagpur, Kharagpur, West Bengal 721302, India
Suman Chakraborty*
Affiliation:
Department of Mechanical Engineering, Indian Institute of Technology Kharagpur, Kharagpur, West Bengal 721302, India
*
†Email address for correspondence: suman@mech.iitkgp.ernet.in

Abstract

Selective heating of a microparticle surface had been observed to cause its autonomous movement in a fluid medium due to self-generated temperature gradients. Here, we theoretically investigate the response of such an auto-thermophoretic particle near an isothermal planar wall. We derive an exact solution of the energy equation and employ the Lorentz reciprocal theorem to obtain the translational and rotational swimming velocities in the creeping-flow limit. We report fixed points for vertical movement of the micromotor for its specific orientations relative to the wall. The critical wall gap for fixed points shows unique non-monotonic dependence on the metallic coating coverage on the particle. Also, the micromotor trajectories can be switched either from wall-bound sliding or stationary state to escape from the near-wall zone by tuning the particle and the surrounding fluid pair thermal conductivity contrast. The scenario holds several exclusive distinguishing features from the otherwise extensively studied self-diffusiophoresis phenomenon near an inert wall, despite obvious analogies in the respective constitutive laws relating the fluxes with the gradients of the concerned forcing parameters. The most contrasting locomotion is the ability of a self-thermophoretic micromotor with a large heated cap to migrate towards the wall even if it is initially directed away from the wall. During the stationary states of swimming, the cold portion on the micromotor surface faces away from the wall under all conditions. Such unique aspects hold the potential of being harnessed in practice towards achieving intricate control over the autonomous motion of microparticles in thermally regulated fluidic environments.

Information

Type
JFM Papers
Creative Commons
Creative Common License - CCCreative Common License - BY
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
© The Author(s), 2021. Published by Cambridge University Press
Figure 0

Figure 1. (a) Schematic of an auto-thermophoretic microswimmer near a constant temperature plane wall. The orange and blue faces of the particle represent the heat-absorbing metallic cap (hot) and uncoated (cold) areas on the micromotor surface, respectively. The angular orientation of the director vector $\boldsymbol {{d}}$ is denoted by the angle $\theta _{p}$, measured in the clockwise direction from the positive $z$-axis. The coverage area of the metallic cap is represented by the angle $\varphi _{cap}$. The centre of the particle is at a distance of $\tilde {h}$ from the wall. (b) Schematic description of the bispherical coordinate used in the present study.

Figure 1

Figure 2. Spatial variation of the scaled temperature $(\bar {\mathcal {T}}=T/(T_{max}-T_{min}))$ in the $x$–$z$ plane, both inside the microswimmer and in the surrounding fluid medium, for a fixed wall-swimmer distance of $\delta =0.5$ and a coverage angle of the metal coating $\varphi _{cap}=90^{\circ }$. The orientation angle ($\theta _{p}$) is $60^{\circ }$ in (a–c), while it is $120^{\circ }$ in (d–f). The thermal conductivity contrast has been varied as 0.1, 1 and 10 from left to right panels. The thick orange arc in each figure represents the metal-coated area of the surface. $(a,d)\, \mathcal {K} = 0.1, (b,e)\ \mathcal {K} = 1,\ (c,f)\ \mathcal {K} = 10.$

Figure 2

Figure 3. (a,b) Surface temperature $(\mathcal {T}_S)$ variation along the surface for different wall distances and thermal conductivity ratios, respectively. Here, the angle $\theta _d$ is at the surface of the microswimmer, measured clockwise from the director axis $\boldsymbol {d}$. In (a), we have taken $\mathcal {K}=1$, while in (b) $\delta =1$. Other parameters are $\varphi _{cap} =90 ^{\circ }$ and $\theta _{p} =60 ^{\circ }$. In (c,d), similar variations are shown for a different inclination of $\theta _{p} = 120 ^{\circ }$. In each plot, the central vertical line provides visual assistance to identify the degree of asymmetry around the director axis, $\boldsymbol { d}$.

Figure 3

Figure 4. (a) Variation of temperature heterogeneity parameter, $\mathcal {H}_T$, with high $\mathcal {K}$ for different gaps from the wall. Here, a low coating coverage, $\varphi _{cap} =40 ^{\circ }$, has been chosen. (a) Variation of $\mathcal {H}_T$ with high coverage angles, $\varphi _{cap}$, for different gaps from the wall. Here, a low conductivity ratio, $\mathcal {K}=0.1$, has been chosen. In both panels, $\theta _{p}=180^{\circ }$. The wall-swimmer configuration has been shown as an inset to the panel (a).

Figure 4

Figure 5. In (a), the unbounded swimming velocity magnitude $|\boldsymbol {V}_{ub}|$ is shown in the $\mathcal {K}-\varphi _{cap}$ plane. In (b,c), the variations in velocity components ($V_z$ and $V_x$, respectively) with the thermal conductivity contrast ($\mathcal {K}$) are shown for both unbounded and near-wall scenarios. The orientation and velocity direction of the particle are shown schematically in each figure.

Figure 5

Figure 6. Variation of translational and rotational velocity components of the microswimmer with distance from the wall $(\delta )$ and various thermal conductivity ratios $(\mathcal {K})$. The heated cap coverage is identically chosen as $\varphi _{cap} =90 ^{\circ }$ for all the cases. In (a,b), $\theta _{p} =60 ^{\circ }$ and $120\,^{\circ }$, respectively. Due to symmetry reasons, the (c) and (d) are applicable for both $\theta _{p}= 60 ^{\circ }$ or $120\,^{\circ }$.

Figure 6

Figure 7. Variation of the vertical thermophoretic thrust $(F_z^{(Thrust)})$ with $\delta$ and for different values of $\mathcal {K}$. The parameters are similar to figure 6(b).

Figure 7

Figure 8. Variation of wall-parallel translational and rotational velocities of the microswimmer with distance from the wall $(\delta )$ and different thermal conductivity ratios $(\mathcal {K})$. Other parameters are chosen as $\varphi _{cap} =140 ^{\circ }$ and $\theta _{p} =150 ^{\circ }$.

Figure 8

Figure 9. Detailed variation of different terms in (3.3b). The parameters are similar to figure 8(b). The yellow bubble signifies the location where $C_y^{(Thrust)}\times f_{x}^T$ becomes smaller than $F_x^{(Thrust)}\times f_{y}^T$.

Figure 9

Figure 10. (a) Phase map demarcating the limits of metallic coating coverage, $\varphi _{cap}$, and the swimmer orientation, $\theta _p$, for the existence of fixed points in the vertical component of velocity, $V_z$. (b) Critical gap size, $\delta _{cr}$, vs. the coating coverage, $\varphi _{cap}$, for different swimmer orientations, $\theta _p$. Data points have been obtained by searching in a grid of 50 equally spaced points (in log scale) for $\delta$ and with a linear increment of $2.5^{\circ }$ for $\varphi _{cap}$. (c) The vertical velocity, $V_z$, vs. gap thickness, $\delta$, for different coating coverages and $\theta _p=50^{\circ }$.

Figure 10

Figure 11. Case-I: (a) phase map of the microswimmer trajectories on the $\mathcal {K}-\theta _{p,0}$ plane. (b) Comparison of swimming trajectories for different thermal conductivity contrast with $\theta _{p,0}=90^{\circ }$. In panel (i), $\mathcal {K}=10$, and in panel (ii), $\mathcal {K}=5$. In panel (i), the microswimmer escapes from the wall and attains a fixed orientation $\theta _p= 48.7 ^{\circ }$. In panel (ii), it slides along the wall with a fixed velocity of $V_{slide}= 0.018$ with a fixed orientation $\theta _{p,end}= 33.23 ^{\circ }$. For both panels (a) and (b), we have chosen $\varphi _{cap}=25^{\circ }$ and $h_ 0=2$. (c) Variation of sliding velocity $(V_{slide})$ and final orientation angle $(\theta _{p,{end}})$ with $\mathcal {K}<\mathcal {K}_{cr}$ as per panel (b). Panels (d,e) correspond to the variations in $\theta _{p}$ and $\theta _{v}$ for the trajectories in panels (b)(i) and (b)(ii), respectively. Hereafter, the yellow arrows on micromotors indicate the instantaneous director orientations in that trajectory. Black arrows in panel (b) indicate the direction of impending motion, while the corresponding director direction $(\theta _p)$ and trajectory direction $(\theta _v)$ are shown in panels (d) and (e).

Figure 11

Figure 12. Case-II: (a,b) phase map of the microswimmer trajectories on the $\mathcal {K}-\theta _{p,0}$ plane for coverage angles $\varphi _{cap}=40 ^{\circ }$ and $50^{\circ }$, respectively. In both panels, $h_0=2$. (c) Comparison of swimming trajectories for different thermal conductivity contrast with $\theta _{p,0}=100 ^{\circ }$ and $\varphi _{cap}=40 ^{\circ }$. In panel (i), $\mathcal {K}=1$, and in panel (ii), $\mathcal {K}=0.1$. In panel (i) the microswimmer escapes from the wall and attains a fixed orientation $\theta _p= 36.5^{\circ }$. In panel (ii), it becomes stationary at position $(x_{stop},\delta _{stop})=(3.92,0.027)$ and a vertical fixed orientation, i.e. $\theta _p = 0 ^{\circ }$. In panels (d) and (e), we have shown the variations of $\theta _{p}$ and $\theta _{v}$ with $x$ for the trajectories in panels (c)(i) and (ii), respectively.

Figure 12

Figure 13. Case-III: (a) phase map of the microswimmer trajectories on the $\mathcal {K}-\theta _{p,0}$ plane for coverage angle $\varphi _{cap}=145^{\circ }$. (b) Comparison of swimming trajectories for different thermal conductivity contrast with $\theta _{p,0}=10 ^{\circ },\varphi _{cap}=145^{\circ }$ and $h_0=2$. In panel (i), $\mathcal {K}=1$, and in panel (ii), $\mathcal {K}=0.1$. In panel (i), the microswimmer escapes from the wall and attains a fixed orientation $\theta _p= 7.8 ^{\circ }$. In panel (ii), it becomes stationary at position $(x_{stop},\delta _{stop})=(0.42,0.015)$ and a vertical fixed orientation, i.e. $\theta _{p,stop} = 0 ^{\circ }$.

Figure 13

Figure 14. Phase maps categorizing the swimming behaviours of the auto-thermophoretic microswimmer for different values of the coverage angle of the metal cap $(\varphi _{cap})$ and initial launching angle $(\theta _p)$. (a), (b) and (c) correspond to different initial heights as shown. The thermal conductivity ratio has been chosen as $\mathcal {K}=1$. Here the phase maps have been constructed on a grid of $5^\circ$ intervals on both the coordinates. $(a)\, \delta_{0} = 1, (b)\, \delta_{0} = 4,\ (c) \delta_{0} = 6$

Figure 14

Figure 15. Panels (a,b) show the direction of surface flow for low and high coverage angles $\varphi _{cap}=60^\circ$ and $160^\circ$, respectively. Here, the background colour denotes the scaled temperature field. (c) Variation of surface temperature along the surface of the micromotor for different coverage angles $(\varphi _{cap})$. Here, $\theta _{p} =10 ^ \circ$ has been chosen for (a–c). (d) Variation of the vertical component of the micromotor velocity $(V_z)$ with $\varphi _{cap}$ for different $\theta _{p}$. (e) Variation of surface temperature along the surface of the micromotor for different coverage angles $(\varphi _{cap})$ with $\theta _{p}=120^\circ$. Other parameters are chosen as $\delta =1$ and $\mathcal {K} =1$.

Figure 15

Figure 16. Swimmer surface temperature variation $(\mathcal {T}_S)$ for different distances from the wall $(\delta )$. Panels (a) and (b) correspond to coverage angles of $\varphi _{cap}=120^\circ$ and $150^\circ$, respectively. (c,d) The solid-black and green-dashed arrows indicate the direction of surface flow. We have chosen $\varphi _{cap}=120^\circ$ and $150^\circ$, respectively, in the two panels. The background colours denote the scaled temperature field. The other parameters are $\mathcal {K}=1$, $\delta =0.1$ and $\theta _p=135^\circ$. The green and yellow bubbles denote the minimum and maximum temperature locations on the plots, respectively.

Figure 16

Figure 17. Vertical microswimmer velocity vs. its distance from the wall for different orientation angle $(\theta _p)$. Here the fixed parameters are $\varphi _{cap}=90^\circ$ and $\mathcal {K}=1$.

Figure 17

Figure 18. Variation of wall-parallel translational and rotational velocities of the microswimmer with distance from the wall $(\delta )$ for different orientation angles $(\theta _{p})$. Other parameters are chosen as $\varphi _{cap} =150 ^{\circ }$ and $\mathcal {K} =1$.