1. Introduction
The study of the interaction of an ultrashort laser pulse with targets, such as solids, gases and clusters, has been considered to be a uniquely convenient approach for the development of a compact and versatile pulsed source of ionizing radiation (Ditmire et al. Reference Ditmire, Springate, Tisch, Shao, Mason, Hay, Marangos and Hutchinson1998; Fomichev et al. Reference Fomichev, Popruzhenko, Zaretsky and Becker2003; Scaffidi et al. Reference Scaffidi, Pender, Pearman, Goode, Colston, Carter and Angel2003; Tiwari & Tripathi Reference Tiwari and Tripathi2006; Spangle et al., Reference Spangle, Essayer and Ting2011; Nemati Siahmazgi Reference Nemati Siahmazgi and Jafari2019a,Reference Nemati Siahmazgi and Jafarib; Nguyen et al. Reference Nguyen, Klinskikh, Meleshenko and Semenov2019; Roozehdar Mogaddam et al. Reference Roozehdar Mogaddam, Sepehri Javan, Javidan and Mohammadzadeh2019). Cluster targets absorb a considerable amount of laser energy, owing to their high local density properties, when interacting with the laser. When nanoclusters are heated by a femtosecond laser, the electric field of the laser causes ionization and converts the nanoclusters into a nanoplasma medium. Furthermore, interaction of the nanoclusters with the laser field leads to the expansion of the nanoplasma and a heating to high temperatures. In this way, fast electrons (Kumarappan et al. Reference Kumarappan, Krishnamurthy and Mathur2002; Springate et al. Reference Springate, Aseyev, Zamith and Vrakking2003), energetic and highly charged ions (Döppner et al. Reference Döppner, Müller, Przystawik, Göde, Tiggesbäumker, Meiwes-Broer, Varin, Ramunno, Brabec and Fennel2010; Bochkarev et al. Reference Bochkarev, Faenov, Pikuz, Brantov, Kovalev, Skobelev, Pikuz, Kodama, Popov and Bychenkov2018; Komar et al. Reference Komar, Kazak, Almassarani, Meiwes-Broer and Tiggesbäumker2018), and X-ray and ultraviolet photons (Gordienko et al. Reference Gordienko, Makarov, Rakov and Savelev2005; Garmatina et al. Reference Garmatina, Zhvaniya, Potemkin and Gordienko2018; Nemati Siahmazgi Reference Nemati Siahmazgi and Jafari2019a,Reference Nemati Siahmazgi and Jafarib) are produced.
As is known, the nonlinear effects in the laser–cluster interaction lead to the generation of optical harmonics (Pysher et al. Reference Pysher, Miwa, Shahrokhshahi, Bloomer and Pfister2011), self-focusing (Schmittberger & Gauthier Reference Schmittberger and Gauthier2014) and nonlinear absorption of laser radiation (Nemati Siahmazgi Reference Nemati Siahmazgi and Jafari2019a,Reference Nemati Siahmazgi and Jafarib).
According to the high-absorption feature of the laser energy by the clusters (compared with solids and gases), X-rays are generated from the interaction of a laser beam with a cluster target with a higher efficiency than with the solid or gaseous targets. X-ray emission has found application in many areas of science and technology, such as astronomy (Chkhalo et al. Reference Chkhalo, Mikhailenko, Pestov, Polkovnikov, Zorina, Zuev, Kazakov, Milkov, Strulya and Filichkina2019), security systems (Gupta et al. Reference Gupta, Sinno, Glover, Paulter and Bovik2019), X-ray microscopy (Pfeiffer Reference Pfeiffer2018), lithography (Wu et al. Reference Wu, Liu, Zhu, Gu, Chen, Xue, Zhao, Wu, Tai and Ouyang2018; Ahmadirad et al. Reference Ahmadirad, Yazdani and Rahimi2019), radiation therapy (Myint et al. Reference Myint, Smith, Gollins, Wong, Rao, Whitmarsh, Sripadam, Rooney, Hershman and Pritchard2018) and spectroscopy (Owens et al. Reference Owens, Mao, Canfield, Grigoropoulos, Mao and Russo2010; Weidler et al. Reference Weidler, Schuch, Knaus, Stenner, Hoch, Maljusch, Schäfer, Kaiser and Jaegermann2017).
A nanoplasma is defined by the energy and interactions of its constituent species by limiting at least one dimension of the plasma to the nanometre range (similar to a nanosolid). In fact, a nanoplasma is a special type of plasma that is characterized by spatial confinement, degeneracy, coupling and ideality. By reducing the size to the nanoscale, a large number of charged particle types (and hence, density) is required to exhibit a plasma-like behaviour. Hence, solids are suitable to provide a sufficient density of charged carriers to produce a nanoplasma. This leads to the definition of a nanoplasma as a fully or partially ionized, overall charge neutral, electrically conducting medium that shows screened Coulomb interactions and a collective behaviour of charged species on the surface of a solid or in the solid matter on the nanometre scale (Ostrikov et al. Reference Ostrikov, Beg and Ng2016).
Many efforts have been made on X-ray systems by various researchers both theoretically and experimentally (Dorchies et al. Reference Dorchies, Blasco, Bontè, Caillaud, Fourment and Peyrusse2008; Kumar et al. Reference Kumar, Singh and Verma2014; Balakin et al. Reference Balakin, Dzhidzhoev, Gordienko, Esaulkov, Zhvaniya, Ivanov, Kotelnikov, Kuzechkin, Ozheredov and Panchenko2017; Dorchies et al. Reference Dorchies, Jourdain, Lecherbourg and Renaudin2018). Dorchies et al. (Reference Dorchies, Blasco, Bontè, Caillaud, Fourment and Peyrusse2008) presented measurements of sub-picosecond duration of multi-keV X-ray pulses emitted from laser-irradiated Ar clusters. They observed that use of a femtosecond laser pulse duration ($400 \pm 100\;{\rm fs}$
) can be appropriate for application in the emerging field of ultrafast X-ray science. Balakin et al. (Reference Balakin, Dzhidzhoev, Gordienko, Esaulkov, Zhvaniya, Ivanov, Kotelnikov, Kuzechkin, Ozheredov and Panchenko2017) theoretically investigated the X-ray emission and terahertz (THz) generation in single-colour and dual-colour high-power femtosecond-laser-irradiated clusters. They analytically calculated the power and the spectrum of the X-ray radiation with a control of the THz radiation. They found that the THz emission strongly decreased under a shorter laser pulse duration, whereas, owing to the rapid rise of the population of outer electrons, the X-ray emission was enhanced. A theoretical study of heating a cluster with an intense Gaussian laser beam and the subsequent X-ray emission was presented by Kumar et al. (Reference Kumar, Singh and Verma2014). They showed that the electron temperature rises sharply near the plasma resonance, $\omega = \omega _{pe}/\sqrt 3$
. Dorchies et al. (Reference Dorchies, Jourdain, Lecherbourg and Renaudin2018) performed a comparison between the X-ray emission of nanocluster targets and solid targets. They found, with an emphasis on the specific role of the target geometry, that spherical hydrodynamic expansion of the cluster accelerated the drop in density and temperature, and then the observed X-ray duration from the cluster became shorter than that from the solid target.
The X-ray emission from a Gaussian laser beam irradiated on a harmonic (uniform) nanocluster has already been discussed by Kumar & Tripathi (Reference Kumar and Tripathi2013). In this study, we consider an anharmonic nanocluster that is exposed to Gaussian and super-Gaussian lasers. We theoretically study the X-ray emission from a short-pulse Gaussian laser beam irradiated on an anharmonic nanocluster. Owing to the high local density of the nanocluster, nanocluster atoms are heated and a nanoplasma is formed. At the primary step of nanoplasma existence, arising from the non-elastic energetic electron collisions with ions and their excitation, the ions emit X-ray radiation. Owing to the non-uniform distribution of ions, which implies an anharmonic cluster, it is better to employ a non-harmonic potential (such as polynomial potentials). In this case, similar to a harmonic cluster distribution, the restoring force will also be nonlinear. Kumar et al. (Reference Kumar and Tripathi2014) studied the generation of harmonic and nonlinear absorption in a laser–anharmonic cluster interaction. In a Gaussian laser–anharmonic cluster interaction, the fluctuation of the nanoplasma electrons will be nearly comparable to the cluster radius in the anharmonic nanocluster, then we expect that the heating rate and the expansion of the cluster electrons will notably change, and consequently the X-ray emission will be significantly enhanced. We analytically derive relations for the heating rate and expansion of the collisional nanoclustered plasma heated by a Gaussian laser beam in § 2. In § 3, Bremsstrahlung X-ray emission is analytically evaluated. In § 4, we discuss the numerical results. Finally, conclusions are presented in § 5.
2. Anharmonic cluster heating rate and expansion
Consider an atomic cluster with density $n_c$
and radius $r_{c0}$
. The equilibrium free electron density of each cluster is specified by $n_{c0}$
. A Gaussian laser beam of frequency $\omega$
and wavenumbers k propagates through the cluster. The electric field of the laser beam is given by

Under the electric field of the laser, the cluster electrons oscillate in the y direction, ${\rm \Delta }\hat{e}_y$
. As the electron oscillates, a space charge is produced and a restoring force is applied to it. A schematic of the electron oscillation in the laser field is shown in figure 1. The third-order electric susceptibility of the plasma is totally assumed to result from the motion of a rigid cold core within the ion potential well. Until a uniform ion distribution will generate a harmonic potential and while the electron oscillations are small, compared with the cluster radius, the restoring force is ${-}m\omega _{pe0}^2 \varDelta {\rm /}3$
. Any deviation from uniformity will present an anharmonic component to the electric potential. Because the cluster is symmetrically spherical, we can express the potential of the cluster as a polynomial expansion, i.e. $V(r) = {\textstyle{1 \over 2}}\omega _0^2 r^2 + {\textstyle{1 \over 4}}br^4 + \cdots$
. In this case, the oscillation of electrons becomes comparable to the cluster radius, and restoring force (for ${r}^{\prime} > r_{c0}$
) becomes (Kumar & Tripathi Reference Kumar and Tripathi2013)
where $\omega _{pe0}^2 = 4{\rm \pi} n_{e0}e^2/m$
, e and m are the electron plasma frequency, charge and mass of electron, respectively. Therefore, the motion equation of cluster electrons in the laser electric field and the restoring force of space charges is
where $\nu$
is the electron–ion collision frequency. Using the well-known perturbative method, we solve (2.3) as

Using (2.3), we can derive the first-, second- and third-order momentum equations as follows:
so that the solutions of these equations become:



Schematic representation for the cluster electron oscillation in the laser field.

To compare the ratio of $\varDelta ^{(1)}$
to $r_{c0}$
, variation of the first-order normalized oscillation amplitude $(\varDelta ^{(1)}/r_{c0})$
as a function of the normalized frequency is plotted in figure 2. As shown in figure 2, the oscillation amplitude is comparable to the cluster radius at the intensities $I\approx 10^{13}\;{\rm W}\;{\rm c}{\rm m}^{{-}2}$
, $10^{14}\;{\rm W}\;{\rm c}{\rm m}^{{-}2}$
and $10^{15}\;{\rm W}\;{\rm c}{\rm m}^{{-}2}$
. For $I > 10^{16}\;{\rm W}\;{\rm c}{\rm m}^{{-}2}$
, the oscillation amplitude becomes larger than the cluster radius. In fact, for $I < 10^{16}\;{\rm W}\;{\rm c}{\rm m}^{{-}2}$
, the amplitude of the oscillation is not large enough to cause the Coulomb explosion, thus the ions in the cluster can be assumed as a static background. The velocity of the oscillation of cluster electrons may be written as

Normalized oscillation amplitude as a function of the normalized frequency for different laser field intensities.

When resonance occurs, that is, when the electron density of the cluster triples the critical density, i.e. $\omega _{pe0} = \sqrt 3 \omega$
, the rates of heating and expansion of the cluster increase. In the adiabatic condition, we have $T_eV^{\gamma -1} = {\rm const} .$
, where V is the volume of the cluster equal to $4{\rm \pi} r_c^3 /3$
and $\gamma$
denotes the ratio of specific heats. The average heating rate of the cluster electrons is obtained under the influence of the laser electric field as well as the cluster expansion under adiabatic conditions as follows:
where $\gamma = 5/3$
, and rc and Te are the cluster radius and the temperature of cluster electron, respectively. As the radius of the cluster increases, its average density decreases, which keeps $\omega _{pe}^2 r_c^3 = {\rm constant}$
, i.e. $\omega _{pe}^2 = \omega _{pe0}^2 (r_c/r_{c0})^{{-}3}$
(Tiwari & Tripathi Reference Tiwari and Tripathi2006), where $\omega _{pe0}$
and rc 0 are the initial cluster electron plasma frequency and the initial cluster radius, respectively. The collision frequency is related to the electron temperature as $\nu = \nu _0(T_e/T_0)^{-{3 / 2}}$
(Kumar & Tripathi Reference Kumar and Tripathi2009, Reference Kumar and Tripathi2011), where T 0 is the electron temperature at t = 0. By defining normalized parameters as $\xi = T_e/T_0$
, $b_1 = \omega ^2/\nu _0^2$
, $d = \omega _{pe0}^2 /\omega ^2$
and $\eta = r_c/r_{c0}$
, we replace these into (2.12) as

where $\alpha = (eA_{L0}/\omega )(\sqrt {{\rm exp}[{-}r^2/r_0^2 ]/mT_0} = \alpha _0\sqrt {{\rm exp}[{-}r^2/r_0^2 ]}$
, ${t}^{\prime} = t-z/c$
and $\tau = \nu _0{t}^{\prime}$
. The radius of the cluster expands as
where cs is the velocity of sound, mi is the ion mass and therefore we derive the time average of the cluster radius rate as
3. Bremsstrahlung X-ray emission
The electrons that acquire enough energy from the laser field and leave the cluster are called free electrons. These free electrons are adjacent to the ions and are absorbed by the ions in the nanoplasma medium. When these electrons, with an initial velocity Ve, pass in the vicinity of the ions with the ion charge state, z, and the impact parameter, b, they accelerate and radiate in the X-ray regime. The electron irradiated energy, using the Larmor formula (Jackson Reference Jackson1962), is

The electron acceleration is a function of time in the X-ray regime; therefore, Fourier analysis of the acceleration is necessary. The electron acceleration and its Fourier transform are achieved as

where $K_0(\omega b/V_e)$
and $K_1(\omega b/V_e)$
are the modified Bessel functions. According to the Parsval relation, the energy of a signal is equal to its Fourier transform energy, $\int_{-\infty }^\infty {{|{a_c(t)} |}^2\,{\rm d}t} = {\rm \pi}\int_0^\infty {{|{a_c(\omega )} |}^2\,{\rm d}\omega }$
. As a result, the energy emitted by the electron becomes:

Thus, the radiation power per electron is
where, using the law of conservation of angular momentum, $b_{\min } = \hbar /mV_e$
, $b_{\max }\approx V_e/\omega$
(Krane Reference Krane1996) and ni is the number of the electron–ion collisions per unit time in b to b + db. The frequency of ω corresponds to electrons having a velocity as $V_e > \sqrt {2\hbar \omega /m}$
. Considering the Maxwellian velocity distribution function, the power radiated per unit frequency interval per unit becomes:

The total power radiated per unit frequency for the plasma channel of length L is obtained as
After solving (3.5) and (3.6) for $n_i = n_e$
, we obtain

where $v_{th}^2 = T_0/m$
is the electron thermal velocity. Using the normalization factor $P_B^0 = (m\omega _{pe0}^4 )/(n_{e0}c)$
, we get

4. Numerical results
In this section, we study numerically the heating rate of the electrons and the expanding of the radius rate of the cluster by solving the coupled equations (2.13) and (2.15). In figure 3, the normalized electron heating rate of a deuterium cluster as a function of normalized time for different values of radial locations is plotted for nc = 1013 cm−3, rc 0 = 10−6 cm located at $r/r_0 = 0.3$
, 0.7 and 0.1, when the parameters are $I\approx 10^{14}\;{\rm W}\;{\rm c}{\rm m}^{{-}2}$
, r 0 = 10−2 cm, g = 0.3, b 1 = 105, d = 5, $\omega _{pe0} = 5 \times 10^{15}\;{\rm rad}\;{\rm s}^{{-}1}$
, $\hbar \omega /T_0 = 10$
, $\alpha _0 = 0.57$
and $\nu _0\tau _L = 1$
. In figure 3, a sharp peak at the resonance time is observed. Furthermore, the heating rate becomes large at a location closer to the radial axis of the laser.
Normalized electron heating rate of cluster as a function of normalized time for different radial locations.

The variation of the electron heating rate of the cluster as a function of normalized time for the anharmonic and harmonic clusters is plotted in figure 4. At the resonant frequency, the temperature of the electrons in the anharmonic cluster is higher than that of them in the harmonic cluster (Kumar et al. Reference Kumar, Singh and Verma2014), owing to the nonlinear restoring force. Figure 5 shows the variation of the electron heating rate of the cluster as a function of normalized time for different values of laser field intensities. It is found that the electron heating rate of the cluster is larger at more intensities.
Normalized electron heating rate of cluster as a function of normalized time for anharmonic and harmonic clusters.

Normalized electron heating rate of cluster as a function of normalized time for different laser field intensities.

The three-dimensional (3-D) plot of the electron heating rate of the deuterium cluster as a function of the normalized time and the normalized radial locations is depicted in figure 6.
Normalized electron heating rate of cluster as a function of normalized time and of normalized radial locations.

The variation of the normalized cluster radius for the deuterium cluster as a function of the normalized time is shown in figure 7. In this figure, before the resonance time, the cluster radius slowly expands; however, when resonance occurs, the radius of the cluster expands rapidly.
Normalized average cluster radius as a function of normalized time for different radial locations.

The variation of the cluster radius as a function of the normalized time for the harmonic and anharmonic clusters is plotted in figure 8. As shown in figure 8, after the resonance time, the harmonic and anharmonic cluster radii expand gradually. In addition, the variation of the anharmonic cluster radius is almost identical to the harmonic cluster radius (Kumar et al. Reference Kumar, Singh and Verma2014).
Normalized average cluster radius as a function of normalized time for harmonic and anharmonic clusters.

Figure 9 shows the variation of the normalized cluster radius as a function of the normalized time for various laser field intensities. It is found that by moving away from the radial axis of the laser, i.e. for large values of $r/r_0$
, a reduction in the expansion of the cluster radius occurs.
Normalized average cluster radius as a function of normalized time for different laser field intensities.

From figure 9, it is found that with increasing the intensity of the laser field, the radius of the cluster is increased. Additionally, the 3-D variation of the cluster radius as a function of the normalized time and of the normalized radial locations, $r/r_0$
is plotted in figure 10.
Normalized average cluster radius as a function of normalized time and of normalized radial locations.

The normalized X-ray emission as a function of the normalized time for $\hbar \omega /T_0 = 12$
is drawn in figure 11. As shown in figure 11, the emission of X-rays has a sharp peak at the resonance time, then it slowly decreases, and at the plasma frequency of the cluster electrons less than the plasma resonance, the rate of Bremsstrahlung encounters is not sufficient to produce X-rays.
Normalized X-ray emission as a function of the normalized time for the deuterium cluster.

A comparison of the spectra of Bremsstrahlung X-ray radiation of deuterium, helium, neon and argon clusters is presented in figure 12. In the laser–nanocluster interaction, a significantly higher X-ray emission peak occurs at the resonance frequency for larger clusters such as the argon cluster. It is observed that the intensities of X-ray radiation spectra of deuterium and helium are approximately 0.01 times the intensities of X-ray radiation spectra of neon and argon. We plot the normalized X-ray emission as a function of the normalized time for different values of $\hbar \omega /T_0 = 8$
, 12 and 18 in figure 13. It is found that with increasing $\hbar \omega$
, with respect to the electron temperature, the intensity of the Bremsstrahlung X-ray radiation spectrum is reduced.
Normalized X-ray emission as a function of the normalized time for the deuterium, helium, neon and argon clusters.

Normalized X-ray emission as a function of normalized time for different values of $\hbar \omega /T_0 = 8$
, 12 and 18 for the deuterium cluster.

The variation of intensity of the Bremsstrahlung X-ray radiation spectrum as a function of $\hbar \omega /T_0$
at $\nu _0{t}^{\prime} = 0.6$
for the deuterium cluster has been plotted in figure 14. It is revealed that the intensity of the Bremsstrahlung X-ray radiation spectrum exponentially decreases at frequencies $\hbar \omega \gg T_e$
, and it increases at the resonance frequency, $\omega = \omega _{pe0}/\sqrt 3 \approx 0.57\omega _{pe0}$
. The comparison among the spectra of X-ray radiation for the deuterium, helium, neon, and argon clusters as a function of $\hbar \omega /T_0$
is presented in figure 15. It is found that the spectrum of X-ray radiation of all these clusters exponentially decreases at frequencies $\hbar \omega \gg T_e$
.
Spectrum of Bremsstrahlung X-ray radiation for $\nu _0{t}^{\prime} = 0.6$
for the deuterium cluster.

Spectrum of Bremsstrahlung X-ray radiation for the deuterium, helium, neon and argon clusters.

5. Conclusions
We analytically studied the soft X-ray emission from a femtosecond laser beam interacting with an anharmonic nanocluster. The nanocluster atoms are heated owing to collision with the Gaussian laser beam and the electrons their outer layer gain enough energy to leave the nucleus. These free electrons created in the cluster pass through the adjacent ions, and are accelerated and then emitted in the X-ray radiation regime. In an anharmonic nanoplasma, the oscillation of the nanoplasma electrons is comparable to the cluster radius, and the restoring force on electrons is nonlinear in term of the oscillation. Therefore, the electron oscillation, the heating rate and the expansion of the cluster electrons vary under the influence of the nonlinear restoring force and, consequently, the X-ray emission enhances. The heating rate of the cluster electrons and the expansion of the cluster are the maximum in the vicinity of the radial axis of the laser and reduce away from the axis of the laser. In addition, the clusters which are closer to the laser axis achieve resonance earlier, and the clusters that are farther from the radial axis of the laser experience resonance at a later time. In this case, the number of resonantly heated electrons increases over time and so X-ray emission increases. In addition, the peak observed in the X-ray spectrum occurs after some picoseconds in the deuterium, helium, neon and argon clusters.
Funding
This research received no specific grant from any funding agency, commercial or not-for-profit sectors.
Editor Dmitri Uzdensky thanks the referees for their advice in evaluating this article.
Declaration of interests
The authors report no conflict of interest.
















