1 Introduction
Granular suspensions are defined as two-phase mixtures of macroscopic particles immersed in a fluid. They are typically non-colloidal in the sense that the characteristic particle diameter is sufficiently high for Brownian effects to be negligible. Flows of granular suspensions are routinely encountered in engineering processes and natural phenomena and it is, therefore, not surprising that the literature devoted to their study spans several decades and comprises an ever-increasing number of relevant works. However, despite the considerable progress that has been achieved thus far, our understanding of the dynamics of granular suspensions remains incomplete and many pertaining questions remain open. This notable restrain can be attributed to the rich phenomenology and the substantially complex behaviours that granular suspensions exhibit. In turn, this renders their study manifestly multi-disciplinary combining aspects of fluid dynamics, rheology, plasticity theory, soil mechanics and others (Savage Reference Savage1979).
An important question in the theoretical analysis of suspensions concerns the relevance of continuum modelling. In other words, whether a collection of macroscopic particles can be described as a continuum and its constitutive relations be properly accommodated into a comprehensive continuum theory, and if yes, then what the predictive capacity of such a theory is. This question has a long history since attempts to develop continuum theories for the mixtures of interest go back more than 50 years and are still ongoing; see, for example, Passman et al. (Reference Passman, Nunziato, Bailey and Reed1986), Svendsen & Hutter (Reference Svendsen and Hutter1995), Briggs, Wang & Massoudi (Reference Briggs, Wang and Massoudi1999), Wang & Hutter (Reference Wang and Hutter1999a ,Reference Wang and Hutter b ), Papalexandris (Reference Papalexandris2004b ), Fang, Wang & Hutter (Reference Fang, Wang and Hutter2006) and references therein. However, providing a conclusive answer has proven to be an extremely challenging task. In fact, since an unequivocally accepted continuum theory for granular suspensions does not exist, to a large extent, this question remains open (Stickel & Powell Reference Stickel and Powell2005; Denn & Morris Reference Denn and Morris2014).
Ever since the onset of the development of continuum theories for granular suspensions, it has been recognized that the volume fraction of the particles constitutes a separate degree of freedom (Wallis Reference Wallis1969; Krier & Gokhale Reference Krier and Gokhale1978; Gough & Zwarts Reference Gough and Zwarts1979). However, these early modelling efforts were unsuccessful in coupling this kinematic independence with their theoretical framework and thus suffered from underdeterminacy problems (Atkin & Craine Reference Atkin and Craine1976). Employing additional assumptions as a remedy such as, for example, pressure equilibrium between the granular material and the fluid, turned out to be problematic as well since it often resulted in ill-posed systems (Stuhmiller Reference Stuhmiller1977). Goodman & Cowin (Reference Goodman and Cowin1972) were probably the first authors who assigned the volume fraction its own evolution equation, usually referred to as the compaction equation. Although this equation was postulated essentially on an ad hoc basis, since Goodman & Cowin (Reference Goodman and Cowin1972) pre-assumed the existence of a balance law that the volume fraction obeys (balance of equilibrated forces), it nonetheless provided the necessary closure to the system of balance laws. This approach was subsequently employed by Passman et al. (Reference Passman, Nunziato, Bailey and Reed1986), Wang & Hutter (Reference Wang and Hutter1999a ,Reference Wang and Hutter b ) and others.
It is interesting to note that in their later work, Cowin & Goodman (Reference Cowin and Goodman1976) tried to remove the ad hoc character of the balance of equilibrated forces by resorting to variational arguments. Still, it is Ván (Reference Ván2004) who resolved this issue by asserting that the balance of equilibrated forces can be recovered if one assumes that the volume fraction is an internal degree of freedom. A similar approach was employed by Baer & Nunziato (Reference Baer and Nunziato1986) who were able to derive an equation for the volume fraction based on purely entropic arguments. Interestingly, the study of Baer & Nunziato (Reference Baer and Nunziato1986) has certain inconsistencies related to the consequences of introducing the volume fraction as a thermodynamic variable which were identified and rectified by Bdzil et al. (Reference Bdzil, Menikoff, Son, Kapila and Stewart1999). This point of view, i.e. treating the volume fraction as an internal degree of freedom, has been also adopted by Papalexandris (Reference Papalexandris2004b ) and Powers (Reference Powers2004). Nonetheless, the status of the volume fraction as a thermodynamic variable and, by extension, the form of the compaction equation are still under debate.
An additional challenge concerns the rationalization of the constitutive relations for the dissipative properties, and in particular for the granular rheology, in a way that is consistent with the second law. Experimental measurements (Frith, Mewis & Strivens Reference Frith, Mewis and Strivens1987; Leighton & Acrivos Reference Leighton and Acrivos1987; Zarraga, Hill & Leighton Reference Zarraga, Hill and Leighton2000; Singh & Nott Reference Singh and Nott2003; Moraczewski, Tang & Shapley Reference Moraczewski, Tang and Shapley2005; Ovarlez, Bertrand & Rodts Reference Ovarlez, Bertrand and Rodts2006; Pabst, Gregorova & Berthold Reference Pabst, Gregorova and Berthold2006; Mueller, Llewellin & Mader Reference Mueller, Llewellin and Mader2009) and numerical simulations (Brady & Bossis Reference Brady and Bossis1985, Reference Brady and Bossis1988; Phung, Brady & Bossis Reference Phung, Brady and Bossis1996; Brady & Morris Reference Brady and Morris1997; Foss & Brady Reference Foss and Brady2000; Brady Reference Brady2001; Sierou & Brady Reference Sierou and Brady2002; Brady, Khair & Swaroop Reference Brady, Khair and Swaroop2006; Yurkovetsky & Morris Reference Yurkovetsky and Morris2008; Lefebvre-Lepot, Merlet & Nguyen Reference Lefebvre-Lepot, Merlet and Nguyen2015) have produced extensive data; see, also Mewis & Wagner (Reference Mewis and Wagner2009) for a succinct review. Based on these data, various theoretical analyses have been carried. These analyses assert that empirical correlations for the viscosity coefficients having the volume fraction of the particles and the shear rate as control parameters accord very well to the data, (Stickel & Powell Reference Stickel and Powell2005; Denn & Morris Reference Denn and Morris2014).
However, no study has thus far incorporated these constitutive relations into a continuum theory that is additionally thermodynamically consistent. In fact, available continuum theories typically ignore the normal viscosity of granular phase (Passman et al.
Reference Passman, Nunziato, Bailey and Reed1986; Wang & Hutter Reference Wang and Hutter1999a
; Papalexandris Reference Papalexandris2004b
; Fang et al.
Reference Fang, Wang and Hutter2006), employ them in an ad hoc fashion (Nott & Brady Reference Nott and Brady1994; Morris & Boulay Reference Morris and Boulay1999; Revil-Baudard & Chauchat Reference Revil-Baudard and Chauchat2013; Chiodi, Claudin & Andreotti Reference Chiodi, Claudin and Andreotti2014) or obtain scalings that do not match experimental data (Massoudi Reference Massoudi2011; Massoudi & Tran Reference Massoudi and Tran2016). This can be traced to the fact that the normal viscosity is associated with a shear-induced pressure that engenders a non-Newtonian behaviour. From shear-flow experiments, it is known that, for a large range of shear rates
$\dot{\unicode[STIX]{x1D6FE}}$
, the shear-induced pressure scales linearly with
$|\dot{\unicode[STIX]{x1D6FE}}|$
(Brady & Morris Reference Brady and Morris1997; Morris & Boulay Reference Morris and Boulay1999; Trulsson, Andreotti & Claudin Reference Trulsson, Andreotti and Claudin2012). This range is usually referred to as the viscous regime. As commented by Hinch (Reference Hinch2011), this observed scaling cannot be described by a simple linear relation between the viscous stress and strain-rate tensors, as typically done in existing modelling efforts. Existing thermodynamic frameworks for other types of non-Newtonian fluids, e.g. polymer melts, are also of little help to granular suspensions as the scalings are utterly different; indeed, for such fluids normal-stress differences scale quadratically with the shear rate.
An alternative point of view was proposed by MiDi (Reference Midi2004) and Da Cruz et al. (Reference Da Cruz, Emam, Prochnow, Roux and Chevoir2005) and is based on a dimensional analysis of homogeneous shear flows of dry granular materials. These collective efforts resulted in the scalar version of the popular
$\unicode[STIX]{x1D707}(I)$
-rheology that was subsequently extended to three dimensions (Jop, Forterre & Pouliquen Reference Jop, Forterre and Pouliquen2006; Forterre & Pouliquen Reference Forterre and Pouliquen2008). The
$\unicode[STIX]{x1D707}(I)$
-rheology provides a representation of the granular viscous stresses in terms of the shear rate and the normal stress (pressure). In other words, the
$\unicode[STIX]{x1D707}(I)$
-rheology is a type of friction law and thus the control parameter is no longer the volume fraction but the pressure. The satisfactory agreement between experimental data for shear flows and the predictions of the
$\unicode[STIX]{x1D707}(I)$
-rheology led to a number of subsequent generalizations, (Kamrin & Koval Reference Kamrin and Koval2012; Henann & Kamrin Reference Henann and Kamrin2013; Gray & Edwards Reference Gray and Edwards2014), and to its extension to granular suspensions (Boyer, Guazzelli & Pouliquen Reference Boyer, Guazzelli and Pouliquen2011a
). A rationalization of one of these extensions, that takes into account non-local effects into a continuum mechanical framework, was carried by Henann & Kamrin (Reference Henann and Kamrin2014).
The study of Boyer et al. (Reference Boyer, Guazzelli and Pouliquen2011a
) is of particular interest since, for the case of homogeneous shear flow, it demonstrates the equivalence between the two representations: the
$\unicode[STIX]{x1D707}(I)$
-rheology law and the ‘traditional’ one that utilize the pressure and the volume fraction as the control variable. Thus, in principle, when developing continuum theories or performing numerical simulations, one may opt for either of the two representations. However, some caution needs to be exercised prior making the choice of the representation. Indeed, Barker et al. (Reference Barker, Schaeffer, Bohorquez and Gray2015) report that the
$\unicode[STIX]{x1D707}(I)$
-rheology can exhibit an ill-posed behaviour in certain flow regimes. Moreover, when implementing the
$\unicode[STIX]{x1D707}(I)$
-rheology in an incompressible solver, as done by Lagrée, Staron & Popinet (Reference Lagrée, Staron and Popinet2011), certain artificial modifications are required so that the negativity of the pressure field does inflict the constitutive relation. On the other hand, it is well known that viscosity correlations based on the volume fraction representation have a singularity at the jamming transition point where they diverge to infinity. This singularity can cause severe numerical issues and we refer to Varsakelis, Monsorno & Papalexandris (Reference Varsakelis, Monsorno and Papalexandris2015) for a thorough discussion.
In this paper, we derive a thermomechanical, two-phase model for granular suspensions that properly accommodates the constitutive relations for the granular stresses in a thermodynamically consistent manner. Our approach is based on a non-equilibrium thermodynamic formalism for immiscible two-phase mixtures proposed in Papalexandris (Reference Papalexandris2004b ). According to this formalism, the carrier fluid and the granular material are treated as two separate thermodynamic continua but the latter is endowed with an augmented state vector so that its microstructure can be captured. Constitutive relations for the dissipative and relaxation phenomena, including granular viscous dissipation, are derived by exploiting the constraints imposed by the entropy inequality on the entropy production rate. The resulting theory is general enough to account for thermal, mechanical and kinematic non-equilibrium between the phases. It is, therefore, conforming to Lhuillier (Reference Lhuillier2001) who argues that flowing suspensions constitute systems out of equilibrium and, as such, display differences between the intensive thermodynamic variables of the fluid and particulate phases. Moreover, our resulting model, being endowed with a compaction equation for the granular volume fraction, captures both compaction and dilatational effects.
Opting for the rationalization of the constitutive expressions into a thermodynamically consistent theory offers compelling advantages over their mere inclusion into the pre-constitutive governing equations. Indeed, even though shear-flow experiments constitute the starting point for many efforts to describe the non-Newtonian behaviour of granular suspensions, the majority of them rely heavily on the specific properties of this flow. As a consequence, extending the corresponding models to other types of flows is not straightforward. By contrast, when constitutive relations are derived, and in a way that conforms with the second law, the resulting post-constitutive equations are formally valid for a broad class of flows. This is well exemplified by the thermodynamic theories for polymer melts where efforts to properly accommodate the non-Newtonian rheological characteristics provided important insights in their properties (Lebon, Jou & Casas-Vázquez Reference Lebon, Jou and Casas-Vázquez2008).
As mentioned above, in order to derive the constitutive relations that conform a priori to the observed scaling, one needs to depart from the usual linear current–force relations and consider more elaborate expressions. The present theory utilizes a subtle, nonlinear coupling between thermodynamic currents and forces and a thorough a posteriori exploitation of the resulting phenomenological coefficients. The complexity of this analysis is necessary to remove undesirable aspects such as singularities and to guarantee the vanishing of the viscous stresses at thermodynamic equilibrium. On the other hand, it is in view of this complexity that additional corollaries are obtained. For example, as a by-product of our analysis, we obtain a result against the validity of a Stokes hypothesis for the bulk viscosity. In turn, this result theoretically corroborates the numerical predictions of Brady et al. (Reference Brady, Khair and Swaroop2006).
In the development of the present thermomechanical theory we do not postulate that the particulate phase or the fluid have a constant density. Rather, we start from a fairly general setting where compressibility effects are allowed and then arrive at the incompressible and constant-density limits via multi-phase low-Mach-number asymptotics (Varsakelis & Papalexandris Reference Varsakelis and Papalexandris2011). Although it is possible to develop the same theory under the constant-density assumption, the passage from compressible to incompressible and then to constant-density flows entails a number of details and critical points that have to be underlined.
The proposed two-phase theory is quite general, however, its strengths and advantages become more evident when dealing with flows that involve concentration gradients, the onset of hydrodynamic instabilities and a strong non-equilibrium between the two phases. Typical examples of such flows include the erosion of granular beds and the subsequent formation of dunes or ripples, subaqueous granular column collapses and suspension flows in channels. Consequently, the present theory is well adapted for the modelling and simulation of natural phenomena like sediment transport in coastal and fluvial environments, avalanches and pyroclastic density currents. Furthermore, the two-phase theory is applicable to a number of industrial and technological applications that involve fluidized beds, dense particulate flows inside bead mills, transport of bulk agricultural materials and others.
The paper is organized as follows. In § 2 we present the basic principles and balance laws of thermomechanics of granular suspensions based on the mixture-theoretic approach that we have adopted. In § 3 we derive constitutive relations for granular suspensions with particular emphasis on the description of the viscous stresses acting on the granular phase. Subsequently, in § 4 we present the complete, post-constitutive form of the proposed thermomechanical model. In § 5 we present the incompressible limit of the complete model, derived via low-Mach-number asymptotics. The reduced equations for the important special case of constant-density flows are also presented. In § 6 we discuss the predictions of our model for the cases of steady shear flow and fully developed pressure-driven flow. Finally, § 7 concludes.
2 Thermomechanics of granular suspensions
We consider a two-phase mixture consisting of a granular material and a carrier fluid. The assumptions upon which our mixture-theoretic formalism is based are the following.
-
(i) Each phase is treated as a continuum thermodynamic system.
-
(ii) The two thermodynamic continua are immiscible but occupy the same space. More specifically, they fill completely the space that they occupy (saturation condition).
-
(iii) The two thermodynamic continua are open to each other and at non-equilibrium. As such, they interact with each other in the form of momentum and energy exchanges. Herein, we assume absence of chemical reactions or phase transformations.
-
(iv) The momentum and energy exchanges between the two continua are pure, i.e. their sum vanishes.
-
(v) The postulate of phase separation holds. In other words, dissipative phenomena associated with only one phase depend exclusively on the variables of this phase.
-
(vi) Both phases are macroscopically isotropic.
Throughout this article, the indices
$f$
and
$s$
are reserved to denote quantities attributed to the fluid and granular phase, respectively.
$\unicode[STIX]{x1D719}_{f}$
and
$\unicode[STIX]{x1D719}_{s}$
stand for the volume fractions of the two phases. Then, the saturation condition of assumption (ii) reads
The local form of the mass, momentum and energy balance laws for each phase are derived in the standard manner, i.e. by first writing the integral balance laws over an arbitrary control volume and then by applying successively the Reynolds transport and divergence theorems. As shown in Drew & Passman (Reference Drew and Passman1999), this procedure yields the following equations,
In the above equations
$\unicode[STIX]{x1D6FC}=f,s$
. Using standard notation,
$\unicode[STIX]{x1D70C}_{\unicode[STIX]{x1D6FC}}$
,
$\boldsymbol{u}_{\unicode[STIX]{x1D6FC}}$
,
$p_{\unicode[STIX]{x1D6FC}}$
and
$e_{\unicode[STIX]{x1D6FC}}^{t}$
, denote the density, velocity vector, thermodynamic pressure and total energy, respectively, of phase
$\unicode[STIX]{x1D6FC}$
. Further,
$\unicode[STIX]{x1D64B}_{\unicode[STIX]{x1D6FC}}$
stands for the (pressureless) stress tensor and
$\boldsymbol{q}_{\unicode[STIX]{x1D6FC}}$
for the heat-flux vector of phase
$\unicode[STIX]{x1D6FC}$
. Finally,
$\boldsymbol{f}_{\unicode[STIX]{x1D6FC}}$
and
${\mathcal{E}}_{\unicode[STIX]{x1D6FC}}$
represent the interphasial momentum and energy exchanges, respectively.
In view of assumption (iii) we set,
It is also convenient to decompose the interphasial energy exchange into a term related to the momentum exchange plus a remaining part. More specifically, we set
Next, we express the total energy of each phase as the sum of internal and kinetic energies,
$e_{\unicode[STIX]{x1D6FC}}^{t}=e_{\unicode[STIX]{x1D6FC}}+(1/2)\boldsymbol{u}_{\unicode[STIX]{x1D6FC}}^{2}$
. Then, the above balance laws for the fluid phase are written as,
whereas the balance laws for the granular phase can be written as,
In the above equations,
$\unicode[STIX]{x1D651}_{\unicode[STIX]{x1D6FC}}$
denotes the strain-rate tensor,
$\unicode[STIX]{x1D651}_{\unicode[STIX]{x1D6FC}}=(\unicode[STIX]{x1D735}\boldsymbol{u}_{\unicode[STIX]{x1D6FC}}+\unicode[STIX]{x1D735}\boldsymbol{u}_{\unicode[STIX]{x1D6FC}}^{\text{T}})/2$
. Also, the double-dot symbol,
$(\boldsymbol{ : })$
, represents the double interior product between two second-order tensors. Finally, the material time derivative with respect to the velocity of phase
$\unicode[STIX]{x1D6FC}$
is defined as,
One might argue that the energy equations in (2.4) are symmetric whereas equations (2.10) and (2.13) are not. However, this is merely an apparent asymmetry and is due to the particular decomposition of
${\mathcal{E}}$
that was introduced in (2.7). More specifically, it is straightforward to show that all decompositions of the form
${\mathcal{E}}=E+\boldsymbol{f}\boldsymbol{\cdot }(c_{1}\boldsymbol{u}_{s}+c_{2}\boldsymbol{u}_{f})$
, with
$c_{1}$
and
$c_{2}$
constants, result in the same constitutive relations. In other words, the particular choice of the constants
$c_{1}$
and
$c_{2}$
is inconsequential to the final results.
The thermodynamic state of each phase is specified by its state vector and thus its Gibbs relation. For the fluid phase, we assume that it consists of a simple, homogeneous fluid. As such, its state vector is
$(e_{f},\unicode[STIX]{x1D70C}_{f})^{\text{T}}$
and the corresponding Gibbs relations reads,
where
$s_{f}$
stands for the entropy of the fluid.
As regards the granular phase, we observe that it can perform additional reversible work due to its microstructure and this work will depend on the volume that grains occupy and on the properties of the fluid–granular conglomerate interface. For this reason, an adequate description of the state of the granular material requires additional field variables. The exact number of such variables remains an open question but a consensus in literature is being built that the standard state vector of simple fluids, here
$(e_{s},\unicode[STIX]{x1D70C}_{s})^{\text{T}}$
, should be augmented by at least two variables: the volume fraction,
$\unicode[STIX]{x1D719}_{s}$
, and its gradient,
$\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
, (Goodman & Cowin Reference Goodman and Cowin1972; Savage Reference Savage1979; Passman et al.
Reference Passman, Nunziato, Bailey and Reed1986; Wang & Hutter Reference Wang and Hutter1999a
,Reference Wang and Hutter
b
,Reference Wang and Hutter
c
; Massoudi & Mehrabadi Reference Massoudi and Mehrabadi2001; Kirchner Reference Kirchner2002; Massoudi Reference Massoudi, Antony, Hoyle and Ding2004; Ván Reference Ván2004; Papalexandris Reference Papalexandris2004b
; Fang et al.
Reference Fang, Wang and Hutter2006). Then, the usual Gibbs relation is modified to accommodate the reversible work of the additional variables as follows,
In this equation
$s_{s}$
stands for the entropy of the granular phase. The quantities
$\unicode[STIX]{x1D6FD}_{s}$
and
$\boldsymbol{h}_{s}$
are defined as the partial derivatives of
$s_{s}$
with respect to
$\unicode[STIX]{x1D719}_{s}$
and
$\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
, respectively. They can equivalently be defined with respect to the Helmholtz free energy
$\unicode[STIX]{x1D713}_{s}$
of the solid phase, so that
According to the Gibbs relation (2.16),
$\unicode[STIX]{x1D6FD}_{s}$
is the force conjugate to the variable
$\unicode[STIX]{x1D719}_{s}$
to
$\unicode[STIX]{x1D719}_{s}$
. It is often referred to as intergranular stress or configuration pressure; see, for example, Goodman & Cowin (Reference Goodman and Cowin1972), Josserand, Lagrée & Lhuillier (Reference Josserand, Lagrée and Lhuillier2004) and Josserand, Lagrée & Lhuillier (Reference Josserand, Lagrée and Lhuillier2006) for dry granular materials, as well as Passman et al. (Reference Passman, Nunziato, Bailey and Reed1986), Wang & Hutter (Reference Wang and Hutter1999a
,Reference Wang and Hutter
b
) and Cochran & Powers (Reference Cochran and Powers2008) for fluid-saturated ones. Physically, it describes the continuum manifestation of contact stresses resulting from strains due to intergranular interactions and, in particular, the resistance of grains to compaction. Herein, these contact stresses are modelled as purely elastic ones and thus the third term on the right-hand side of the Gibbs relation (2.16) accounts for the total work of these stresses; a more elaborate discussion can be found in Bdzil et al. (Reference Bdzil, Menikoff, Son, Kapila and Stewart1999). Quasi-static compaction experiments have shown that
$\unicode[STIX]{x1D6FD}_{s}\geqslant 0$
(Elban & Chiarito Reference Elban and Chiarito1986; Mesri & Vardhanabhuti Reference Mesri and Vardhanabhuti2009). In other words, the intergranular stress is of purely repulsive nature.
As regards
$\boldsymbol{h}_{s}$
, we first observe that the presumed macroscopic isotropy of the granular material implies that its free energy is an isotropic function so that
$\boldsymbol{h}_{s}$
can be written as
In this manner, the term
$\unicode[STIX]{x1D6FE}_{s}$
is the quantity conjugate to
$|\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}|^{2}$
. This quantity is related to stresses that are developed due to rearrangements of the interfacial area density. At this point, a couple of comments regarding the introduction of
$\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
as an additional variable are due. First we note that, as shown in Drew & Passman (Reference Drew and Passman1999),
$\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
is a measure of the interfacial area density and, as such, relates directly to the microstructure of the system. Also, as demonstrated by Dunn & Serrin (Reference Dunn and Serrin1985), the description of stresses related to variations of the interfacial area density within thermodynamically consistent theories requires that the free energy of the material is a function of the volume fraction gradient. As regards the physical meaning of these stresses, we note that macroscopically the interface between a granular material and the interstitial fluid is not a sharp discontinuity; instead it has a non-zero thickness, thus constituting a thin transition layer. Within this layer, the steep volume fraction gradients result in Korteweg stress, i.e. a weak interfacial tension that resembles surface tension, Varsakelis & Papalexandris (Reference Varsakelis and Papalexandris2016).
Finally, with respect to the Gibbs relation for the granular phase, we remark that this work is concerned with granular suspensions that are by definition non-colloidal, i.e. the Péclet numbers are high. For this reason, the Gibbs relation (2.16) does not contain any term related to Brownian effects.
Next, the mass-averaged density
$\unicode[STIX]{x1D70C}$
, velocity
$\boldsymbol{u}$
and entropy
$s$
of the mixture are defined as follows,
As is the case for any observable field, the mixture entropy obeys a balance law of the form
where
$\boldsymbol{J}^{s}$
represents the entropy flux and
$\unicode[STIX]{x1D70E}$
the entropy production rate. In this relation the material derivative of the entropy is taken with respect to the mass-averaged velocity, that is,
Next, we note that, according to the second thermodynamic axiom, the entropy production rate is non-negative,
Upon combination of equations (2.8) and (2.11) with the definitions of the mass-averaged quantities (2.19), (2.20) and (2.21), the following expression for the material derivative of the mixture entropy
$s$
is obtained.
3 Derivation of the constitutive relations
In this section we derive constitutive relations for the dissipative and relaxation phenomena that occur in granular suspensions by exploiting the constraints imposed by the second thermodynamic axiom (2.24).
Our starting point is the rate equation for the mixture entropy (2.25). This equation can be expanded further upon introduction of the Gibbs relations (2.15) and (2.16) and the balance laws (2.8)–(2.13). By doing so and by collecting terms, we finally arrive at the balance equation for the mixture entropy. This equation has the form of (2.22) with the entropy flux
$\boldsymbol{J}^{s}$
given by
and the entropy production rate
$\unicode[STIX]{x1D70E}$
given by
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70E} & = & \displaystyle E\left(\frac{1}{T_{s}}-\frac{1}{T_{f}}\right)+\frac{\text{d}\unicode[STIX]{x1D719}_{s}}{\text{d}t_{s}}\left(\frac{p_{s}-\unicode[STIX]{x1D6FD}_{s}}{T_{s}}-\frac{p_{f}}{T_{f}}+\unicode[STIX]{x1D735}\boldsymbol{\cdot }\left(\frac{\unicode[STIX]{x1D6FE}_{s}}{T_{s}}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right)\right)+\boldsymbol{f}\boldsymbol{\cdot }\left(\frac{\boldsymbol{u}_{f}}{T_{f}}-\frac{\boldsymbol{u}_{s}}{T_{s}}\right)\nonumber\\ \displaystyle & & \displaystyle -\,\frac{p_{f}}{T_{f}}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\boldsymbol{\cdot }(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+\unicode[STIX]{x1D719}_{f}\boldsymbol{q}_{f}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\left(\frac{1}{T_{f}}\right)+\unicode[STIX]{x1D719}_{s}\boldsymbol{q}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\left(\frac{1}{T_{s}}\right)+\frac{\unicode[STIX]{x1D719}_{f}}{T_{f}}\unicode[STIX]{x1D64B}_{f}\boldsymbol{ : }\unicode[STIX]{x1D651}_{f}\nonumber\\ \displaystyle & & \displaystyle +\,\frac{1}{T_{s}}\left(\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D64B}_{s}+\unicode[STIX]{x1D63E}_{s}\right)\boldsymbol{ : }\unicode[STIX]{x1D651}_{s}.\end{eqnarray}$$
In the last equation, the second-order tensor
$\unicode[STIX]{x1D63E}_{s}$
is defined as
where the symbol
$\otimes$
denotes the dyadic product between two vectors.
Next, we follow the proposition of Bdzil et al. (Reference Bdzil, Menikoff, Son, Kapila and Stewart1999) who advocated to treat the differences
$(T_{s}-T_{f})$
,
$(p_{s}-\unicode[STIX]{x1D6FD}_{s}-p_{f})$
, and
$(\boldsymbol{u}_{s}-\boldsymbol{u}_{f})$
as independent forces that drive the system toward equilibrium. This amounts to collecting the terms related to these differences in the expression for
$\unicode[STIX]{x1D70E}$
above. Accordingly, we perform the following two decompositions:
As will be shown below, these decompositions have important implications to the rate equation for
$\unicode[STIX]{x1D719}_{s}$
, especially in the incompressible limit; see also Varsakelis & Papalexandris (Reference Varsakelis and Papalexandris2017). To be more explicit, this decomposition was chosen so as, in the limit, the thermomechanical model be able to predict dilatancy of the granular medium; see § 5 below. By contrast, in the model proposed by Papalexandris (Reference Papalexandris2004b
) this particular grouping of terms was not introduced. Consequently, that model cannot predict dilatancy of the granular material for constant-density flows; see Varsakelis & Papalexandris (Reference Varsakelis and Papalexandris2011).
Further, we introduce
$\unicode[STIX]{x1D651}_{f}^{d}$
and
$\unicode[STIX]{x1D64B}_{f}^{d}$
as the deviatoric parts of
$\unicode[STIX]{x1D651}_{f}$
and
$\unicode[STIX]{x1D64B}_{f}$
, respectively. They are defined by the standard decompositions
with
$p_{f}^{v}$
being the bulk viscous pressure of the fluid phase. The reason for not applying this decomposition to the granular phase will become evident below in the paper. By substituting relations (3.4), (3.5) and (3.6) to (3.2), we finally arrive at
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70E} & = & \displaystyle \left(E+\frac{\text{d}\unicode[STIX]{x1D719}_{s}}{\text{d}_{s}t}p_{f}\right)\left(\frac{1}{T_{s}}-\frac{1}{T_{f}}\!\right)+\frac{\text{d}\unicode[STIX]{x1D719}_{s}}{\text{d}t_{s}}\left(\frac{p_{s}-\unicode[STIX]{x1D6FD}_{s}-p_{f}}{T_{s}}+\unicode[STIX]{x1D735}\boldsymbol{\cdot }\left(\frac{\unicode[STIX]{x1D6FE}_{s}}{T_{s}}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right)\right)\nonumber\\ \displaystyle & & \displaystyle -\,\frac{\unicode[STIX]{x1D719}_{f}}{T_{f}}p_{f}^{v}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{f}+\frac{1}{T_{f}}\left(\boldsymbol{f}-p_{f}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right)\boldsymbol{\cdot }(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+\unicode[STIX]{x1D719}_{f}\boldsymbol{q}_{f}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\left(\frac{1}{T_{f}}\right)+\unicode[STIX]{x1D719}_{s}\boldsymbol{q}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\left(\frac{1}{T_{s}}\right)\nonumber\\ \displaystyle & & \displaystyle +\,\frac{\unicode[STIX]{x1D719}_{f}}{T_{f}}\unicode[STIX]{x1D64B}_{f}^{d}\boldsymbol{ : }\unicode[STIX]{x1D651}_{f}^{d}+\frac{1}{T_{s}}\left(\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D64B}_{s}+\unicode[STIX]{x1D63E}_{s}\right)\boldsymbol{ : }\unicode[STIX]{x1D651}_{s}.\end{eqnarray}$$
Next we observe that, in view of (3.7), the entropy production rate is expressed as a sum of products with each product being associated with a particular dissipative process. In other words, the entropy production rate
$\unicode[STIX]{x1D70E}$
can be written as
In this expression, the quantities
$X_{i}$
are identified as the thermodynamic forces, while the quantities
$Y_{i}$
are identified as the thermodynamic currents. More specifically, in view of (3.7), the thermodynamic forces are
$$\begin{eqnarray}\displaystyle & & \displaystyle X_{i}\in \left\{\left(\frac{1}{T_{s}}-\frac{1}{T_{f}}\right),\frac{1}{T_{s}}\left(p_{s}-\unicode[STIX]{x1D6FD}_{s}-p_{f}+T_{s}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\left({\displaystyle \frac{\unicode[STIX]{x1D6FE}_{s}}{T_{s}}}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right)\right),\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{f},\right.\nonumber\\ \displaystyle & & \displaystyle \qquad \qquad \left.(\boldsymbol{u}_{f}-\boldsymbol{u}_{s}),\unicode[STIX]{x1D735}\left(\frac{1}{T_{f}}\right),\unicode[STIX]{x1D735}\left(\frac{1}{T_{s}}\right),\unicode[STIX]{x1D651}_{f}^{d},\unicode[STIX]{x1D651}_{s}\right\},\end{eqnarray}$$
whereas the thermodynamic currents are
$$\begin{eqnarray}\displaystyle & & \displaystyle Y_{i}\in \left\{\left(E+\frac{\text{d}\unicode[STIX]{x1D719}_{s}}{\text{d}_{s}t}p_{f}\right),\frac{\text{d}\unicode[STIX]{x1D719}_{s}}{\text{d}_{s}t},-\frac{\unicode[STIX]{x1D719}_{f}}{T_{f}}p_{f}^{v},\frac{1}{T_{f}}\left(\boldsymbol{f}-p_{f}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right),\unicode[STIX]{x1D719}_{f}\boldsymbol{q}_{f},\unicode[STIX]{x1D719}_{s}\boldsymbol{q}_{s},\frac{\unicode[STIX]{x1D719}_{f}}{T_{f}}\unicode[STIX]{x1D64B}_{f}^{d},\right.\nonumber\\ \displaystyle & & \displaystyle \qquad \qquad \left.\frac{1}{T_{s}}(\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D64B}_{s}+\unicode[STIX]{x1D63E}_{s})\right\}.\end{eqnarray}$$
It should be noted that both thermodynamic forces and currents vanish at equilibrium. Moreover, the entropy inequality (2.24) is written as
Next, we consider that the thermodynamic currents are functions of the forces. For all but the last of the currents above we assume linear relationships between currents and forces. This is equivalent to considering the Taylor expansions of these currents with respect to the forces around an equilibrium state and keeping the first-order terms of these expansions. In this manner, we arrive at
The coefficients
$L_{ij}$
are the so-called phenomenological coefficients. By virtue of the presumed macroscopic isotropy of the two phases and of the representation theorem of linear isotropic tensors, the phenomenological coefficients above are scalars. Actually, the decompositions given by (3.6) were introduced so as to make more convenient the application of the representation theorem for the viscous stresses acting on the fluid.
As regards the off-diagonal elements of the matrix of phenomenological coefficients, we remark that coefficients that couple a current and a force of difference tensorial order vanish; this is a consequence of the representation theorem of linear isotropic tensors. Further, according to the principle of phase separation, coefficients that couple currents related to only one phase (such as the heat fluxes
$\boldsymbol{q}_{f}$
and
$\boldsymbol{q}_{s}$
) with forces that depend on state variables of the other phase, vanish as well. Consequently, the only non-vanishing off-diagonal phenomenological coefficients are
$L_{12}$
and
$L_{21}$
. Also, by assuming the validity of Onsager reciprocity relations, these two coefficients are equal. Then, the only non-zero phenomenological coefficients are the following,
By virtue of the above equation and the linear relations (3.12), the entropy inequality (3.11) yields
with
The current
$Y_{8}$
has been singled out and will be treated separately because it represents the viscous stresses acting on the granular phase (divided by
$T_{s}$
). These stresses have a manifestly non-Newtonian behaviour that cannot be described by a purely linear theory. Accordingly, we provide the detailed derivation of their constitutive relations separately in the next subsection. For the time being, we remark that, by the principle of phase separation,
$Y_{8}$
can only be a function of
$X_{8}$
and possibly
$X_{6}=\unicode[STIX]{x1D735}T_{s}^{-1}$
. If we further limit ourselves to linear dependence of
$Y_{8}$
on temperature gradients then, by virtue of the representation theorem of linear isotropic tensors, the dependence of
$Y_{8}$
on
$X_{6}$
vanishes. Therefore,
$Y_{8}$
becomes a function of
$X_{8}$
only.
Furthermore, since
$X_{8}$
is independent of the other thermodynamic forces, the entropy inequality (3.14) requires that the matrix of phenomenological coefficients
$L_{ij}$
be positive definite and that the product
$X_{8}Y_{8}$
be positive. In other words, the entropy inequality (3.14) is equivalent to the following conditions that should be independently satisfied,
$$\begin{eqnarray}\displaystyle \left.\begin{array}{@{}c@{}}L_{ii}\geqslant 0,\quad i=1,\ldots 7,\\ L_{12}^{2}\leqslant L_{11}L_{22},\\ X_{8}Y_{8}\geqslant 0.\end{array}\right\} & & \displaystyle\end{eqnarray}$$
Finally, before deriving the constitutive relation for
$Y_{8}$
, it is worth pointing out that the phenomenological coefficients
$L_{ii}$
and
$L_{12}$
can be recast in terms of transport coefficients. Those involving only one phase can be written as
where
$\unicode[STIX]{x1D705}_{f}$
and
$\unicode[STIX]{x1D705}_{s}$
are the thermal conductivities of the two phases, while
$\unicode[STIX]{x1D707}_{f}$
and
$\unicode[STIX]{x1D701}_{f}$
are the first and second viscosity coefficients of the Newtonian stress tensor of the fluid phase, respectively.
The remaining phenomenological coefficients are related to interactions between the two phases and can be cast in the form of transport coefficients via the following definitions,
In the above,
$\unicode[STIX]{x1D709}$
represents the interphasial heat-transfer coefficient while
$\unicode[STIX]{x1D6FF}$
represents the coefficient of interphasial drag. Also,
$\unicode[STIX]{x1D707}_{c}$
has dimensions of viscosity and is commonly referred to as compaction viscosity. It expresses responsiveness of the granular material to compaction. Finally,
$\unicode[STIX]{x1D706}$
is a coefficient for cross effect of the variation of
$\unicode[STIX]{x1D719}_{s}$
due to thermal non-equilibrium between the two phases; in other words,
$\unicode[STIX]{x1D706}$
expresses the capacity of the granular material to compact due to thermal loadings. According to the first of inequalities (3.16), all these transport coefficients are positive except for
$\unicode[STIX]{x1D706}$
whose sign cannot be constrained on the basis of thermodynamics. Nonetheless, its amplitude is constrained by the second of inequalities (3.16) according to which,
3.1 Constitutive relations for the viscous stresses of the granular phase
As mentioned above, the current
$Y_{8}$
is a function of
$X_{8}$
only. The starting point for the derivation of a constitutive relation for
$Y_{8}$
is the general representation theorem for isotropic tensors, Truesdell & Noll (Reference Truesdell and Noll2004). According to it, the expression for
$Y_{8}$
reads,
where the coefficients
$g_{0}$
,
$g_{1}$
and
$g_{2}$
are functions of the principal invariants of the strain-rate tensor
$\unicode[STIX]{x1D651}_{s}$
and of the state variables of the granular phase.
In the derivation of the sought-after nonlinear constitutive expression for
$Y_{8}$
we further require that
$Y_{8}$
be non-singular and tend to zero as
$\unicode[STIX]{x1D651}_{s}$
vanishes, i.e. at equilibrium. It is also noted that the component
$\unicode[STIX]{x1D63E}_{s}$
of
$Y_{8}$
is a function of the state variable
$\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
, cf. definition (3.3), which implies that it describes elastic stresses. As such,
$\unicode[STIX]{x1D63E}_{s}$
does not vanish at equilibrium. In other words, the pressureless stress tensor
$\unicode[STIX]{x1D64B}_{s}$
consists of an elastic component stemming from
$\unicode[STIX]{x1D63E}_{s}$
plus a viscous component stemming from
$Y_{8}$
which should tend to zero at equilibrium.
Additionally, we observe that, according to accumulated experimental and numerical evidence, the viscous stresses acting on granular suspensions admit a ‘first-order scaling’ with respect to the shear rate
$\dot{\unicode[STIX]{x1D6FE}}$
. More specifically, in experiments of simple shear flow in the viscous regime, these stresses are found to be linear with respect to
$|\dot{\unicode[STIX]{x1D6FE}}|$
, Boyer et al. (Reference Boyer, Guazzelli and Pouliquen2011a
), Boyer, Pouliquen & Guazzelli (Reference Boyer, Pouliquen and Guazzelli2011b
) and Dbouk, Lobry & Lemaire (Reference Dbouk, Lobry and Lemaire2013). The same has also been predicted in the simulations of Brady & Morris (Reference Brady and Morris1997), Morris & Boulay (Reference Morris and Boulay1999) and Foss & Brady (Reference Foss and Brady2000) that were based on Stokesian dynamics.
Guided by this evidence, we are seeking a constitutive relation for
$Y_{8}$
that extends this scaling with respect to the shear rate to more general flows. Actually, this idea is not new and has been examined before by, among others, Fang et al. (Reference Fang, Mammoli, Brady, Ingber, Mondy and Graham2002) and Jop et al. (Reference Jop, Forterre and Pouliquen2006), who proposed a linear scaling with
$\sqrt{\unicode[STIX]{x1D651}_{s}\boldsymbol{ : }\unicode[STIX]{x1D651}_{s}}$
. We note, however, that a scaling with this quantity cannot provide by itself a tensorial representation of the stresses because this quantity is a scalar.
Herein, we propose to extend this scaling to the tensorial representation (3.20) by considering positive homogeneous functions of degree one in
$\unicode[STIX]{x1D651}_{s}$
, so that
Next, we introduce the following invariants
$l_{1}$
,
$l_{2}$
and
$l_{3}$
of
$\unicode[STIX]{x1D651}_{s}$
,
where
$\text{I}_{\boldsymbol{v}_{s}}$
,
$\text{II}_{\boldsymbol{v}_{s}}$
and
$\text{III}_{\boldsymbol{v}_{s}}$
are the principal invariants of
$\unicode[STIX]{x1D651}_{s}$
. It can be directly verified that
$l_{1}$
,
$l_{2}$
and
$l_{3}$
are homogeneous of degree one. Also, the following identity holds for
$J_{\boldsymbol{v}_{s}}$
,
Since
$J_{\boldsymbol{v}_{s}}$
is positive, there are bijective relations between the following invariant triplets,
so that the quantities
$g_{0}$
,
$g_{1}$
and
$g_{2}$
appearing in (3.20) can be considered as functions of the invariants
$l_{1}$
,
$l_{2}$
and
$l_{3}$
. Further, in view of the tensorial representation (3.20), equation (3.21) implies the following homogeneity constraints on these quantities,
Since
$g_{2}$
is homogeneous of degree
$-1$
, one has to verify that the boundedness constraint of
$Y_{8}$
holds for any finite
$\unicode[STIX]{x1D651}_{s}$
. To this end we remark that since
one can define
with
$\tilde{g}_{2}$
homogeneous of degree zero. Then, the third term on the right-hand side of (3.20) is written as
$$\begin{eqnarray}\displaystyle g_{2}\unicode[STIX]{x1D651}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D651}_{s}=\frac{\tilde{g}_{2}}{\sqrt{{\displaystyle \frac{l_{1}^{2}}{3}}+l_{2}^{2}}}\unicode[STIX]{x1D651}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D651}_{s}. & & \displaystyle\end{eqnarray}$$
According to this equation, if
$\tilde{g}_{2}$
is bounded, then the term
$g_{2}\unicode[STIX]{x1D651}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D651}_{s}$
is always bounded and vanishes as
$\unicode[STIX]{x1D651}_{s}\rightarrow 0$
.
A simple choice to satisfy the homogeneity requirements on
$g_{0}$
,
$g_{1}$
and
$\tilde{g}_{2}$
would be to take the series expansions of these quantities up to the degree of homogeneity. This would yield
with the coefficients
$c_{i}$
being functions of the state variables of the granular phase but independent of
$\unicode[STIX]{x1D651}_{s}$
. However, as it turns out, this simple choice is unsatisfactory because it leads to the appearance of the third-order term
in the product
$X_{8}Y_{8}$
. The sign of this term is undetermined and so would be the sign of the product
$X_{8}Y_{8}$
, since (3.32) is the highest-order term. This, in turn, implies that the entropy inequality would not be satisfied.
This conundrum can be circumvented by modifying the expressions (3.31), so as to remove the third-order term (3.32) from the entropy inequality. This is achieved by splitting the term (3.32) into two components and by subtracting one component from
$g_{0}$
and the other component from
$g_{1}$
, respectively. In this manner, the proposed expressions for
$g_{0}$
and
$g_{1}$
read,
$$\begin{eqnarray}\displaystyle & \displaystyle g_{0}=(c_{1}l_{1}+c_{2}l_{2}+c_{3}l_{3})-\frac{3}{2}\frac{\tilde{g}_{2}}{\sqrt{{\displaystyle \frac{l_{1}^{2}}{3}}+l_{2}^{2}}}\,l_{2}^{2}, & \displaystyle\end{eqnarray}$$
$$\begin{eqnarray}\displaystyle & \displaystyle g_{1}=c_{4}-\tilde{g}_{2}\frac{l_{3}^{3}}{\left(\displaystyle \frac{l_{1}^{2}}{3}+l_{2}^{2}\right)^{3/2}}. & \displaystyle\end{eqnarray}$$
By introducing the above expressions for
$g_{0}$
and
$g_{1}$
and the aforementioned expression
$\tilde{g}_{2}=c_{5}$
, we arrive at the following expression for the pressureless stress tensor
$\unicode[STIX]{x1D64B}_{s}$
,
$$\begin{eqnarray}\displaystyle (\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D64B}_{s}+\unicode[STIX]{x1D63E}_{s}) & = & \displaystyle \left(c_{1}l_{1}+c_{2}l_{2}+c_{3}l_{3}-c_{5}{\displaystyle \frac{3\,l_{2}^{2}}{2\sqrt{{\displaystyle \frac{l_{1}^{2}}{3}}+l_{2}^{2}}}}\right)\unicode[STIX]{x1D644}\nonumber\\ \displaystyle & & \displaystyle +\,\left(c_{4}-c_{5}{\displaystyle \frac{l_{3}^{3}}{\left({\displaystyle \frac{l_{1}^{2}}{3}}+l_{2}^{2}\right)^{3/2}}}\right)\unicode[STIX]{x1D651}_{s}~+c_{5}{\displaystyle \frac{1}{\sqrt{{\displaystyle \frac{l_{1}^{2}}{3}}+l_{2}^{2}}}}\unicode[STIX]{x1D651}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D651}_{s}.\end{eqnarray}$$
It is straightforward to verify that this representation satisfies the homogeneity requirements (3.25)–(3.27). Furthermore, it is continuous with respect to its arguments, non-singular and tends to zero at equilibrium.
Also, with the above representation, the third inequality in (3.16) stemming from the second thermodynamic axiom reads,
This implies the following constraints on the coefficients
$c_{i}$
,
Next, we observe that we can decompose the second term on the right-hand side of (3.35) into a deviatoric and an isotropic component so that this equation is written in the following form,
$$\begin{eqnarray}\displaystyle (\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D64B}_{s}+\unicode[STIX]{x1D63E}_{s}) & = & \displaystyle \left(c_{1}+{\displaystyle \frac{c_{4}}{3}}-{\displaystyle \frac{c_{5}}{3}}{\displaystyle \frac{\det \unicode[STIX]{x1D651}_{s}}{\left(\unicode[STIX]{x1D651}_{s}\mathbf{:}\unicode[STIX]{x1D651}_{s}\right)^{3/2}}}\right)(\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{s})\,\unicode[STIX]{x1D644}\nonumber\\ \displaystyle & & \displaystyle +\,\left(c_{4}-c_{5}{\displaystyle \frac{\det \unicode[STIX]{x1D651}_{s}}{\left(\unicode[STIX]{x1D651}_{s}\mathbf{:}\unicode[STIX]{x1D651}_{s}\right)^{3/2}}}\right)\unicode[STIX]{x1D651}_{s}^{d}\nonumber\\ \displaystyle & & \displaystyle +\,\left(c_{2}\sqrt{\unicode[STIX]{x1D651}_{s}^{d}\boldsymbol{ : }\unicode[STIX]{x1D651}_{s}^{d}}-{\displaystyle \frac{3}{2}}c_{5}{\displaystyle \frac{\unicode[STIX]{x1D651}_{s}^{d}\mathbf{:}\unicode[STIX]{x1D651}_{s}^{d}}{\sqrt{\unicode[STIX]{x1D651}_{s}\boldsymbol{ :}\unicode[STIX]{x1D651}_{s}}}}\right)\unicode[STIX]{x1D644}\nonumber\\ \displaystyle & & \displaystyle +\,\left(c_{5}{\displaystyle \frac{1}{\sqrt{\unicode[STIX]{x1D651}_{s}\boldsymbol{ :}\unicode[STIX]{x1D651}_{s}}}}\right)\unicode[STIX]{x1D651}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D651}_{s}.\end{eqnarray}$$
According to the above relation, two generalized Newtonian stress components can be identified by setting,
The coefficients
$\unicode[STIX]{x1D707}_{s}$
and
$\unicode[STIX]{x1D701}_{s}$
are interpreted as the first and second (bulk) viscosity of the granular phase. It is interesting to observe that the representation (3.38) reduces to that of a Newtonian fluid when
$c_{2}=c_{5}=0$
. In this limiting case, the constraints (3.37) translate to
$\unicode[STIX]{x1D707}_{s}\geqslant 0$
and
$\unicode[STIX]{x1D701}_{s}\geqslant 0$
, as expected. Nonetheless, according to (3.39), in the general case and for three-dimensional flows where
$\det \unicode[STIX]{x1D651}_{s}\neq 0$
, there are additional contributions to
$\unicode[STIX]{x1D707}_{s}$
and
$\unicode[STIX]{x1D701}_{s}$
that depend on the strain rate.
Also, the sum of the remaining terms in (3.38),
represents additional non-Newtonian viscous stresses of the granular phase. Its isotropic component is commonly referred to as the suspension pressure, see for example Morris & Boulay (Reference Morris and Boulay1999), and is responsible for the shear-induced dilatancy that is a characteristic feature of granular suspensions. Also, its deviatoric component gives rise to normal-stress differences under simple shear that are discussed in § 6.1.
We also observe that, in view of (3.39), if the bulk viscosity was assumed to be zero, then the following conditions would be true:
$c_{5}=0$
and
$(c_{1}+c_{4}/3)=0$
. These conditions must hold simultaneously because the coefficients
$c_{i}$
do not depend on the velocity gradients. But then, the fourth constraint in (3.36), implies that
$c_{2}=0$
also. In this case, the non-Newtonian viscous stresses given by (3.40) should vanish as well. However, this goes against preponderant experimental evidence that has established shear-induced dilatancy and normal-stress differences in granular suspensions. We therefore conclude that our model excludes the possibility of a Stokes-type hypothesis for the granular phase. Bulk viscosity is notoriously difficult to measure but the prediction of our model of non-zero bulk viscosity is consistent with the findings of Brady et al. (Reference Brady, Khair and Swaroop2006) who predicted non-zero
$\unicode[STIX]{x1D701}_{s}$
via Stokesian dynamics simulations.
Finally, for the sake of clarity of exposition, we introduce the following short-hand notation,
which allows to express the stress tensor
$\unicode[STIX]{x1D64B}_{s}$
in a concise manner,
It should be stressed that since the coefficients
$c_{i}$
are functions of the state variables, so are the coefficients
$\unicode[STIX]{x1D701}_{s}$
,
$\unicode[STIX]{x1D707}_{s}$
,
$\unicode[STIX]{x1D712}_{a}$
and
$\unicode[STIX]{x1D712}_{b}$
. In particular, they can depend on both
$\unicode[STIX]{x1D719}_{s}$
and
$\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
.
4 Post-constitutive equations
The balance laws for the two phases, (2.8)–(2.10) and (2.11)–(2.13), supplemented by the constitutive equations (3.12) and (3.42), the saturation condition (2.1) and by appropriate equations of state for each phase, constitute a closed system of governing equations for granular suspensions. Further, by combining these relations, and upon introduction of the expressions for the transport coefficients (3.17) and (3.18), we finally arrive to the following post-constitutive equations.
Fluid phase
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70C}_{f}\unicode[STIX]{x1D719}_{f}\frac{\text{d}\boldsymbol{u}_{f}}{\text{d}_{f}t}+\unicode[STIX]{x1D735}(p_{f}\unicode[STIX]{x1D719}_{f}) & = & \displaystyle \unicode[STIX]{x1D735}\boldsymbol{\cdot }\left(\left(\unicode[STIX]{x1D701}_{f}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{f}\right)\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D644}+2\unicode[STIX]{x1D707}_{f}\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D651}_{f}^{d}\right)\nonumber\\ \displaystyle & & \displaystyle -\,\left(\unicode[STIX]{x1D6FF}(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+p_{f}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right),\end{eqnarray}$$
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70C}_{f}\unicode[STIX]{x1D719}_{f}\frac{\text{d}e_{f}}{\text{d}_{f}t}+p_{f}\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{f} & = & \displaystyle 2\unicode[STIX]{x1D707}_{f}\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D651}_{f}^{d}\boldsymbol{ : }\unicode[STIX]{x1D651}_{f}^{d}+\unicode[STIX]{x1D701}_{f}\unicode[STIX]{x1D719}_{f}(\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{f})^{2}\nonumber\\ \displaystyle & & \displaystyle +\,\unicode[STIX]{x1D735}\boldsymbol{\cdot }(\unicode[STIX]{x1D705}_{f}\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D735}T_{f})-\unicode[STIX]{x1D709}(T_{f}-T_{s})\nonumber\\ \displaystyle & & \displaystyle +\,\left(\unicode[STIX]{x1D6FF}(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+p_{f}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right)\boldsymbol{\cdot }(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+p_{f}\frac{\text{d}\unicode[STIX]{x1D719}_{s}}{\text{d}_{s}t}\nonumber\\ \displaystyle & & \displaystyle -\,\unicode[STIX]{x1D706}\,T_{f}\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D719}_{s}\left(p_{s}-\unicode[STIX]{x1D6FD}_{s}-p_{f}+T_{s}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\left({\displaystyle \frac{\unicode[STIX]{x1D6FE}_{s}}{T_{s}}}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right)\right).\end{eqnarray}$$
Granular phase
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70C}_{s}\unicode[STIX]{x1D719}_{s}\frac{\text{d}\boldsymbol{u}_{s}}{\text{d}_{s}t}+\unicode[STIX]{x1D735}(p_{s}\unicode[STIX]{x1D719}_{s}) & = & \displaystyle \unicode[STIX]{x1D735}\boldsymbol{\cdot }\left(\left(\unicode[STIX]{x1D701}_{s}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{s}+\unicode[STIX]{x1D712}_{a}\right)\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D644}+2\unicode[STIX]{x1D707}_{s}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D651}_{s}^{d}+\unicode[STIX]{x1D712}_{b}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D651}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D651}_{s}\right)\nonumber\\ \displaystyle & & \displaystyle -\,\unicode[STIX]{x1D735}\boldsymbol{\cdot }\unicode[STIX]{x1D63E}_{s}+\left(\unicode[STIX]{x1D6FF}(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+p_{f}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right),\end{eqnarray}$$
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70C}_{s}\unicode[STIX]{x1D719}_{s}\frac{\text{d}e_{s}}{\text{d}_{s}t}+p_{s}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{s} & = & \displaystyle 2\unicode[STIX]{x1D707}_{s}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D651}_{s}^{d}\!\boldsymbol{ : }\!\unicode[STIX]{x1D651}_{s}^{d}+\unicode[STIX]{x1D701}_{s}\unicode[STIX]{x1D719}_{s}(\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{s})^{2}+\unicode[STIX]{x1D712}_{a}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{s}\nonumber\\ \displaystyle & & \displaystyle -\,\unicode[STIX]{x1D63E}_{s}\boldsymbol{ : }\unicode[STIX]{x1D651}_{s}+\unicode[STIX]{x1D712}_{b}\unicode[STIX]{x1D719}_{s}(\unicode[STIX]{x1D651}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D651}_{s})\boldsymbol{ : }\unicode[STIX]{x1D651}_{s}+\unicode[STIX]{x1D735}\boldsymbol{\cdot }(\unicode[STIX]{x1D705}_{s}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D735}T_{s})\nonumber\\ \displaystyle & & \displaystyle +\,\unicode[STIX]{x1D709}(T_{f}-T_{s})-p_{f}\frac{\text{d}\unicode[STIX]{x1D719}_{s}}{\text{d}_{s}t}\nonumber\\ \displaystyle & & \displaystyle +\,\unicode[STIX]{x1D706}\,T_{f}\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D719}_{s}\left(p_{s}-\unicode[STIX]{x1D6FD}_{s}-p_{f}+T_{s}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\left({\displaystyle \frac{\unicode[STIX]{x1D6FE}_{s}}{T_{s}}}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right)\right).\end{eqnarray}$$
Compaction equation
Equation (4.7) is the compaction equation and describes the evolution of the volume fraction of the granular phase. We remark that it is not derived by a conservation principle; instead it is follows directly from the constitutive relations (3.12) between thermodynamic currents and forces.
An interesting property of the system is that at the limit
$\unicode[STIX]{x1D719}_{s}\rightarrow 0$
, all terms in (4.4)–(4.6) for the granular phase become zero, while (4.1)–(4.3) for the fluid reduce to the compressible Navier–Stokes equations.
It is also worth commenting on the form of the term that describes the interphasial momentum exchanges. This term reads
with
$\unicode[STIX]{x1D6FF}$
being the interphasial drag coefficient, cf. (3.18). Jackson (Reference Jackson2000) proposed the decomposition of the interphasial momentum exchange into a drag and an Archimedean-type force that actually agrees with (4.8). This expression was subsequently employed by a number of modelling efforts, such as, for example, Revil-Baudard & Chauchat (Reference Revil-Baudard and Chauchat2013) and Chiodi et al. (Reference Chiodi, Claudin and Andreotti2014), that further report that this decomposition is really a postulate. Our analysis, however, asserts that this decomposition is dictated by the second law of thermodynamics. More specifically, discarding this term leads to a system of governing equations that violates the positivity of the entropy production rate
$\unicode[STIX]{x1D70E}$
. In other words, the particular form of (4.8) is not an ad hoc assumption but a necessary condition for thermodynamic consistency.
Actually, the inclusion of the term
$p_{f}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
has a long history that seems to be underestimated by some contemporary studies. This term is usually referred to as nozzling term or non-conservative product; see the discussion in Powers (Reference Powers2004) and Papalexandris (Reference Papalexandris2004a
). Further, Bdzil et al. (Reference Bdzil, Menikoff, Son, Kapila and Stewart1999) remark that changes in the volume fraction can accelerate or decelerate the flow thereby acting as a nozzle. In turn, this can engender a relative motion between the two phases. The labelling of
$p_{f}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
as a non-conservative product is also of interest. If one considers the inviscid limit of the above equations, then it is straightforward to show that, due to the presence of
$p_{f}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
, these equations cannot be cast into a conservative form. As a consequence, even weak solutions cannot be defined and the corresponding Riemann problem is ill posed (Deledicque & Papalexandris Reference Deledicque and Papalexandris2007).
At this point, some remarks about the calibration of the various parameters that appear in the post-constitutive equations are appropriate. The parameters related to the fluid phase are the shear and bulk viscosities,
$\unicode[STIX]{x1D707}_{f}$
and
$\unicode[STIX]{x1D701}_{f}$
, and the thermal conductivity
$\unicode[STIX]{x1D705}_{f}$
. They have been measured for a wide class of Newtonian fluids in a variety of thermodynamic conditions and their values are readily available. The situation with the parameters related to the granular phase is more complex. Due to the structure of this phase at the grain (mesoscopic) level, these parameters generally depend on
$\unicode[STIX]{x1D719}_{s}$
. For constant-density flows, various expressions for the viscosities
$\unicode[STIX]{x1D707}_{s}$
,
$\unicode[STIX]{x1D712}_{a}$
and
$\unicode[STIX]{x1D712}_{b}$
are available, mostly derived from shear-flow experiments; see, for example, Morris & Boulay (Reference Morris and Boulay1999), Jop et al. (Reference Jop, Forterre and Pouliquen2006) and Boyer et al. (Reference Boyer, Pouliquen and Guazzelli2011b
). On the other hand, data for the bulk viscosity
$\unicode[STIX]{x1D701}_{s}$
are available only for very dilute mixtures, Brady et al. (Reference Brady, Khair and Swaroop2006). Also, the variation of these viscosities with temperature is largely unexplored. For the thermal conductivity
$\unicode[STIX]{x1D705}_{s}$
, experimental correlations are available in the literature, cf. Carson et al. (Reference Carson, Lovatt, Tanner and Cleland2005) and Samantray, Karthikeyan & Reddy (Reference Samantray, Karthikeyan and Reddy2006). As regards
$\unicode[STIX]{x1D6FD}_{s}$
, relations based on quasi-static compaction experiments have been provided by Elban & Chiarito (Reference Elban and Chiarito1986) and Mesri & Vardhanabhuti (Reference Mesri and Vardhanabhuti2009); see also the analysis in Bdzil et al. (Reference Bdzil, Menikoff, Son, Kapila and Stewart1999). By contrast, no detailed experimental data are available for
$\unicode[STIX]{x1D6FE}_{s}$
. For this reason, people often assume a power-law dependence on
$\unicode[STIX]{x1D719}_{s}$
based mostly on physical intuition. As regards the parameters related to phase interactions, various correlations have been proposed for the interphasial drag and heat-transfer coefficients,
$\unicode[STIX]{x1D6FF}$
and
$\unicode[STIX]{x1D709}$
, that are readily available in the literature. Much less is known for the compaction viscosity
$\unicode[STIX]{x1D707}_{c}$
. It is often considered to be a constant whose magnitude is approximated via simplified transport models, Baer & Nunziato (Reference Baer and Nunziato1986). Similarly, no data are available for the off-diagonal coefficient
$\unicode[STIX]{x1D706}$
. In many situations, however, one may assume that the evolution of the volume fraction
$\unicode[STIX]{x1D719}_{s}$
depends only weakly on the thermal non-equilibrium between the two phases, especially in view of constraint (3.19). In any case, it is expected that numerical simulations based on this model, combined with available and forthcoming experimental data, will yield more accurate estimations of these parameters.
We conclude this section with a discussion on the boundary conditions that are needed to close the above system of equations. The assignment of boundary conditions for the variables related to the fluid phase,
$\boldsymbol{u}_{f}$
and
$p_{f}$
does not pose any problem and it can be performed in the same way as in single-phase flows. For example, at rigid walls, we can assume zero slip for the fluid velocity and Neumann condition for the fluid pressure. The same is true for the pressure of the granular phase
$p_{s}$
. On the other hand, the assignment of boundary condition for
$\boldsymbol{u}_{s}$
at walls requires more attention because we might have non-zero slip. Appropriate slip conditions are hard to derive and are material dependent; nonetheless, there are some works available in the literature, cf. Soltani & Yilmazer (Reference Soltani and Yilmazer1998). Similarly, the derivation of wall conditions for the volume fraction
$\unicode[STIX]{x1D719}_{s}$
is quite challenging. Quite often a Neumann condition is employed but the value of the normal derivative is determined via the compaction equation or is set to zero. However, these choices are dictated by convenience and the issue is still open; additional physical evidence is required in order to derive more accurate boundary conditions for
$\unicode[STIX]{x1D719}_{s}$
. Finally, as regards thermal boundary conditions at walls, quite often one may assume that the two phases are in thermal equilibrium since they are both in contact with the walls. Then, the prescription of thermal conditions can be performed in a similar manner as in single-phase flows.
5 The incompressible limit
The thermomechanical model given by (4.1)–(4.7) is valid for both compressible and incompressible flows. Nonetheless, in many practical applications, the velocities of the two phases are very small with respect to the speed of sound of the two phases and, consequently, compressibility effects are negligible. This is identified as the incompressible limit. In this case, one can employ the square of the smallest of the two Mach numbers as a perturbation parameter and perturb the governing equations with respect to this parameter. The result of this procedure is a system of equations, referred to as the ‘low-Mach-number approximation’, that is simpler than the original one in several important aspects.
In this section, we present the derivation of the low-Mach-number approximation for the model given by (4.1)–(4.7). The procedure is laborious but straightforward. For this reason, herein we present only the basic steps and the final result. For a more detailed description on the derivation of the low-Mach-number approximation for two-phase flow models, the reader is referred to Varsakelis & Papalexandris (Reference Varsakelis and Papalexandris2011).
Step 1. We consider a reference length
$l_{r}$
and a reference velocity
$u_{r}$
. Also, for non-dimensionalization purposes, we consider reference values of the thermodynamic variables
$\unicode[STIX]{x1D70C}_{r}$
,
$T_{r}$
,
$p_{r}$
, specific heats
${c_{p}}_{r}$
and
${c_{v}}_{r}$
and transport coefficients
$\unicode[STIX]{x1D707}_{r}$
and
$\unicode[STIX]{x1D705}_{r}$
with respect to a reference state of the phase with the smallest speed of sound. In most practical cases, this is the fluid phase. Herein we make this assumption as well.
Step 2. We introduce equations of state for each phase. For example, the fluid can be considered to obey the ideal gas law, so that
$p_{r}=({c_{p}}_{r}-{c_{v}}_{r})\,\unicode[STIX]{x1D70C}_{r}T_{r}$
.
Step 3. We introduce the reference Mach number
$M$
as the ratio between the reference velocity and the fluid speed of sound at a reference state. Under the ideal gas law,
$$\begin{eqnarray}\displaystyle M=\frac{u_{r}}{\sqrt{\displaystyle \frac{\hat{\unicode[STIX]{x1D6FE}}p_{r}}{\unicode[STIX]{x1D70C}_{r}}}},\quad \hat{\unicode[STIX]{x1D6FE}}=\frac{{c_{p}}_{r}}{{c_{v}}_{r}}. & & \displaystyle\end{eqnarray}$$
Then, the perturbation parameter
$\unicode[STIX]{x1D716}$
is defined as
Step 4. The governing equations and the equations of state are non-dimensionalized with respect to the reference quantities.
Henceforth, in order to avoid the introduction of additional symbols, every variable is understood to be non-dimensionalized (except for the reference quantities).
Step 5. All variables are expanded in perturbation series of powers of
$\unicode[STIX]{x1D716}$
. For example,
where the superscript refers to the order of a term in the expansion.
Step 6. We insert the perturbation expansions of all variables to the governing system of equations and collect terms of the same order.
The results are presented below. Henceforth, in order to avoid unnecessary complexity in the notation, all quantities are supposed to represent the zeroth-order term of the expansions and, therefore, the superscript zero is dropped. For example,
$p_{s}^{0}$
is now written as
$p_{s}$
etc. The only exception to this convention is for the first-order terms of the pressures which will still be denoted as
$p_{s}^{1}$
and
$p_{f}^{1}$
. These are typically referred to as ‘dynamic pressures’, whereas the zeroth-order terms are referred to as ‘thermodynamic pressures’.
At order
$O(\unicode[STIX]{x1D716}^{-1})$
the momentum equations of the two phases (4.2) and (4.5) yield,
Since
$p_{f}$
,
$p_{s}$
and
$\unicode[STIX]{x1D719}_{s}$
are independent variables, equations (5.4) and (5.5) reduce to
Also, in view of this equation, the compaction equation is identically satisfied at order
$O(\unicode[STIX]{x1D716}^{-1})$
. Further, at order
$O(1)$
, we arrive at the following equations.
Fluid phase
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70C}_{f}\unicode[STIX]{x1D719}_{f}\frac{\text{d}\boldsymbol{u}_{f}}{\text{d}_{f}t}+\unicode[STIX]{x1D735}(p_{f}^{1}\unicode[STIX]{x1D719}_{f}) & = & \displaystyle \frac{1}{Re}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\left(\left(\unicode[STIX]{x1D701}_{f}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{f}\right)\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D644}+2\unicode[STIX]{x1D707}_{f}\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D651}_{f}^{d}\right)\nonumber\\ \displaystyle & & \displaystyle -\,\left(\unicode[STIX]{x1D6FF}(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+p_{f}^{1}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right),\end{eqnarray}$$
Granular phase
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70C}_{s}\unicode[STIX]{x1D719}_{s}\frac{\text{d}\boldsymbol{u}_{s}}{\text{d}_{s}t}+\unicode[STIX]{x1D735}(p_{s}^{1}\unicode[STIX]{x1D719}_{s}) & = & \displaystyle \frac{1}{Re}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\left(\left(\unicode[STIX]{x1D701}_{s}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{s}+\unicode[STIX]{x1D712}_{a}\right)\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D644}+2\unicode[STIX]{x1D707}_{s}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D651}_{s}^{d}~+\unicode[STIX]{x1D712}_{b}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D651}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D651}_{s}\right)\nonumber\\ \displaystyle & & \displaystyle -\,\unicode[STIX]{x1D735}\boldsymbol{\cdot }\unicode[STIX]{x1D63E}_{s}+\left(\unicode[STIX]{x1D6FF}(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+p_{f}^{1}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right),\end{eqnarray}$$
Compaction equation
In the above equations,
$h_{f}$
and
$h_{s}$
stand for the enthalpies of the two phases. Also
$Re$
and
$Pr$
stand for the Reynolds and Prandtl number, respectively, based on the reference variables. Further, the non-dimensional number
$Re_{c}$
is the Reynolds number based on the compaction viscosity,
$\unicode[STIX]{x1D707}_{c}$
. Finally, we note that for the derivation of these results, we assumed that
$\unicode[STIX]{x1D6FD}_{s}$
and
$\unicode[STIX]{x1D6FE}_{s}$
scale with
$\unicode[STIX]{x1D70C}_{r}u_{r}^{2}$
and
$\unicode[STIX]{x1D70C}_{r}u_{r}^{2}l_{r}^{2}$
, respectively; see the relative discussion in Varsakelis & Papalexandris (Reference Varsakelis and Papalexandris2011).
The most important simplification in the incompressible limit is that the thermodynamic pressures no longer appear in the momentum equations. In this sense, the energy equation for each phase is essentially decoupled from the corresponding momentum equation. An interesting feature of the model is that it predicts thermal non-equilibrium between the two phases even at low Mach numbers, cf. (5.9) and (5.12). Moreover, when the thermodynamic pressure
$p$
remains constant, as in the case of open domains, the energy equations above reduce to the standard advection–diffusion equations for
$T_{f}$
and
$T_{s}$
with the additional relaxation term representing interphasial heat exchange.
5.1 Special case: constant-density flows
We now consider the important special case where the densities of the two phases are constant, and the two temperatures
$T_{s}$
and
$T_{f}$
are also constant and equal to each other. Then, the energy equations (5.9) and (5.12) are trivially satisfied and the remaining equations simplify to the following system,
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70C}_{f}\unicode[STIX]{x1D719}_{f}\frac{\text{d}\boldsymbol{u}_{f}}{\text{d}_{f}t}+\unicode[STIX]{x1D735}(p_{f}^{1}\unicode[STIX]{x1D719}_{f}) & = & \displaystyle \frac{1}{Re}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\left(\left(\unicode[STIX]{x1D701}_{f}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{f}\right)\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D644}+2\unicode[STIX]{x1D707}_{f}\unicode[STIX]{x1D719}_{f}\unicode[STIX]{x1D651}_{f}^{d}\right)\nonumber\\ \displaystyle & & \displaystyle -\,\left(\unicode[STIX]{x1D6FF}(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+p_{f}^{1}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right),\end{eqnarray}$$
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D70C}_{s}\unicode[STIX]{x1D719}_{s}\frac{\text{d}\boldsymbol{u}_{s}}{\text{d}_{s}t}+\unicode[STIX]{x1D735}(p_{s}^{1}\unicode[STIX]{x1D719}_{s}) & = & \displaystyle \frac{1}{Re}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\left(\left(\unicode[STIX]{x1D701}_{s}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}_{s}+\unicode[STIX]{x1D712}_{a}\right)\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D644}+2\unicode[STIX]{x1D707}_{s}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D651}_{s}^{d}~+\unicode[STIX]{x1D712}_{b}\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D651}_{s}\boldsymbol{\cdot }\unicode[STIX]{x1D651}_{s}\right)\nonumber\\ \displaystyle & & \displaystyle -\,\unicode[STIX]{x1D735}\boldsymbol{\cdot }\unicode[STIX]{x1D63E}_{s}+\left(\unicode[STIX]{x1D6FF}(\boldsymbol{u}_{f}-\boldsymbol{u}_{s})+p_{f}^{1}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}\right),\end{eqnarray}$$
The above constant-density model has the important property that it does not constrain the velocity field of either phase to be divergence free. This is a direct consequence of the compaction equation (5.18) which stipulates that the volume fraction
$\unicode[STIX]{x1D719}_{s}$
is not conserved along streamlines of the granular phase. We further note that, in a manner analogous to the Navier–Stokes equations which require that the dynamic pressure be determined only up to an additive constant, the above model requires that the two dynamic pressures
$p_{s}^{1}$
and
$p_{f}^{1}$
be determined up to the same additive constant. This is due to the structure of the compaction equation (5.18) which requires that the difference
$(p_{s}^{1}-p_{f}^{1})$
be uniquely determined.
Also, the above model has the property that at the single-phase limit,
$\unicode[STIX]{x1D719}_{s}\rightarrow 0$
, the equations for the fluid phase reduce to the Navier–Stokes equations, as they should. Finally, it is worth mentioning that algorithms for the numerical integration of systems of equations of this type have been recently proposed by Varsakelis & Papalexandris (Reference Varsakelis and Papalexandris2014) and Varsakelis et al. (Reference Varsakelis, Monsorno and Papalexandris2015).
6 Examples
In this section, and in order to gain insight into the structure and the predictive capacity of our model, we apply the constant-density equations (5.14)–(5.18) to two different flows of a granular suspension between two parallel plates. In particular, we consider the cases of (i) steady homogeneous shear flow with
$\unicode[STIX]{x1D719}_{s}=const.$
, and (ii) pressure-driven fully developed flow.
6.1 Steady shear flow
In this example we assume that the bottom plate remains at rest whereas the upper plate is moving at a constant velocity. The (non-dimensional) shear rate,
$\dot{\unicode[STIX]{x1D6FE}}$
, is then defined as the ratio between the velocity of the upper plate divided by the distance between the two plates. Assuming no-slip boundary conditions at the wall, it is easy to verify that the solution to this problem consists of linear velocity profiles given by
$\boldsymbol{e}_{x}$
being the unit vector pointing to the streamwise direction. The dynamic pressures and solid volume fraction
$\unicode[STIX]{x1D719}_{s}$
are also constant and satisfy the following relation,
By virtue of the above relation, the compaction equation (5.18) is also satisfied. Then, the strain-rate tensors are given by
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D651}_{f}=\unicode[STIX]{x1D651}_{s}=\dot{\unicode[STIX]{x1D6FE}}\left(\begin{array}{@{}ccc@{}}0 & \frac{1}{2} & 0\\ \frac{1}{2} & 0 & 0\\ 0 & 0 & 0\end{array}\right) & & \displaystyle\end{eqnarray}$$
and have the following invariants, cf. (3.22).
Further, the non-dimensional stress tensors reduce to the following expressions, cf. (3.38),
$$\begin{eqnarray}\displaystyle & \displaystyle \unicode[STIX]{x1D64B}_{f}=\frac{\dot{\unicode[STIX]{x1D6FE}}}{Re}\left(\begin{array}{@{}ccc@{}}0 & 1 & 0\\ 1 & 0 & 0\\ 0 & 0 & 0\end{array}\right), & \displaystyle\end{eqnarray}$$
$$\begin{eqnarray}\displaystyle & \displaystyle \unicode[STIX]{x1D64B}_{s}=\frac{\unicode[STIX]{x1D707}_{s}\dot{\unicode[STIX]{x1D6FE}}}{Re}\left(\begin{array}{@{}ccc@{}}0 & 1 & 0\\ 1 & 0 & 0\\ 0 & 0 & 0\end{array}\right)-\frac{\unicode[STIX]{x1D707}_{n}|\dot{\unicode[STIX]{x1D6FE}}|}{Re}\left(\begin{array}{@{}ccc@{}}1 & 0 & 0\\ 0 & 1 & 0\\ 0 & 0 & \displaystyle \frac{c_{2}-\frac{3}{2}c_{5}}{c_{2}-c_{5}}\end{array}\right)\,. & \displaystyle\end{eqnarray}$$
In the last expression, the shear viscosity of the granular phase
$\unicode[STIX]{x1D707}_{s}$
is given by (3.39). Moreover,
$\unicode[STIX]{x1D707}_{n}$
is the so-called normal viscosity, defined by Morris & Boulay (Reference Morris and Boulay1999). In the context of our proposed thermomechanical model,
$\unicode[STIX]{x1D707}_{n}$
is given by
Herein, both
$\unicode[STIX]{x1D707}_{s}$
and
$\unicode[STIX]{x1D707}_{n}$
are understood to have been non-dimensionalized by the fluid’s shear viscosity.
The stress tensor of the granular phase
$\unicode[STIX]{x1D719}_{s}\unicode[STIX]{x1D64B}_{s}$
can also be written as a function of the anisotropy coefficients, following the procedure of Morris & Boulay (Reference Morris and Boulay1999). Accordingly, the expression for
$\unicode[STIX]{x1D64B}_{s}$
reads,
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D64B}_{s}=\frac{2\,\unicode[STIX]{x1D707}_{s}}{Re}\unicode[STIX]{x1D651}_{s}^{d}-\frac{\unicode[STIX]{x1D707}_{n}|\dot{\unicode[STIX]{x1D6FE}}|}{Re}\,\hat{\unicode[STIX]{x1D64C}},\quad \text{with}~\hat{\unicode[STIX]{x1D64C}}=\left(\begin{array}{@{}ccc@{}}1 & 0 & 0\\ 0 & \unicode[STIX]{x1D706}_{2} & 0\\ 0 & 0 & \unicode[STIX]{x1D706}_{3}\end{array}\right), & & \displaystyle\end{eqnarray}$$
where
$\unicode[STIX]{x1D706}_{2}$
and
$\unicode[STIX]{x1D706}_{3}$
are the anisotropy coefficients. In our case, their values are the following.
$$\begin{eqnarray}\displaystyle \unicode[STIX]{x1D706}_{2}=1,\quad \unicode[STIX]{x1D706}_{3}=\frac{c_{2}-\displaystyle \frac{3}{2}c_{5}}{c_{2}-c_{5}}. & & \displaystyle\end{eqnarray}$$
Then, the first and second normal-stress differences become proportional to
$(\unicode[STIX]{x1D706}_{2}-1)$
and
$(\unicode[STIX]{x1D706}_{3}-\unicode[STIX]{x1D706}_{2})$
, respectively.
As regards the second normal-stress difference, which scales with
$(\unicode[STIX]{x1D706}_{3}-\unicode[STIX]{x1D706}_{2})$
, we remark that in our model
$\unicode[STIX]{x1D706}_{3}$
depends on the ratio
$c_{5}/c_{2}$
which has to be measured experimentally. Nonetheless, if we set
then
$\unicode[STIX]{x1D706}_{3}=0.5$
, which gives the same normal stresses that are predicted by the model of Brady & Morris (Reference Brady and Morris1997). There is also a general agreement that
$\unicode[STIX]{x1D706}_{3}=0.5$
and that the value of
$\unicode[STIX]{x1D706}_{2}$
is close to unity, which is the prediction of our model. For example, Brady & Carpen (Reference Brady and Carpen2002) and Fang et al. (Reference Fang, Mammoli, Brady, Ingber, Mondy and Graham2002) set explicitly
$\unicode[STIX]{x1D706}_{2}=1$
in their computations and Stickel, Phillips & Powell (Reference Stickel, Phillips and Powell2007) reached a similar conclusion with the constitutive model that they proposed. On the other hand, the experimental measurements of Zarraga et al. (Reference Zarraga, Hill and Leighton2000), Singh & Nott (Reference Singh and Nott2003) and Boyer et al. (Reference Boyer, Pouliquen and Guazzelli2011b
) are compatible with
$\unicode[STIX]{x1D706}_{2}\simeq 0.85$
and
$\unicode[STIX]{x1D706}_{3}=0.5\,$
. Also, the simulations of Morris & Boulay (Reference Morris and Boulay1999) are in good agreement with these values of the anisotropy coefficients.
As regards the first normal-stress difference, since it scales with
$(\unicode[STIX]{x1D706}_{2}-1)$
, our model predicts that it equals to zero. Actually, it can be shown that the representation theorem (3.20), upon which our model is based, implies a priori that is zero. We note that this has been explicitly assumed in a number of previous studies. In any case, there is a consensus that the first normal-stress difference is much smaller than the second one. However, while definite conclusions cannot be drawn yet, there is experimental evidence that the first normal-stress difference admits a small albeit non-zero value; see, for example, Zarraga et al. (Reference Zarraga, Hill and Leighton2000), Singh & Nott (Reference Singh and Nott2003) and Boyer et al. (Reference Boyer, Pouliquen and Guazzelli2011b
).
In our view, the most likely cause of it is the slow relaxation of the internal ordering of the granular phase. In fact, as is known from experimental observations and discrete-element simulations, flowing granular suspensions present a partially ordered structure because the macroscopic motion of the particles cannot be completely decoupled from their microscale configuration; a review on this issue has been provided by Morris (Reference Morris2009). In the derivation of our model, the assumption that
$\unicode[STIX]{x1D64B}_{s}$
is an algebraic function of
$\unicode[STIX]{x1D651}_{s}$
is equivalent to assuming that the dynamics controlling the microscale configuration is very fast with respect to the characteristic time scales of the flow. In other words, this assumption implies that any additional internal degree of freedom at the grain level relaxes very fast with respect to the flow time scales so that effectively the stresses are determined by
$\unicode[STIX]{x1D719}_{s}$
,
$\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{s}$
and the deformation tensor
$\unicode[STIX]{x1D651}_{s}$
.
This assumption, however, can be removed by the introduction of an additional tensorial order parameter that relates to the microstructure of the granular phase; say
$\boldsymbol{A}_{s}$
. Possible candidates of such an order parameter include fabric tensors, Phan-Thien (Reference Phan-Thien1995), Hinrichsen & Wolf (Reference Hinrichsen and Wolf2004) and Goddard (Reference Goddard2006), a microstructure tensor based on the mean-free path length (Stickel, Phillips & Powell Reference Stickel, Phillips and Powell2006) and others. This approach allows for the description of time-dependent stresses related to relaxation phenomena. We remark that within the framework of non-equilibrium thermodynamics, the introduction of an order parameter
$\boldsymbol{A}_{s}$
provides an extra term to the Gibbs equation,
$-\boldsymbol{B}_{s}\boldsymbol{ : }\text{d}\boldsymbol{A}_{s}$
, with
$\boldsymbol{B}_{s}$
being the partial derivative of the Helmholtz free energy of the granular phase with respect to
$\boldsymbol{A}_{s}$
. Consequently, by exploiting the entropy inequality, one can derive a rate equation for
$\boldsymbol{A}_{s}$
and a constitutive equation for
$\unicode[STIX]{x1D64B}_{s}$
that depend both on
$\unicode[STIX]{x1D651}_{s}$
and on
$\boldsymbol{B}_{s}$
. This procedure has already been used by Lhuillier (Reference Lhuillier2001) and Bedeaux & Rubi (Reference Bedeaux and Rubi2002) for the case of colloidal suspensions.
In the present work, we have chosen to refrain from the introduction of a tensorial order parameter related to the granular microstructure for the following two reasons. First, currently there exists no univocal definition of such a tensorial order parameter and, to the best of our knowledge, there is not sufficient experimental guidance about how the free energy of the granular phase should depend on it. Second, from a trade-off point of view, the first normal-stress difference has been measured to be quite small, yet the introduction of a tensorial order parameter would increase considerably the complexity of the governing equations.
6.2 Pressure-driven channel flow
This test case is a convenient benchmark for suspension models because it is relatively simple to describe, yet the presence of a varying velocity gradient allows the observation of particle migration due to non-Newtonian stresses. Over the years, it has been the subject of numerous experimental studies, ranging from early works such as Karnis, Goldsmith & Mason (Reference Karnis, Goldsmith and Mason1966) to the well-known studies of Koh, Hookham & Leal (Reference Koh, Hookham and Leal1994), Hampton et al. (Reference Hampton, Mammoli, Graham, Tetlow and Altobelli1997) and Lyon & Leal (Reference Lyon and Leal1998). More recent experimental results have been obtained by the group of Gilchrist, cf. Gao, Xu & Gilchrist (Reference Gao, Xu and Gilchrist2009) and Gao et al. (Reference Gao, Kulkarni, Morris and Gilchrist2010). Experimental measurements of the group of Gilchrist and numerical results obtained via a discrete-element method have recently been reported in Yeo & Maxey (Reference Yeo and Maxey2011). Herein we compare the predictions of our model against those results.
In the experiment that we chose for our comparisons, a suspension of rigid silica microspheres in a glycerine–water solution is pumped through a rectangular channel whose width equals
$40~\unicode[STIX]{x03BC}\text{m}$
. The particle diameter is
$1.0~\unicode[STIX]{x03BC}\text{m}$
and the initial average concentration is set at
$\langle \unicode[STIX]{x1D719}_{s}\rangle =0.411$
. Due to the small channel size and the high particle concentration, the effect of gravity is negligible and, therefore, the flow is symmetric around the centreline. The experimental data are taken when the flow has reached steady state and is fully developed. For this reason, we look explicitly for a one-dimensional and time-independent numerical solution of equations (5.14)–(5.18). In particular, we compute steady-state solutions of these equations via an iterative, under-relaxation numerical method.
In our computations, the reference values that we use for non-dimensionalisation purposes are defined as follows. The reference length is equal to the channel’s half-width,
$l_{r}=20~\unicode[STIX]{x03BC}\text{m}$
. The reference velocity is the one at the centreline,
$u_{r}=2\times 10^{-4}~\text{m}~\text{s}^{-1}$
. The reference density and viscosity are the ones of the liquid,
$\unicode[STIX]{x1D70C}_{r}=1200~\text{kg}~\text{m}^{-3}$
and
$\unicode[STIX]{x1D707}_{r}=0.04~\text{Pa}~\text{s}$
. Finally, the reference pressure is
$l_{r}u_{r}^{2}$
.
As regards the material parameters, the drag coefficient
$\unicode[STIX]{x1D6FF}$
is approximated by the correlation proposed in Benyahia, Syamlal & O’Brien (Reference Benyahia, Syamlal and O’Brien2005). In this particular case, the drag coefficient is so high that the fluid and solid phasial velocities practically coincide. For the viscous stresses, we remark that in this particular case the bulk stresses are zero because the flow is divergence free and the shear viscosity coefficient does not depend on
$\unicode[STIX]{x1D651}_{s}$
because
$\det \unicode[STIX]{x1D651}_{s}=0$
, cf. (3.39). This allows us to use the following expressions proposed in Morris & Boulay (Reference Morris and Boulay1999),
In the above relations
$\unicode[STIX]{x1D719}_{m}$
represents the granular volume fraction at the jamming transition,
$\unicode[STIX]{x1D719}_{m}=0.6$
. The values of
$\unicode[STIX]{x1D707}_{s}$
and
$\unicode[STIX]{x1D707}_{n}$
, calculated at the average value
$\langle \unicode[STIX]{x1D719}_{s}\rangle =0.4$
, are
$14.4$
and
$8.6$
, respectively. In other words, these viscosities are an order of magnitude larger than the viscosity of the liquid. The remaining coefficients
$\unicode[STIX]{x1D712}_{a}$
and
$\unicode[STIX]{x1D712}_{b}$
are evaluated by combining the above expression for
$\unicode[STIX]{x1D707}_{n}$
with (6.10) and (3.41).
For
$\unicode[STIX]{x1D6FD}_{s}$
we consider the following relation, which is a simplified version of the expression proposed in Powers (Reference Powers2004),
where
$\unicode[STIX]{x1D6FD}_{0}$
is a constant. Finally, as regards
$\unicode[STIX]{x1D6FE}_{s}$
, we note that reliable experimental data are currently unavailable. For this reason, in our study we tested various power laws of
$\unicode[STIX]{x1D719}_{s}$
. Our tests showed that high exponents gave better agreement with experiments. In particular, the following expression
with
$\unicode[STIX]{x1D6FE}_{0}$
being a constant, turned out to work well in practice. The non-dimensional values of
$\unicode[STIX]{x1D6FD}_{0}$
and
$\unicode[STIX]{x1D6FE}_{0}$
, are set as follows,
(The dimensional values of the above parameters are
$5\times 10^{-2}~\text{Pa}$
and
$1\times 10^{-9}~\text{N}$
, respectively. This implies, for example, that
$\unicode[STIX]{x1D6FD}_{0}$
is approximately 35 times smaller than the pressure gradient along the channel multiplied by the channel half-width.) Finally, the Reynolds number of the problem is equal to
$Re=1.2\times 10^{-4}$
.
Pressure-driven flow: profiles of the granular volume fraction
$\unicode[STIX]{x1D719}_{s}$
and velocity
$u_{s}$
. The predictions of our model are plotted against the experimental results and the discrete-element simulations reported in Yeo & Maxey (Reference Yeo and Maxey2011) (denoted by Y&M in the figure legends). Average volume fraction,
$\langle \unicode[STIX]{x1D719}_{s}\rangle =0.4$
.
Next, we proceed to the discussion of our results. Figure 1(a) shows numerical predictions and experimental data for the volume fraction
$\unicode[STIX]{x1D719}_{s}$
. The observed particle migration towards the centre of the channel can be explained as follows. In the initial stages of the flow, the granular volume fraction is uniform. Then, the high velocity gradients in the wall regions translate into higher shear-induced normal stresses in these regions. In turn, these stresses drive the particles towards the centreline, resulting in the particle migration that is observed in the fully developed flow. As regards our model, this migration is predicted by virtue of the coupling between the momentum balance (5.17) and the compaction equation (5.18).
We can infer from figure 1(a) that the predictions of our model compare quite well with the experimental data. Nonetheless, there is a discrepancy inside a thin layer (2 to 3 grain diameters) next to the channel walls. This discrepancy may be attributed to the fact that continuum theories such as ours cannot capture flow structures that are present only at the grain scale.
Figure 1(b) shows the numerical predictions for the velocity profile. We can observe the blunting of this profile near the centreline with respect to the parabolic solution. This is due to the dependence of the viscosity coefficients on the volume fraction
$\unicode[STIX]{x1D719}_{s}$
. In particular, as
$\unicode[STIX]{x1D719}_{s}$
increases, so does the viscosity coefficient
$\unicode[STIX]{x1D707}_{s}$
, cf. equation (6.11). For the high value of the average volume fraction
$\langle \unicode[STIX]{x1D719}_{s}\rangle$
of this example, a central plug zone is predicted which exhibits practically constant velocity. As can be directly inferred from figure 1(b), the profile predicted by our model agrees quite well with the one predicted by the computations of Yeo & Maxey (Reference Yeo and Maxey2011).
7 Conclusions
In this article we have presented a mixture-theoretic formalism for granular suspensions, i.e. for mixtures of a granular material and a carrier fluid at high Péclet numbers. According to this formalism, the two phases are treated as coexisting but open thermodynamic continua that interact with each other. As such, each phase is endowed with its own set of thermodynamic variables and conservation laws. Subsequently, this formalism was applied for the derivation of a thermomechanical model for the mixtures of interest. Constitutive equations for the dissipative and relaxation phenomena occurring in both phases are derived by exploiting the constraints imposed by the entropy inequality when applied to the entire mixture.
The proposed model is valid for both compressible and incompressible flows. In this paper we have also derived the incompressible limit of the model via low-Mach-number asymptotic expansion. The resulting system of equations is substantially simpler than the full model and, therefore, more convenient for flows where compressibility effects are negligible. For the important special case of constant-density flows, the reduced equations have also been presented and discussed.
In our derivation, particular emphasis has been placed on three objectives. First, the model should be able to handle thermal non-equilibrium even at low Mach numbers. To this end, each phase has been endowed with its own temperature field. Second, the model should provide an evolution equation for the solid volume fraction. Moreover, this evolution equation should yield divergent velocity fields even for constant-density flows so that the dilatancy of the granular phase can be predicted. To this end, we have introduced the solid volume fraction as an additional thermodynamic variable. Then, both the first and second objectives have been achieved by writing the entropy production rate in a convenient form of sum of products. The third objective is to capture as accurately as possible the non-Newtonian behaviour of the viscous stresses acting on the granular phase. To this end, we have employed the general representation theorem of isotropic tensors and imposed the following requirements: (i) the representation should yield the same scaling with respect to the shear rate as the one observed in experiments, (ii) it should remain bounded at equilibrium and (iii) it should satisfy the entropy inequality. This provided a well-defined, shear-rate-dependent constitutive relation for the granular viscous stress tensor.
When applied to the problem of steady shear flow, the proposed model predicts a zero value for the first normal-stress difference and a negative value for the second one. These predictions match previous numerical studies and are in good agreement with experimental observations. However, available experimental data show a small non-zero value for the first normal-stress difference. A likely explanation for this discrepancy is the presence of relaxation phenomena at the grain level that are unaccounted for in our model. Even though the macroscopic effects of these phenomena are expected to be small, they can in principle be captured via the introduction of an additional order parameter of tensorial character that is related to the microstructure of the granular phase. Finally, we have applied the model to steady pressure-driven channel flow, in order to assess the accuracy of its predictions in a more complex scenario, namely, where the viscous stresses generate particle migration. Our numerical results were found to be in good agreement with earlier experimental data and discrete-element computations.
Acknowledgements
Financial support for the first author has been provided by the European Commission via SEDITRANS (REA grant agreement no. 607394), an ITN project of the Marie Curie Actions of the 7th Framework Programme. The second author acknowledges the financial support of the National Research Fund of Belgium (FNRS) under the GRANMIX grant.