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Wall-temperature effects in a turbulent hypersonic boundary layer in chemical non-equilibrium

Published online by Cambridge University Press:  07 September 2026

Marco Fratini*
Affiliation:
Department of Mechanical and Aerospace Engineering, Sapienza University of Rome, via Eudossiana 18, 00184 Rome, Italy
Matteo Bernardini
Affiliation:
Department of Mechanical and Aerospace Engineering, Sapienza University of Rome, via Eudossiana 18, 00184 Rome, Italy
*
Corresponding author: Marco Fratini, marco.fratini@uniroma1.it

Abstract

Content of image described in text.

Hypersonic vehicles operate in extreme environments where intense aerodynamic heating, wall heat transfer and thermochemical non-equilibrium are tightly coupled. In this regime, wall temperature plays a pivotal role in mediating the interaction between turbulence, thermal transport and chemical activity, progressively undermining similarity properties derived for adiabatic or low-enthalpy flows. In this work, direct numerical simulations of a spatially evolving, zero-pressure-gradient hypersonic turbulent boundary layer under chemical non-equilibrium are performed to assess wall-temperature effects. The configuration corresponds to a Mach 10 flow characterised by a stagnation enthalpy sufficiently high to activate thermochemical processes. Three isothermal, non-catalytic wall conditions are considered, with wall temperatures in the range $T_w = 1400-2000\:\text{K}$. Wall cooling promotes an earlier transition and a monotonic increase in wall heat flux. Mean-velocity profiles collapse satisfactorily under modern compressibility transformations, confirming their applicability to high-enthalpy boundary layers. The thermal field exhibits two distinct modifications with stronger wall cooling: a progressive reduction of the mean temperature profile and an outward shift of the wall-normal position of the temperature peak. These modifications strongly affect both turbulence statistics and chemical activity. By lowering the mean temperature profile, wall cooling suppresses endothermic chemical reactions and reduces the associated energy drain, allowing larger temperature fluctuations to develop. As a result, the concentration of dissociation products decreases by up to a factor of two between the hottest and coldest wall conditions, highlighting the key role of the wall temperature in shaping the thermal field and, in turn, in regulating the chemical activity within the boundary layer.

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JFM Papers
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution and reproduction, provided the original article is properly cited.
Copyright
© The Author(s), 2026. Published by Cambridge University Press
Figure 0

Table 1. Summary of parameters for the DNSs. Grid spacings are reported in wall-units and are evaluated at the stations reported in table 2, with Δyw+$\Delta y^+_w$ and Δyδ+$\Delta y^+_\delta$ referring to y$y$-spacing at the wall and boundary-layer edge, respectively.Table 1 long description.

Figure 1

Table 2. Spanwise and time-averaged boundary-layer properties at the selected stations. Here, Reδ∗=ρeueδ∗/μe$\textit{Re}_{\delta ^*}=\rho _e u_e \delta ^* /\mu _e$, Reθ=ρeueθ/μe$\textit{Re}_\theta =\rho _e u_e \theta /\mu _e$, Reδ2=ρeueθ/μw$\textit{Re}_{\delta _2}=\rho _e u_e \theta /\mu _w$, Reτ∗=ρeτwδ/μe$\textit{Re}_{\tau }^*=\sqrt {\rho _e \tau _w} \delta /\mu _e$, Mτ=uτ/aw$M_\tau =u_\tau /a_w$ where aw$a_w$ is the speed of sound at the wall, Cf=τw/(0.5ρeue2)$C_{\!f} = \tau _w/(0.5 \rho _e u_e^2)$ and Bq=qw/(ρwuτhw)$B_q=q_w/(\rho _w u_\tau h_w)$, with τw=(μ∂u/∂y)|w$\tau _w=(\mu \partial u /\partial y)|_w$ and qw=(−λ∂T/∂y)|w$q_w=(-\lambda \partial T /\partial y)|_w$.Table 2 long description.

Figure 2

Table 3. Parameters used for the boundary-layer tripping.Table 3 long description.

Figure 3

Figure 1. Instantaneous velocity field in the x$x$–z$z$ slice at y∗≈40$y^* \approx 40$ for the T20 case.

Figure 4

Figure 2. Instantaneous contours of velocity and temperature fluctuations in a wall-parallel plane at y∗≈40$y^* \approx 40$. (a,c,e) velocity fluctuations scaled as ρ¯/τwu″$\sqrt {\bar {\rho } / \tau _w} u''$. (b,d,f) temperature fluctuations scaled as ρ¯R~T″/τw$\bar {\rho } \tilde {R} T'' / \tau _w$. From top to bottom, T14, T17 and T20 cases.

Figure 5

Figure 3. (a) Spanwise and (b) temporal spectra of the streamwise velocity fluctuations at Reτ=1500$\textit{Re}_\tau =1500$ for different wall-normal locations. The results refer to the T20 case. The spectra are normalised by the corresponding variance, so that their integral is equal to unity. The vertical lines in panels (a) and (b) denote the spanwise and temporal scales associated with the tripping forcing, respectively.

Figure 6

Figure 4. Streamwise evolution of (a) skin friction coefficient Cf$C_{\!f}$ and (b) wall heat-flux coefficient Cq$C_q$ as a function of Reδ∗$\textit{Re}_{\delta ^*}$.

Figure 7

Figure 5. Mean-velocity profiles scaled using the (a) Van Driest (1951), (b) Volpiani et al. (2020), (c) Griffin et al. (2021), (d) Hasan et al. (2023) compressibility transformations, plotted as a function of the transformed wall-normal coordinate Y+$Y^+$. In the grey dashed line, the incompressible law of the wall is shown: viscous sublayer U+=Y+$U^+=Y^+$, log layer U+=1/0.41ln⁡Y++5.2$U^+=1/0.41 \ln {Y^+} + 5.2$.

Figure 8

Figure 6. Wall-normal profiles of the mean local Mach number M¯=|u|/a¯$\bar {M}=\overline {|\boldsymbol{u}|/a}$, where a$a$ is the local speed of sound, as a function of the wall-normal coordinate y∗$y^*$. The dashed grey line represents the sonic condition, M=1$M=1$.

Figure 9

Figure 7. Wall-normal profiles of the non-dimensional mean temperature T~/Te$\tilde {T}/T_e$ (a) and (T~−Tw)/Tw$(\tilde {T}-T_w)/T_w$ (b) as a function of the wall-normal coordinate y∗$y^*$. In panel (b), the position of the temperature peak is marked with a symbol.

Figure 10

Table 4. Summary of parameters of the selected DNS studies.Table 4 long description.

Figure 11

Figure 8. Wall-normal position of the temperature peak, expressed in semi-local scaled y$y$-coordinate, as a function of the diabatic parameter Θ$\varTheta$ for the DNS database reported in table 4.

Figure 12

Figure 9. Figure 9 long description.Wall-normal profiles of the Reynolds-stress components (a–d), the turbulent Mach number Mt$M_t$ (e) and turbulent kinetic energy budget terms (f), plotted as a function of the wall-normal coordinate in semi-local units y∗$y^*$.

Figure 13

Figure 10. Wall-normal profiles of r.m.s. of temperature (a), density (b) and pressure (c) fluctuations, plotted as a function of the wall-normal coordinate in semi-local units y∗$y^*$.

Figure 14

Figure 11. Pressure and dilatation structures for the T20 case. (a) Pressure fluctuations p′+=p′/τw$p'^+=p'/\tau _w$ in a wall-parallel plane at y∗≈5$y^*\approx 5$. (b) Dilatation fluctuations θ′+=θ′μw/τw$\theta '^+=\theta '\mu _w/\tau _w$ in the same plane, with θ=∂ui/∂xi$\theta =\partial u_i/\partial x_i$. (c) Premultiplied streamwise pressure spectrum, with λx+=(2π/kx)/δv$\lambda _x^+=(2\pi /k_x)/\delta _v$ and Ep′p′+=Ep′p′/τw2$E^+_{p'p'}=E_{p'p'}/\tau _w^2$. (d) Space–time diagram of p′+$p'^+$ in a z$z$–t$t$ plane at y∗≈5$y^*\approx 5$, with z∗=z/δv∗$z^*=z/\delta _v^*$ and t∗=t/(δv∗/uτ∗)$t^*=t/(\delta _v^*/u_\tau ^*)$.

Figure 15

Figure 12. (a) Wall-normal profiles of turbulent (solid lines) and conductive (dashed lines) heat-transfer contributions plotted as a function of the wall-normal coordinate in semi-local units y∗$y^*$. The turbulent enthalpy flux is scaled with ρ¯uτ∗3$\bar {\rho } {u_\tau ^*}^3$, while the conductive term is scaled with uτ∗2/δv∗${u_\tau ^*}^2 / \delta _v^*$. (b) Relative difference δy∗=(y∂h~/∂y=0∗−yρ¯h″v″~=0∗)/y∂h~/∂y=0∗$\delta y^*=(y^*_{\partial \tilde {h} / \partial y=0}-y^*_{\bar {\rho } \widetilde {h''v''}=0})/y^*_{\partial \tilde {h} / \partial y=0}$ between the wall-normal locations of the zero crossing of the mean enthalpy gradient and the turbulent enthalpy flux for the DNS database reported in table 4, plotted as a function of the friction Mach number Mτ$M_\tau$. The symbols’ definitions are the same as those used in figure 8.

Figure 16

Figure 13. Assessment of the mean velocity–enthalpy relation. (a) Mean enthalpy profiles as a function of the mean streamwise velocity. Solid lines denote the DNS data, while symbols denote the prediction given by (3.5) and (3.7). (b) Percentage error between the DNS data and the Reynolds analogy prediction, defined as ε=(h~DNS−h~DM)/h~DNS×100$\varepsilon = (\tilde {h}_{\textit{DNS}}-\tilde {h}_{\textit{DM}})/\tilde {h}_{\textit{DNS}} \times 100$, where h~DM$\tilde {h}_{\textit{DM}}$ denotes the enthalpy obtained from (3.5).

Figure 17

Table 5. Boundary-layer-averaged values of sPr$sPr$, evaluated at the stations listed in table 2.Table 5 long description.

Figure 18

Figure 14. Assessment of the SRA: (a) wall-normal profiles of the turbulent Prandtl number; (b) ratio between left-hand side and right-hand side of the GHSRA (3.10); (c) wall-normal profiles of the velocity–temperature correlation coefficient.

Figure 19

Figure 15. Wall-normal profiles of Favre-averaged mass fractions of (a) N2$\textrm {N}_2$, (b) O2$\textrm {O}_2$, (c) NO, (d) O and (e) N, plotted as a function of the wall-normal coordinate in semi-local units y∗$y^*$.

Figure 20

Figure 16. Wall-normal profiles of the mean heat-release rate plotted as a function of the wall-normal coordinate in semi-local units y∗$y^*$.

Figure 21

Table 6. Turbulent Damköhler numbers.Table 6 long description.

Figure 22

Figure 17. Wall-normal profiles of Favre-averaged r.m.s. of mass fractions of (a) N2$\textrm {N}_2$, (b) O2$\textrm {O}_2$, (c) NO, (d) O and (e) N, plotted as a function of the wall-normal coordinate in semi-local units y∗$y^*$.

Figure 23

Figure 18. Wall-normal profiles of the Reynolds-averaged chemical production rates (solid lines) and the corresponding mean-field approximations (dashed lines) of (a) N2$\textrm {N}_2$, (b) O2$\textrm {O}_2$, (c) NO, (d) O and (e) N, plotted as a function of the wall-normal coordinate in semi-local units y∗$y^*$. Production rates are scaled with the semi-local quantity μ¯/(ρ¯τw)$\bar {\mu } / (\bar {\rho } \tau _w)$.

Figure 24

Figure 19. Wall-normal profiles of the correlation coefficient between fluctuations of mass fraction and streamwise velocity (solid lines) and between fluctuations of mass fraction and wall-normal velocity (dashed lines) for (a) N2$\textrm {N}_2$, (b) O2$\textrm {O}_2$, (c) NO, (d) O and (e) N, plotted as a function of the outer-scaled wall-normal coordinate y/δ99$y/\delta _{99}$.

Figure 25

Figure 20. Diagnostics of shocklet-like compressive events. (a) Probability density function (p.d.f.) of the normalised dilatation fluctuation, θ′/θrms′(y)$\theta '/\theta '_{{rms}}(y)$. (b) The p.d.f. of the negative-dilatation fluctuation, −θ′/θrms′(y)$-\theta '/\theta '_{{rms}}(y)$, in log–log scale. (c) Joint p.d.f. of the heat-release rate and normalised dilatation fluctuation for the T14 case.

Figure 26

Table 7. Grid parameters for the baseline (T20) and coarse (T20-C) simulations. Grid spacings are evaluated at the analysis station (Reτ=1500$\textit{Re}_\tau =1500$) and are reported in wall units, with Δyw+$\Delta y^+_w$ and Δyδ+$\Delta y^+_\delta$ referring to y$y$-spacing at the wall and boundary-layer edge, respectively.Table 7 long description.

Figure 27

Figure 21. Figure 21 long description.Grid-convergence assessment for the T20 case. (a) Hasan-transformed mean-velocity profile, (b) Favre-averaged temperature, (c) Reynolds-stress components and (d) r.m.s. of temperature fluctuations.