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Mineral chemistry and thermobarometry of the staurolite-chloritoid schists from Poshtuk, NW Iran

Published online by Cambridge University Press:  17 May 2012

ADEL SAKI*
Affiliation:
Department of Geology, Shahid Chamran University of Ahvaz, Iran
MOHSSEN MOAZZEN
Affiliation:
Department of Geology, University of Tabriz, 51664, Tabriz, Iran
ROLAND OBERHÄNSLI
Affiliation:
Institute of Earth & Environmental Sciences, Potsdam University, Karl-Liebknecht-Strasse 24, 14476 Potsdam, Germany
*
†Author for correspondence: adel_saki@scu.ac.ir
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Abstract

The Poshtuk metapelitic rocks in northwestern Iran underwent two main phases of regional and contact metamorphism. Microstructures, textural features and field relations indicate that these rocks underwent a polymetamorphic history. The dominant metamorphic assemblage of the metapelites is garnet, staurolite, chloritoid, chlorite, muscovite and quartz, which grew mainly syntectonically during the later contact metamorphic event. Peak metamorphic conditions of this event took place at 580 °C and ~3–4 kbar, indicating that this event occurred under high-temperature and low-pressure conditions (HT/LP metamorphism), which reflects the high heat flow in this part of the crust. This event is mainly controlled by advective heat input through magmatic intrusions into all levels of the crust. These extensive Eocene metamorphic and magmatic activities can be associated with the early Alpine Orogeny, which resulted in this area from the convergence between the Arabian and Eurasian plates, and the Cenozoic closure of the Tethys oceanic tract(s).

Information

Type
Original Articles
Copyright
Copyright © Cambridge University Press 2012
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Figure 1. (a) Simplified structural subdivision map of Iran and the locality of the study area (modified from Stocklin & Setudenia, 1972). (b) Geological map of the Mahneshan Complex and Poshtuk sub-area and sample locations.

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Table 1. Representative major (wt%) compositions of metapelitic rocks from the Poshtuk area (bulk rock analyses)

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Figure 2. (a) Garnet porphyroblasts (Grt) with 5 to 15 mm diameter are formed in chloritoid schists; hand specimen. (b) D1 and D2 deformational phases picked up by S1 and S2 schistosities. (c) A schistosity (S1) is defined by a preferred orientation of muscovite; chloritoid and chlorite is affected by a crenulation schistosity. (d) Chlorite and chloritoid are formed in equilibrium. (e) Staurolite and muscovite nucleated at the margin of garnet. (f) Syntectonic helcitic garnet porphyroblasts (Grt1) formed during M2 metamorphism; garnet (Grt2) is formed during contact metamorphic phase.

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Table 2. Representative trace (ppm) element compositions of metapelitic rocks from the Poshtuk area (bulk rock analyses)

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Figure 3. Discrimination diagram log (Fe2O3t/K2O) v. log (SiO2/Al2O3) from Herron (1988), showing a predominant shale composition for the Poshtuk metapelites.

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Table 3. Representative chloritoid, muscovite and chlorite analyses and structural formulae

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Table 4. Representative staurolite and garnet analyses and structural formulae

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Figure 4. (a) Chlorite composition of the Poshtuk metapelites on a formula proportion diagram (Al(VI)+2Ti+Cr-2 versus Al(IV)-2). Compositional variation along the 1:1 line represents the Tschermak substitution. After Larid (1988). (b) Analysed white micas plotted on SAF (SiO2, Al2O3, FeO) diagram. In all samples they are muscovite in composition. After Lambert (1959). (c) Composition of the studied garnets plotted on the Ca+Mn, Fe2+ and Mg triangular diagrams. Garnets are Fe-garnet. (d) Garnet zoning profiles from chloritoid schists of Poshtuk. Profile extends from rim to rim through the core of the garnets, which shows a flat profile. (e) Composition of the studied chloritoids plotted on the Mn, Fe2+, Mg and Mn+Fe2+, Al+Fe3+, Mg triangular diagrams. Chloritoids are Fe-chloritoid.

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Figure 5. (a–c) Al2O3–FeO–MgO (AFM) projection from quartz, muscovite and H2O of coexisting minerals in the Poshtuk schists.

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Figure 6. (a, b) AFM plots showing the mineral sub-assemblages for the garnet zone and staurolite zone samples (temperature T1 < temperature T2).

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Figure 7. (a) Representative results of multiple-equilibrium calculation using the THERMOCALC (3.2) program. A pressure of ~ 3.5 kbar and temperature of ~ 570 °C can be considered for metamorphism of the Poshtuk metapelites. (b) The above P–T results and fluid-bearing reaction allowed us to estimate the H2O content (0.8–1) of the fluid phase in the Poshtuk metapelite rocks.

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Figure 8. Simple linear temperature–depth trends for subduction, continental crust, and magmatic arc and contact aureole environments. The geothermal gradient of Poshtuk plots in the contact aureole environment.